This disclosure relates to inorganic structured metal luminophores for the detection of peroxides and/or free radicals in proximity thereto. The disclosure includes the application of inorganic phosphates or mixtures thereof with one or more metal components that provides a structured metal luminophore capable of providing real-time detection and/or measurement of the presence of peroxides and/or free radicals in an environment proximal to the structured metal luminophore.

A phosphor according to the present disclosure has excellent light emission properties in a blue-green region and high color rendering properties. The phosphor is represented by a chemical formula of Lu.sub.(3-x-y-z)Mg.sub.xZn.sub.yAl.sub.5O.sub.12:Ce.sub.z, in which when z is in a range of 0.01≤z≤0.03, then 0≤x≤1.4 and 0≤y≤1.4, excluding x=0 and y=0; when z is in a range of is 0.03<z≤0.06, then y<0.2 and 0.1≤x≤1.4, or x<0.2 and 0.1≤y≤1.4, or x=0.2 and y=0.2; when z is in a range of 0.06<z≤0.09, then y<0.2 and 0.1≤x<1.4, or x<0.2 and 0.1≤y<1.4; and when z is in a range of 0.09<z≤0.12, then y<0.2 and 0.1≤x<0.9, or x<0.2 and 0.1≤y<0.9.

A device including an LED light source optically coupled to a phosphor selected from [Y,Gd,Tb,La,Sm,Pr,Lu].sub.3[Al,Ga].sub.5−aO.sub.12−3/2a:Ce.sup.3+ (wherein 0<a<0.5), beta-SiAlON:Eu.sup.2+, [Sr,Ca,Ba][Al,Ga,In].sub.2S.sub.4:Eu.sup.2+, alpha-SiAlON doped with Eu.sup.2+ and/or Ce.sup.3+, Ca.sub.1−h−rCe.sub.hEu.sub.rAl.sub.1−h[Mg,Zn].sub.hSiN.sub.3, (where 0<h<0.2, 0<r<0.2), Sr(LiAl.sub.3N.sub.4):Eu.sup.2+, [Ca,Sr]S:Eu.sup.2+ or Ce.sup.3+, [Ba,Sr,Ca].sub.bSi.sub.gN.sub.m:Eu.sup.2+ (wherein 2b+4g=3m), quantum dot materials, and combinations thereof; and a green-emitting U.sup.6+-doped phosphor having a composition selected from the group consisting of U.sup.6+-doped phosphate-vanadate phosphors, U.sup.6+-doped halide phosphors, U.sup.6+-doped oxyhalide phosphors, U.sup.6+-doped silicate-germanate phosphors, U.sup.6+-doped alkali earth oxide phosphors, and combinations thereof, is presented.

A device including an LED light source optically coupled to a green-emitting U.sup.6+-doped phosphor having a composition selected from the group consisting of U.sup.6+-doped phosphate-vanadate phosphors, U.sup.6+-doped halide phosphors, U.sup.6+-doped oxyhalide phosphors, U.sup.6+-doped silicate-germanate phosphors, U.sup.6+-doped alkali earth oxide phosphors, and combinations thereof, is presented. The U.sup.6+-doped phosphate-vanadate phosphors are selected from the group consisting of compositions of formulas (A1)-(A12). The U.sup.6+-doped halide phosphors are selected from the group consisting of compositions for formulas (B1)-(B3). The U.sup.6+-doped oxyhalide phosphors are selected from the group consisting of compositions of formulas (C1)-(C5). The U.sup.6+-doped silicate-germanate phosphors are selected from the group consisting of compositions of formulas (D1)-(D11). The U.sup.6+-doped alkali earth oxide phosphors are selected from the group consisting of formulas (E1)-(E11).

A device including an LED light source optically coupled to a green-emitting U.sup.6+-doped phosphor having a composition selected from the group consisting of U.sup.6+-doped phosphate-vanadate phosphors, U.sup.6+-doped halide phosphors, U.sup.6+-doped oxyhalide phosphors, U.sup.6+-doped silicate-germanate phosphors, U.sup.6+-doped alkali earth oxide phosphors, and combinations thereof, is presented. The U.sup.6+-doped phosphate-vanadate phosphors are selected from the group consisting of compositions of formulas (A1)-(A12). The U.sup.6+-doped halide phosphors are selected from the group consisting of compositions for formulas (B1)-(B3). The U.sup.6+-doped oxyhalide phosphors are selected from the group consisting of compositions of formulas (C1)-(C5). The U.sup.6+-doped silicate-germanate phosphors are selected from the group consisting of compositions of formulas (D1)-(D11). The U.sup.6+-doped alkali earth oxide phosphors are selected from the group consisting of formulas (E1)-(E11).

A phosphor according to the present disclosure has excellent light emission properties in a blue-green region and high color rendering properties. The phosphor is represented by a chemical formula of Lu.sub.(3-x-y-z)Mg.sub.xZn.sub.yAl.sub.5O.sub.12:Ce.sub.z, in which when z is in a range of 0.01z0.03, then 0x1.4 and 0y1.4, excluding x=0 and y=0; when z is in a range of is 0.03<z0.06, then y<0.2 and 0.1x1.4, or x<0.2 and 0.1y1.4, or x=0.2 and y=0.2; when z is in a range of 0.06<z0.09, then y<0.2 and 0.1x<1.4, or x<0.2 and 0.1y<1.4; and when z is in a range of 0.09<z0.12, then y<0.2 and 0.1x<0.9, or x<0.2 and 0.1y<0.9.

The invention relates to a security feature for securing value documents, comprising a chemically unstable inorganic feature substance and a stabilizing component that comprises a substance that stabilizes the feature substance, which substance has at least the same solubility in water as the feature substance to be protected and releases ions when said substance is decomposed, which ions conform to the ions of the feature substance at least in part.

The invention relates to a security feature for securing value documents, comprising a chemically unstable inorganic feature substance and a stabilizing component that comprises a substance that stabilizes the feature substance, which substance has at least the same solubility in water as the feature substance to be protected and releases ions when said substance is decomposed, which ions conform to the ions of the feature substance at least in part.

A device including an LED light source optically coupled to a green-emitting U.sup.6+-doped phosphor having a composition selected from the group consisting of U.sup.6+-doped phosphate-vanadate phosphors, U.sup.6+-doped halide phosphors, U.sup.6+-doped oxyhalide phosphors, U.sup.6+-doped silicate-germanate phosphors, U.sup.6+-doped alkali earth oxide phosphors, and combinations thereof, is presented. The U.sup.6+-doped phosphate-vanadate phosphors are selected from the group consisting of compositions of formulas (A1)-(A12). The U.sup.6+-doped halide phosphors are selected from the group consisting of compositions for formulas (B1)-(B3). The U.sup.6+-doped oxyhalide phosphors are selected from the group consisting of compositions of formulas (C1)-(C5). The U.sup.6+-doped silicate-germanate phosphors are selected from the group consisting of compositions of formulas (D1)-(D11). The U.sup.6+-doped alkali earth oxide phosphors are selected from the group consisting of formulas (E1)-(E11).

This disclosure relates to inorganic structured metal luminophores for the detection of peroxides and/or free radicals in proximity thereto. The disclosure includes the application of inorganic phosphates or mixtures thereof with one or more metal components that provides a structured metal luminophore capable of providing real-time detection and/or measurement of the presence of peroxides and/or free radicals in an environment proximal to the structured metal luminophore.