Patent classifications
C09K15/22
HYDROCARBON FUNCTIONALIZED POLYAMINES FOR CORROSION INHIBITION
Compositions and methods are provided for reducing, inhibiting, or preventing corrosion of a surface, the polyamine compounds corresponding to the structure of Formula 1 or 2, or a salt thereof:
##STR(1)##
wherein X.sub.1 is —C(O)R.sub.9 or —[C(R.sub.10R.sub.11)].sub.p—C(R.sub.12)(X.sub.2)—R.sub.13; X.sub.2 is —OH or —NH.sub.2; R.sub.1 and R.sub.4 are independently hydrogen, alkyl, or —[C(R.sub.10R.sub.11)].sub.p—C(R.sub.12)(X.sub.2)—R.sub.13; R.sub.2, R.sub.3, R.sub.5, R.sub.6, R.sub.7, R.sub.8, R.sub.10, R.sub.11, and R.sub.12 are independently hydrogen or alkyl; R.sub.9 and R.sub.13 are independently C.sub.7 to C.sub.30 alkyl or alkenyl; m and o are integers from 1 to 10; n is an integer from 1 to 6; and p is an integer from 1 to 10;
##STR(2)##
wherein X.sub.2 is —OH or —NH.sub.2; R.sub.21, R.sub.22, R.sub.23, R.sub.24, R.sub.25, R.sub.26, and R.sub.28 are independently hydrogen or alkyl; R.sub.27 is C.sub.10 to C.sub.30 alkyl or alkenyl; m and o are integers from 1 to 10; n is an integer from 1 to 6; and q is an integer from 0 to 10.
HYDROCARBON FUNCTIONALIZED POLYAMINES FOR CORROSION INHIBITION
Compositions and methods are provided for reducing, inhibiting, or preventing corrosion of a surface, the polyamine compounds corresponding to the structure of Formula 1 or 2, or a salt thereof:
##STR(1)##
wherein X.sub.1 is —C(O)R.sub.9 or —[C(R.sub.10R.sub.11)].sub.p—C(R.sub.12)(X.sub.2)—R.sub.13; X.sub.2 is —OH or —NH.sub.2; R.sub.1 and R.sub.4 are independently hydrogen, alkyl, or —[C(R.sub.10R.sub.11)].sub.p—C(R.sub.12)(X.sub.2)—R.sub.13; R.sub.2, R.sub.3, R.sub.5, R.sub.6, R.sub.7, R.sub.8, R.sub.10, R.sub.11, and R.sub.12 are independently hydrogen or alkyl; R.sub.9 and R.sub.13 are independently C.sub.7 to C.sub.30 alkyl or alkenyl; m and o are integers from 1 to 10; n is an integer from 1 to 6; and p is an integer from 1 to 10;
##STR(2)##
wherein X.sub.2 is —OH or —NH.sub.2; R.sub.21, R.sub.22, R.sub.23, R.sub.24, R.sub.25, R.sub.26, and R.sub.28 are independently hydrogen or alkyl; R.sub.27 is C.sub.10 to C.sub.30 alkyl or alkenyl; m and o are integers from 1 to 10; n is an integer from 1 to 6; and q is an integer from 0 to 10.
ALKYL LACTONE-DERIVED CORROSION INHIBITORS
Disclosed are alkyl lactone-derived hydroxyamide and alkyl lactone-derived hydroxyester used in compositions and methods for inhibiting corrosion. The alkyl lactone-derived hydroxyamide and alkyl lactone-derived hydroxyester are reaction products of an alkyl lactone and an amine, and an alkyl lactone and an alcohol, respectively.
ALKYL LACTONE-DERIVED CORROSION INHIBITORS
Disclosed are alkyl lactone-derived hydroxyamide and alkyl lactone-derived hydroxyester used in compositions and methods for inhibiting corrosion. The alkyl lactone-derived hydroxyamide and alkyl lactone-derived hydroxyester are reaction products of an alkyl lactone and an amine, and an alkyl lactone and an alcohol, respectively.
Oxidation inhibitor, and food and drink containing fats and oils using same
An oxidation inhibitor containing, as an active ingredient, an aminocarbonyl compound having a structure resulting from binding of an amino group of a compound having sphingoid base structure and a carbonyl group of a carbonyl compound. The oxidation inhibitor has high oxidation inhibitory effects, and inhibits oxidation of fats and oils, in particular, fats and oils containing a large proportion of polyunsaturated fatty acids to prevent deterioration due to oxidation of fats and oils.
Oxidation inhibitor, and food and drink containing fats and oils using same
An oxidation inhibitor containing, as an active ingredient, an aminocarbonyl compound having a structure resulting from binding of an amino group of a compound having sphingoid base structure and a carbonyl group of a carbonyl compound. The oxidation inhibitor has high oxidation inhibitory effects, and inhibits oxidation of fats and oils, in particular, fats and oils containing a large proportion of polyunsaturated fatty acids to prevent deterioration due to oxidation of fats and oils.
COMPOSITONS AND METHODS COMPRISING NITRIFICATION INHIBITORS CONTAINING A MIXTURE OF PROTIC AND APROTIC SOLVENT SYSTEMS
The present invention relates to increasing longevity of the nitrogen content of soil through improved liquid delivery formulations of nitrification inhibitors. The liquid formulation can also be comprised of nitrification inhibitors and optionally urease inhibitors that are blended solutions of each. The nitrification inhibitors are present in a mixture that comprises both a protic and an aprotic solvent system. The novel formulations are designed to be applied to fertilizers, especially urea and manure based fertilizers. The delivery formulations provide an environmentally sound and inherently safe solvating system that improves the storage stability of the urease inhibitors by utilizing liquid organic non-water containing solvents, maintains the nitrification inhibitors in solution to storage temperatures of at least 10° C., and provides improved application to fertilizer of nitrification inhibitors. These delivery formulations enable safe storage, transport and subsequent application or blending with urea-based or manure-based fertilizers that can be applied to soil in either a liquid or granular form to provide improved nitrogen retention in the soil for uptake for plant life.
COMPOSITONS AND METHODS COMPRISING NITRIFICATION INHIBITORS CONTAINING A MIXTURE OF PROTIC AND APROTIC SOLVENT SYSTEMS
The present invention relates to increasing longevity of the nitrogen content of soil through improved liquid delivery formulations of nitrification inhibitors. The liquid formulation can also be comprised of nitrification inhibitors and optionally urease inhibitors that are blended solutions of each. The nitrification inhibitors are present in a mixture that comprises both a protic and an aprotic solvent system. The novel formulations are designed to be applied to fertilizers, especially urea and manure based fertilizers. The delivery formulations provide an environmentally sound and inherently safe solvating system that improves the storage stability of the urease inhibitors by utilizing liquid organic non-water containing solvents, maintains the nitrification inhibitors in solution to storage temperatures of at least 10° C., and provides improved application to fertilizer of nitrification inhibitors. These delivery formulations enable safe storage, transport and subsequent application or blending with urea-based or manure-based fertilizers that can be applied to soil in either a liquid or granular form to provide improved nitrogen retention in the soil for uptake for plant life.
Corrosion-Inhibiting Compositions
The invention relates to a composition comprising a) at least one N-methyl-N-acylglucamine of formula (I), wherein R.sup.1 represents a linear or branched, saturated or unsaturated hydrocarbon chain with 7 to 21 carbon atoms, one or more organic acids of formula (II) and/or the salts thereof, R.sup.2—COOM, wherein R.sup.2 represents a linear or branched alkyl group or a linear or branched mono- or poly-unsaturated alkenyl group with 5 to 29 carbon atoms, and M represents hydrogen or one or more cations, wherein the cations are present in charge-equalizing amounts, and c) one or more alkanolamines of formula (III), wherein NR.sup.1R.sup.2R.sup.3R.sup.1, R.sup.2 and R.sup.3 represent hydrogen, a linear or branched alkyl group with 1 to 4 carbon atoms, a cycloalkyl group with 5 to 7 carbon atoms, a linear or branched hydroxyalkyl group with 2 to 5 carbon atoms and 1 or 2 hydroxy groups or a hydroxyether group with 2 to 6 carbon atoms, with the provision that at least one of the groups is a hydroxyalkyl group or a hydroxyether group.
##STR00001##
Quaternized fatty amines, amidoamines and their derivatives from natural oil metathesis
Quaternary ammonium, betaine, or sulfobetaine compositions derived from fatty amines, wherein the fatty amine is made by reducing the amide reaction product of a metathesis-derived C.sub.10-C.sub.17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives and a secondary amine, are disclosed. Quaternary ammonium, betaine, or sulfobetaine compositions derived from fatty amidoamines, wherein the amidoamine is made by reacting of a metathesis-derived C.sub.10-C.sub.17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives and an aminoalkyl-substituted tertiary amine, are also disclosed. The quaternized compositions are advantageously sulfonated or sulfitated. In one aspect, the ester derivative of the C.sub.10-C.sub.17 monounsaturated acid or octadecene-1,18-dioic acid is a lower alkyl ester. In other aspects, the ester derivative is a modified triglyceride made by self-metathesis of a natural oil or an unsaturated triglyceride made by cross-metathesis of a natural oil with an olefin. The quaternary ammonium, betaine, and sulfobetaine compositions and their sulfonated or sulfitated derivatives are valuable for a wide variety of end uses, including cleaners, fabric treatment, hair conditioning, personal care (liquid cleansing products, conditioning bars, oral care products), antimicrobial compositions, agricultural uses, and oil field applications.