C09K19/2007

Liquid crystalline composition, side chain type polymer liquid crystalline compound, light absorption anisotropic film, laminate, and image display device

A side chain type polymer liquid crystalline compound with which a light absorption anisotropic film having a high alignment degree can be formed, which includes a liquid crystalline composition, a light absorption anisotropic film which is formed of the liquid crystalline composition, a laminate, and an image display device. A liquid crystalline composition contains a side chain type polymer liquid crystalline compound and a dichroic substance, the side chain type polymer liquid crystalline compound is a copolymer having repeating units 1 and 2, the repeating unit 1 has a mesogenic group and an electron-withdrawing group having a Hammett's substituent constant σp of greater than 0 at a terminal of the mesogenic group, and the repeating unit 2 has a mesogenic group and a group having a Hammett's substituent constant σp of 0 or less at a terminal of the mesogenic group.

COMPOUND, COMPOSITION, CURED SUBSTANCE, OPTICALLY ANISOTROPIC BODY, OPTICAL ELEMENT, AND LIGHT GUIDE ELEMENT

A compound represented by the General Formula (I) as defined herein, in which, in the General Formula (I), P.sup.1 and P.sup.2 each independently represent a hydrogen atom, —CN, —NCS, or a polymerizable group, Sp.sup.1 and Sp.sup.2 each independently represent a single bond or a divalent linking group as defined herein, Z.sup.1, Z.sup.2 and Z.sup.3 each independently represent a particular linking group as defined herein, X.sup.1 and X.sup.2 each independently represent a single bond or —S as defined herein, k represents an integer of 2 to 4, m and n each independently represent an integer of 0 to 3 as defined herein, A.sup.1, A.sup.2, A.sup.3, and A.sup.4 each independently represent a particular group as defined herein is provided.

Optical film comprising a stretched resin film and a liquid crystal layer including a polyfunctional compound having two or more polymerizable groups in one molecule, circularly polarizing plate, and image display apparatus

Provided are an optical film, a circularly polarizing plate, and an image display apparatus in each of which the occurrence of cracks is suppressed in the obtained film in a case of being punched. The optical film includes a stretched resin film and a liquid crystal layer formed by fixing a liquid crystal compound twist-aligned along a helical axis extending along a direction in thickness, in which a δa value calculated using a three-dimensional solubility parameter of a resin in the stretched resin film is 8.0 MPa.sup.1/2 or less, the liquid crystal layer contains a cured substance of a polyfunctional compound having two or more polymerizable groups in one molecule, and an absolute value of a difference between the δa value calculated using the three-dimensional solubility parameter of the polyfunctional compound and the δa value calculated using the three-dimensional solubility parameter of the resin is 4.0 MPa.sup.1/2 or less.

POLYMERIZABLE COMPOSITION AND OPTICALLY ANISOTROPIC BODY USING SAME

The polymerizable composition contains: a) a polymerizable compound having one or two or more polymerizable groups and satisfying formula (I):


Re(450 nm)/Re(550 nm)<1.0  (I);

b) at least one photopolymerization initiator selected from the group consisting of alkylphenone-based compounds, acylphosphine oxide-based compounds, and oxime ester-based compounds; and c) a polymerization inhibitor. The present invention also provides an optically anisotropic body, a retardation film, an antireflective film, and a liquid crystal display device that are produced using the polymerizable liquid crystal composition. The polymerizable composition of the present invention is excellent in solubility and has high storage stability, so that no precipitation of crystals etc. occurs. When a film-shaped polymer is produced by polymerizing the above composition, the unevenness of the surface of the coating film is small while the alignment of the liquid crystal is maintained, and high durability is obtained. Therefore, the polymerizable composition is useful.

COMPOUND AND LIQUID CRYSTAL COMPOSITION

The present invention provides a compound having an excellent amount of change in HTP and an excellent HTP saturation rate during exposure, and a liquid crystal composition including the compound. The compound of the present invention is a compound represented by General Formula (A).


(Y).sub.n-G-(X).sub.m   (A)

G represents a group represented by General Formula (B-1) or a group represented by General Formula (B-2), * represents a bonding position, and X and Y represent a predetermined group.

##STR00001##

Polymerizable liquid crystal composition, optically anisotropic film, optical film, polarizing plate, and image display device

Provided is a polymerizable liquid crystal composition used for formation of an optically anisotropic film having excellent durability, an optically anisotropic film, an optical film, a polarizing plate, and an image display device. The polymerizable liquid crystal composition contains a polymerizable liquid crystal compound represented by Formula (1) and an acidic compound, in which a pKa of the acidic compound is more than −10 and 5 or less, and a content of the acidic compound is 20 parts by mass or less with respect to 100 parts by mass of the polymerizable liquid crystal compound. ##STR00001##

Polymerizable composition and optically anisotropic body using same

A polymerizable composition containing: a) a polymerizable compound having one or two or more polymerizable groups and satisfying formula (I): Re(450 nm)/Re(550 nm)<1.0 (I); b) at least one photopolymerization initiator selected from the group consisting of alkylphenone-based compounds, acylphosphine oxide-based compounds, and oxime ester-based compounds; and c) a polymerization inhibitor. An optically anisotropic body, a retardation film, an antireflective film, and a liquid crystal display device that are produced using the polymerizable liquid crystal composition. The polymerizable composition is excellent in solubility and has high storage stability, so that no precipitation of crystals etc. occurs. When a film-shaped polymer is produced by polymerizing the above composition, the unevenness of the surface of the coating film is small while the alignment of the liquid crystal is maintained, and high durability is obtained. Therefore, the polymerizable composition is useful.

Liquid crystal composition, method for producing high-molecular weight liquid crystal compound, light absorption anisotropic film, laminate, and image display device
11697770 · 2023-07-11 · ·

The present invention provides a liquid crystal composition with which a light absorption anisotropic film excellent in plane shape uniformity with a high alignment degree can be formed, a method of producing same, a light absorption anisotropic film, a laminate, and an image display device. The liquid crystal composition contains a high-molecular weight liquid crystal compound, and a dichroic substance, where the composition is a copolymer containing 90% by mass or more of a repeating unit (1) of Formula (1) and 10% by mass or less of a repeating unit (2) of Formula (2). In Formulae (1) and (2), P1 to P3 represent main chains, L1 to L3 represent a single bond or divalent linking group, P2 to SP3 represent a single bond or spacer group (SP1), M1 to M3 represent mesogenic groups, T1 represents a terminal group, and n and m are integers of 0 or 1. ##STR00001##

LIGHT COLOR CONVERSION MATERIAL AND LIGHT COLOR CONVERSION INK

Provided are a light color conversion material and a light color conversion ink. The light color conversion material includes a quantum dot and a cross-linkable cholesteric liquid crystal material. The cross-linkable cholesteric liquid crystal material encapsulates the quantum dot. The cross-linkable cholesteric liquid crystal material has Bragg diffraction characteristic after cross-linking, and blue light with a wavelength between 400 nm and 480 nm may be reflected by the cross-linked cholesteric liquid crystal material and transmitted through the cross-linked cholesteric liquid crystal material at the same time.

OPTICAL FILM, CIRCULARLY POLARIZING PLATE, AND IMAGE DISPLAY APPARATUS

Provided are an optical film, a circularly polarizing plate, and an image display apparatus in each of which the occurrence of cracks is suppressed in the obtained film in a case of being punched. The optical film includes a stretched resin film and a liquid crystal layer formed by fixing a liquid crystal compound twist-aligned along a helical axis extending along a direction in thickness, in which a δa value calculated using a three-dimensional solubility parameter of a resin in the stretched resin film is 8.0 MPa.sup.1/2 or less, the liquid crystal layer contains a cured substance of a polyfunctional compound having two or more polymerizable groups in one molecule, and an absolute value of a difference between the δa value calculated using the three-dimensional solubility parameter of the polyfunctional compound and the δa value calculated using the three-dimensional solubility parameter of the resin is 4.0 MPa.sup.1/2 or less.