Methods are disclosed to prepare permanent materials that can be coated onto microelectronic substrates or used for other structural or optical applications. The materials are thermally stable to at least about 300 C., curable using a photo or thermal process, exhibit good chemical resistance (including during metal passivation), and have a lifespan of at least about 5 years, preferably at least about 10 years, in the final device. Advantageously, these materials can also be bonded at room temperature. The materials exhibit no movement or squeeze-out after bonding and adhere to a variety of substrate types.

A novel photosensitive adhesive composition including the following components (A), (B), (C), and (D): Component (A): a polymer having a structural unit of the following formula (1) and a structure of the following formula (2) at a terminal, Component (B): a polymer having the structural unit of formula (1), and a carboxy group or hydroxy group at a terminal, Component (C): a radical photopolymerization initiator, and Component (D): a solvent, wherein the content by mass of the component (B) is larger than that of the component (A), ##STR00001##
(wherein X is a C.sub.1-6 alkyl group, a vinyl group, an allyl group, or a glycidyl group, m and n are each independently 0 or 1, Q is a divalent C.sub.1-16 hydrocarbon group, Z is a divalent C.sub.1-4 linking group, the divalent linking group being bonded to an O group in formula (1), and R.sup.1 is a hydrogen atom or a methyl group.)

A novel photosensitive adhesive composition including the following components (A), (B), (C), and (D): Component (A): a polymer having a structural unit of the following formula (1) and a structure of the following formula (2) at a terminal, Component (B): a polymer having the structural unit of formula (1), and a carboxy group or hydroxy group at a terminal, Component (C): a radical photopolymerization initiator, and Component (D): a solvent, wherein the content by mass of the component (B) is larger than that of the component (A), ##STR00001##
(wherein X is a C.sub.1-6 alkyl group, a vinyl group, an allyl group, or a glycidyl group, m and n are each independently 0 or 1, Q is a divalent C.sub.1-16 hydrocarbon group, Z is a divalent C.sub.1-4 linking group, the divalent linking group being bonded to an O group in formula (1), and R.sup.1 is a hydrogen atom or a methyl group.)

A polyester including at least one crosslinkable moiety is described. Each crosslinkable moiety includes at least one crosslinkable pendent group. A ratio of a total number of the at least one crosslinkable pendent groups to a total number of ester groups in the polyester may be in a range of 0.0001 to 0.5.

A polyester including at least one crosslinkable moiety is described. Each crosslinkable moiety includes at least one crosslinkable pendent group. A ratio of a total number of the at least one crosslinkable pendent groups to a total number of ester groups in the polyester may be in a range of 0.0001 to 0.5.

Processing tapes for use in preparing optical articles include a thermally stable tape backing and a low tack adhesive layer at least partially coated on tape backing. The low tack adhesive layer includes a crosslinked, polyester-containing (meth)acrylate-based polymer that is essentially free of volatile components, is unchanged after heat aging of 150 C for 1 hour under a pressure of 4.31 kiloPascals, and is able to removably adhere to the anti-reflective, nanostructured surface coating of an optical construction.

Processing tapes for use in preparing optical articles include a thermally stable tape backing and a low tack adhesive layer at least partially coated on tape backing. The low tack adhesive layer includes a crosslinked, polyester-containing (meth)acrylate-based polymer that is essentially free of volatile components, is unchanged after heat aging of 150 C for 1 hour under a pressure of 4.31 kiloPascals, and is able to removably adhere to the anti-reflective, nanostructured surface coating of an optical construction.

A composition with improved adhesive and sealant properties comprising a pre-polymer comprising a polymeric unit of the general formula (1A1B-).sub.n, wherein A represents a substituted or un-substituted ester, B represents a substituted or un-substituted acid ester comprising at least two acid ester functionalities, and n represents an integer greater than 1, wherein the compositions has a grafted anhydride content of less than about 0.05 mol/mol of polyacid.

A composition with improved adhesive and sealant properties comprising a pre-polymer comprising a polymeric unit of the general formula (1A1B-).sub.n, wherein A represents a substituted or un-substituted ester, B represents a substituted or un-substituted acid ester comprising at least two acid ester functionalities, and n represents an integer greater than 1, wherein the compositions has a grafted anhydride content of less than about 0.05 mol/mol of polyacid.

A composition with improved adhesive and sealant properties comprises a) a pre-polymer comprising a polymeric unit of the general formula (-A-B-).sub.n, wherein A represents a substituted or un-substituted ester, B represents a substituted or un-substituted acid ester comprising at least two acid ester functionalities, and n represents an integer greater than 1; wherein the content of grafted anhydride in the composition is less than 0.05 mol/mol of polyacid.