A resin composition includes a first (meth)acrylate monomer a second (meth)acrylate monomer containing an oxy group or a divalent alkyl group, a urethane (meth)acrylate oligomer, and at least one photoinitiator. A content of the first (meth)acrylate monomer is about 1.6 to about 4.7 times greater than a content of the urethane (meth)acrylate oligomer.

A resin composition includes a first (meth)acrylate monomer a second (meth)acrylate monomer containing an oxy group or a divalent alkyl group, a urethane (meth)acrylate oligomer, and at least one photoinitiator. A content of the first (meth)acrylate monomer is about 1.6 to about 4.7 times greater than a content of the urethane (meth)acrylate oligomer.

An extruded film manufactured by a process having the steps of manufacturing a compounded composition by compounding: a polyolefin; a first component that is: a polyethylene glycol, a polyethylene glycol mono-ester, a polyethylene glycol di-ester, a polycaprolactone, a polypropylene glycol, a polypropylene glycol mono-ester, a polypropylene glycol di-ester, a polyethylene-glycol polypropylene-glycol copolymer, an ester prepared from a copolymer of polyethylene glycol and polypropylene glycol, a polyethylene-glycol polycaprolactone copolymer, or a polypropylene-glycol polycaprolactone copolymer; a second component that is a phosphorus-containing compound having one of the following two structures:

##STR00001##

wherein each R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 is independently selected and is a C.sub.10-C.sub.18 alkyl moiety; n is an integer ranging from 3 to 11; and the sum of x.sub.1+x.sub.2 is an integer ranging from 1-251, or

##STR00002##

wherein each R.sup.1, R.sup.2, R.sup.3 and R.sup.4 is independently selected and is a C.sub.10-C.sub.18 alkyl moiety; m is an integer ranging from 3 to 11; and x is an integer ranging from 1 to 122; and a third component that is a salt; wherein the compounded composition does not include a fluorine-containing compound; and manufacturing an extruded film using the compounded composition, wherein the film has reduced melt fracture relative to a film manufactured by the same process and with a compounded composition that is otherwise the same but does not include the first, second, or third component.

A flame-retardant aconitic acid-derived monomer, a process for forming a flame-retardant polymer, and an article of manufacture comprising a material that contains a flame-retardant aconitic acid-derived monomer are disclosed. The flame-retardant aconitic acid-derived monomer can have at least one phosphoryl or phosphonyl moiety with functional groups that can participate in a polymerization reaction, such as allyl, epoxy, or propylene carbonate functional groups. The process for forming the flame-retardant polymer can include forming an aconitic acid derivative, forming a phosphorus-based flame-retardant molecule, and reacting the aconitic acid derivative with the phosphorus-based flame-retardant molecule to form a flame-retardant aconitic acid-derived monomer, which is then polymerized. The aconitic acid derivative can be synthesized from aconitic acid obtained from a bio-based source. The material in the article of manufacture can be a resin or adhesive, and the article of manufacture can further comprise an electronic component.

A flame-retardant aconitic acid-derived monomer, a process for forming a flame-retardant polymer, and an article of manufacture comprising a material that contains a flame-retardant aconitic acid-derived monomer are disclosed. The flame-retardant aconitic acid-derived monomer can have at least one phosphoryl or phosphonyl moiety with functional groups that can participate in a polymerization reaction, such as allyl, epoxy, or propylene carbonate functional groups. The process for forming the flame-retardant polymer can include forming an aconitic acid derivative, forming a phosphorus-based flame-retardant molecule, and reacting the aconitic acid derivative with the phosphorus-based flame-retardant molecule to form a flame-retardant aconitic acid-derived monomer, which is then polymerized. The aconitic acid derivative can be synthesized from aconitic acid obtained from a bio-based source. The material in the article of manufacture can be a resin or adhesive, and the article of manufacture can further comprise an electronic component.

A flame-retardant aconitic acid-derived monomer, a process for forming a flame-retardant polymer, and an article of manufacture comprising a material that contains a flame-retardant aconitic acid-derived monomer are disclosed. The flame-retardant aconitic acid-derived monomer can have at least one phosphoryl or phosphonyl moiety with functional groups that can participate in a polymerization reaction, such as allyl, epoxy, or propylene carbonate functional groups. The process for forming the flame-retardant polymer can include forming an aconitic acid derivative, forming a phosphorus-based flame-retardant molecule, and reacting the aconitic acid derivative with the phosphorus-based flame-retardant molecule to form a flame-retardant aconitic acid-derived monomer, which is then polymerized. The aconitic acid derivative can be synthesized from aconitic acid obtained from a bio-based source. The material in the article of manufacture can be a resin or adhesive, and the article of manufacture can further comprise an electronic component.

A flame-retardant aconitic acid-derived monomer, a process for forming a flame-retardant polymer, and an article of manufacture comprising a material that contains a flame-retardant aconitic acid-derived monomer are disclosed. The flame-retardant aconitic acid-derived monomer can have at least one phosphoryl or phosphonyl moiety with functional groups that can participate in a polymerization reaction, such as allyl, epoxy, or propylene carbonate functional groups. The process for forming the flame-retardant polymer can include forming an aconitic acid derivative, forming a phosphorus-based flame-retardant molecule, and reacting the aconitic acid derivative with the phosphorus-based flame-retardant molecule to form a flame-retardant aconitic acid-derived monomer, which is then polymerized. The aconitic acid derivative can be synthesized from aconitic acid obtained from a bio-based source. The material in the article of manufacture can be a resin or adhesive, and the article of manufacture can further comprise an electronic component.

Epoxy resin compositions that include oligomeric phosphonates, carbodiimides, carbodiimides and phenolic antioxidants or phosphite antioxidants, oligomeric phosphonates and carbodiimides, or oligomeric phosphonates, carbodiimides, and phenolic antioxidants or phosphite antioxidants and exhibit improved glass transition temperature, improved heat resistance, and improved flame retardancy are described herein.

An adhesive composition that is capable of functioning alone as an adhesive component without using a curable resin, and adhering to integrate an inorganic material and an organic material, and a composite material using the same. The adhesive composition contains an adduct containing an acidic phosphate ester comprising one or more kinds of compounds represented by General Formulae (1) and (2), and a metal. The composite material includes one material, the other material, and an adhesive composition disposed between the materials to adhere to the materials, the one material and the other material being integrated by the adhesive composition. P(O)(OR.sub.1)(OH).sub.2 . . . (1), and P(O)(OR.sub.1).sub.2(OH) . . . (2), where R.sub.1 represents an aliphatic hydrocarbon group having 4 to 30 carbon atoms, and has one or more branched chain structures, or one or more carbon-carbon double bond structures.

The disclosed subject matter relates compounds of structure (I), and polymers of structure (II) having a polydispersity ranging from 1 to about 1.1, compositions comprising said polymers and a spin casting solvent, the process of forming a pinning layer selectively on metal with said composition and the process of using said pinning layers to affect chemoepitaxy directed self-assembly of an overlying block copolymer, and the subsequent process of pattern transfer of this self-assembled layer into a substrate by etching. ##STR00001##