To show a liquid crystal composition containing a polymerizable compound, to exhibit excellent persistence characteristics and display unevenness characteristics, a liquid crystal display device including such a composition, and an optical device. To show a liquid crystal composition containing the polymerizable compound and satisfying at least one of characteristics such as high maximum temperature, low minimum temperature, small viscosity, suitable optical anisotropy, large negative dielectric anisotropy and large specific resistance; and an AM device having characteristics such as a small persistence ratio, a short response time, a low threshold voltage, a large voltage holding ratio, a large contrast ratio and a long service life. The liquid crystal composition contains as a first component a polymerizable monomer that has a capability of a hydrogen bond donor and can form a hydrogen bond with an alignment film surface, or an oligomer, a prepolymer or a polymer of the monomer.

The present invention relates to a composite material, a liquid crystal film, a method for preparing the film, a temperature-responsive device comprising the film, and a circular polarizer made therefrom. The liquid crystal film comprises the composite material of the present invention, wherein the composite material comprises a polymer network of a cholesteric liquid crystal material, and a chiral material capable of hydrogen-bond-assisted self-assembly, and wherein the chiral material is dispersed in and restrained by the polymer network. The obtained liquid crystal film can exhibit a high reflectivity and a high transmittance as well as a broad band reflection. And, the liquid crystal film is applicable for an industrial development because it can be produced with a simple process and at a lower cost, and requires a lower UV luminous intensity.