Patent classifications
C09K2200/062
Sealant composition
The instant invention provides a polyolefin composition suitable for sealant applications, sealant compositions, method of producing the same, and films and multilayer structures made therefrom. The polyolefin composition suitable for sealant applications according to the present invention comprises: an ethylene/α-olefin interpolymer composition having a Comonomer Distribution Constant (CDC) in the range of from 40 to 110, vinyl unsaturation of less than 0.1 vinyls per one thousand carbon atoms present in the backbone of the ethylene-based polymer composition; a zero shear viscosity ratio (ZSVR) in the range of from 1.01 to 2.0; a density in the range of from 0.908 to 0.922 g/cm.sup.3, a melt index (I.sub.2 at 190° C./2.16 kg) in the range of from 0.5 to 5.0 g/10 minutes, a molecular weight distribution (defined as the weight average molecular weight divided by the number average molecular weight, M.sub.w/M.sub.n) in the range of from 2.0 to 4.0, and tan delta at 0.1 radian/second, determined at 190° C., in the range of from 5 to 50.
SOLAR CELL MODULE
Disclosed is a solar cell module including an n-type crystalline silicon-based solar cell element as a power generation element, in which at least one surface of the n-type crystalline silicon-based solar cell element is encapsulated with a solar-cell encapsulating material including an ethylene•α-olefin copolymer satisfying the following requirements a1) to a4).
a1) A content proportion of a structural unit derived from ethylene is in a range of 80 to 90 mol %, and a content proportion of a structural unit derived from an α-olefin having 3 to 20 carbon atoms is in a range of 10 to 20 mol %.
a2) MFR measured under defined conditions is in a range of 0.1 to 50 g/10 minutes. a3) A density, which is measured under defined conditions in a range of 0.865 to 0.884 g/cm.sup.3.
a4) A Shore A hardness, which is measured under defined conditions is in a range of 60 to 85.
SEALING MATERIAL FOR SOLAR CELL MODULES, AND MANUFACTURING METHOD THEREOF
Disclosed are a sealing material for solar cell modules and a manufacturing method thereof capable of endowing good transparency and heat resistance to the sealing material for solar cell modules while using a polyethylene-based resin. The disclosed sealing material for solar cell modules uses a polyethylene-based resin with a density of 0.900 g/cm3 or less, and an MFR between 0.1 g/10 min and 1.0 g/10 min. The sealing material is obtained by melt molding a resin composition containing a polyethylene-based resin with density 0.890 g/cm3 or less, and a polymerization initiator contained at 0.02 mass % or more but less than 0.5 mass % of the composition, wherein the density difference of the resin composition before and after the melt molding is within 0.05 g/cm3, and the MFR difference of the resin composition before and after the melt molding is 1.0 g/10 min or greater.
SEALANT FILM
The present invention provides a film and/or a packaging bag from which contents that may be viscous are easily brought out, and exhibiting enough heat seal properties as well as superior anti-blocking effect and slipperiness. The sealant film has a seal layer consisting of a resin composition including the following (a) and (b), and the film satisfies the following (1) to (3). (a) Polyolefin-based resin; and (b) Silylated polyolefin resin, (1) An abundance ratio (Si/C) of silicon atoms Si to carbon atoms C included in the seal layer of 0.001 or more and 0.02 or less; (2) An abundance ratio (Si/C) of silicon atoms Si to carbon atoms C present at a surface of the seal layer of 0.05 or more and 0.2 or less; and (3) An arithmetic average roughness Ra of a surface of the seal layer of 0.1 μm or more and 0.5 μm or less
Gas phase polyethylene copolymers
Polyethylene copolymers with a structure that provides improved film properties are provided. The copolymers can have a density of about 0.905 to about 0.911 g/cm.sup.3. The copolymers can also have a DRI/I2 ratio of about 0.0008 to about 0.060, an I2 value of about 0.6 to about 3.8 dg/min, and an I21 value of about 8 to about 57 dg/min. The copolymers having those properties can be produced by introducing ethylene and at least one other olefin comonomer to a single reactor at a comonomer/ethylene mole ratio of about 0.02 to about 0.03 and polymerizing at a temperature of about 76.7° C. to about 80.6° C. and a pressure of about 1,724 kPa to about 2,413 kPa. The copolymers can be used to make films having a 21 mol % O.sub.2 transmission rate of about 150 to about 200 cc/100 in.sup.2/24 hr. and hot tack seal initiation temperatures of about 65° C. to 80° C.
CONTAINER CLOSURE WITH A SEALING ELEMENT
The invention relates to a container closure (1, 21, 41, 61) with a sealing element (3, 23, 43, 63). The sealing element (3, 23, 43, 63) comprises a polymer composition. The polymer composition comprises a butene copolymer. The butene copolymer has a melting temperature T.sub.m of between 30° C. and 130° C., wherein the melting temperature T. is determined by the second heating curve of a DSC measurement at a heating rate of 10° C. min.sup.−1
A THERMOPLASTIC COMPOSITION HAVING IMPROVED MECHANICAL PROPERTIES
A thermoplastic composition including a thermoplastic polymer component and at least one elastomer, wherein the thermoplastic polymer component comprises at least one propylene copolymer having a propylene content of at least 60 wt.-% and at least one ethylene copolymer having an ethylene content of at least 50 wt.-%. The invention is also directed to a sealing device comprising a waterproofing layer obtained by using the thermoplastic composition, to a method for producing a sealing device, to a method for waterproofing a substrate, and to a method for bonding a first substrate to a second substrate.
Combined seals, compositions, and methods of making the same
A combined sealing member is provided that includes a composition comprising two or more polyolefin elastomers selected from the group consisting of a dense, a micro-dense and a dynamic silane-crosslinked polyolefin elastomer having a respective density of less than 0.90 g/cm.sup.3, less than 0.70 g/cm.sup.3, and less than 0.60 g/cm.sup.3. The combined sealing member exhibits a compression set of from about 5.0% to about 35.0%, as measured according to ASTM D 395 (22 hrs @ 70° C.).
RESIN COMPOSITION, AND FILM FOR LID MATERIALS
The purpose is to provide a resin composition and a film for lid material which excel in sealability and adhesiveness to plastic containers, especially containers made of polyethylene terephthalate, polylactic acid, polystyrene, or polypropylene, and are suitably usable as sealant layers of lid materials for containers. Provided is a resin composition including: an ethylene-vinyl acetate copolymer (A) by 60-95 parts by weight, the ethylene-vinyl acetate copolymer (A) having a vinyl acetate content (VA) of 3-13% by weight, and having a ratio Qw between a weight-average molecular weight (Mw) and a number-average molecular weight (Mn) of 1.5-4.5; and a tackifier resin (B) by 5-40 parts by weight, where a total amount of (A) and (B) is 100 parts by weight.
Gas Phase Polyethylene Copolymers
Polyethylene copolymers with a structure that provides improved film properties are provided. The copolymers can have a density of about 0.905 to about 0.911 g/cm.sup.3. The copolymers can also have a DRI/I2 ratio of about 0.0008 to about 0.060, an I2 value of about 0.6 to about 3.8 dg/min, and an I21 value of about 8 to about 57 dg/min. The copolymers having those properties can be produced by introducing ethylene and at least one other olefin comonomer to a single reactor at a comonomer/ethylene mole ratio of about 0.02 to about 0.03 and polymerizing at a temperature of about 76.7° C. to about 80.6° C. and a pressure of about 1,724 kPa to about 2,413 kPa. The copolymers can be used to make films having a 21 mol % O.sub.2 transmission rate of about 150 to about 200 cc/100 in.sup.2/24 hr. and hot tack seal initiation temperatures of about 65° C. to 80° C.