C09K2323/035

Liquid crystalline composition, side chain type polymer liquid crystalline compound, light absorption anisotropic film, laminate, and image display device

A side chain type polymer liquid crystalline compound with which a light absorption anisotropic film having a high alignment degree can be formed, which includes a liquid crystalline composition, a light absorption anisotropic film which is formed of the liquid crystalline composition, a laminate, and an image display device. A liquid crystalline composition contains a side chain type polymer liquid crystalline compound and a dichroic substance, the side chain type polymer liquid crystalline compound is a copolymer having repeating units 1 and 2, the repeating unit 1 has a mesogenic group and an electron-withdrawing group having a Hammett's substituent constant σp of greater than 0 at a terminal of the mesogenic group, and the repeating unit 2 has a mesogenic group and a group having a Hammett's substituent constant σp of 0 or less at a terminal of the mesogenic group.

REGIOSELECTIVELY SUBSTITUTED CELLULOSE ESTERS AND FILMS MADE THEREFROM

Regioselectively substituted cellulose esters having a plurality of pivaloyl substituents and a plurality of aryl-acyl substituents are disclosed along with methods for making the same. Such cellulose esters may be suitable for use in films, such as +A optical films, and/or +C optical films. Optical films prepared employing such cellulose esters have a variety of commercial applications, such as, for example, as compensation films in liquid crystal displays and/or waveplates in creating circular polarized light used in 3-D technology.

Polymerizable liquid crystal composition, optically anisotropic film, optical film, polarizing plate, and image display device

Provided is a polymerizable liquid crystal composition used for formation of an optically anisotropic film having excellent durability, an optically anisotropic film, an optical film, a polarizing plate, and an image display device. The polymerizable liquid crystal composition contains a polymerizable liquid crystal compound represented by Formula (1) and an acidic compound, in which a pKa of the acidic compound is more than −10 and 5 or less, and a content of the acidic compound is 20 parts by mass or less with respect to 100 parts by mass of the polymerizable liquid crystal compound. ##STR00001##

Polarizer and image display device

Provided are a polarizer having a high degree of alignment and an image display device including the polarizer. The polarizer of the present invention is a polarizer which is formed of a polarizer-forming composition containing a liquid crystal compound and a dichroic material, in which the liquid crystal compound and the dichroic material are horizontally aligned, and in an X-ray diffraction spectrum of the polarizer, at least one of a plurality of peaks observed in a diffraction angle range of 17° or less is a peak A in which an interval of a periodic structure corresponding to the at least one peak does not have an integer multiple relationship with an interval of a periodic structure corresponding to at least one of other peaks.

Optical film, polarizing plate, and image display device

An object of the present invention is to provide an optical film which is excellent in the adhesiveness between a polymer support and a photo alignment film and in which a liquid crystal compound having reverse wavelength dispersibility is uniformly aligned. The optical film is obtained by laminating, in the following order: a polymer support containing an additive; a photo alignment film; and an optically anisotropic film, wherein the optically anisotropic film is formed of a polymerizable liquid crystal composition containing a polymerizable liquid crystal compound having reverse wavelength dispersibility, and an amount of a component derived from the additive of the polymer support, which is contained in a boundary region with the optically anisotropic film in the photo alignment film is 0.10 to 0.50 mass % with respect to a total mass of the photo alignment film.

Liquid crystal display device

An alignment film is given a 2-layer structure comprising a photoalignment film that is photoalignable and a low-resistivity alignment film whose resistivity is smaller than that of the photoalignment film. The photoalignment film is formed by a polyimide whose precursor is polyamide acid alkyl ester, the number molecular weight of the photoalignment film is large, and the stability of alignment of the photoalignment film by photoalignment is excellent. The low-resistivity alignment film is formed by a polyimide whose precursor is polyamide acid, the number molecular weight of the low-resistivity alignment film is small, and the resistivity of the low-resistivity alignment film is small. The 2-layer structure alignment film can be maintaining an excellent photoalignment characteristic, so DC afterimages can be controlled.

Anti-glare hard coat laminated film

One embodiment provides a hard coat laminated film, comprising, in order from a surface layer side, a first hard coat, a second hard coat, and a transparent resin film layer, where the first hard coat is formed of a coating material including: (A) 100 parts by mass of a polyfunctional (meth)acrylate; (B) 0.01 to 7 parts by mass of a water repellent; (C) 0.01 to 10 parts by mass of a silane coupling agent; and (D) 0.1 to 10 parts by mass of resin microparticles having an average particle diameter of 0.5 to 10 μm, and containing no inorganic particles, and where the second hard coat is formed of a coating material containing inorganic particles. Another embodiment provides a hard coat laminated film having, in order from a surface layer side, a first hard coat, a second hard coat, and a resin film layer. The first hard coat includes a coating material that does not include inorganic particles. The second hard coat includes a coating material including inorganic particles. The adhesive film fulfills the conditions: (i) a total light transmission rate of at least 85%; (ii) a pencil hardness for the first hard coat surface of at least 5H; and (iii) a Y value for an XYZ color system of 1.5%-4.2%.

Polymerizable liquid crystal material, polymerizable liquid crystal composition, polymer, optical film, optically anisotropic body, polarizing plate, anti-reflection film, display device, and method of producing polymerizable liquid crystal composition
11492552 · 2022-11-08 · ·

Disclosed is a polymerizable liquid crystal material wherein an amount of a salt represented by the following formula (I) is less than 0.01 parts by mass per 100 parts by mass of a polymerizable liquid crystal compound, and an amount of a nitrogen-containing compound represented by the following formula (II) is 0.01 parts by mass or less per 100 parts by mass of the polymerizable liquid crystal compound. R.sup.1 to R.sup.5 each independently represent a hydrogen atom or a C1-C7 alkyl group, R.sup.6 and R.sup.7 represents a hydrogen atom, and X represents F.sup.−, Br.sup.−, Cl.sup.−, I.sup.−, HSO.sub.4.sup.−, 1/2(HPO.sub.4.sup.2−), H.sub.2PO.sub.4.sup.−, R—C(═O)—O.sup.−, 1/2(.sup.−O—(C═O)—R′—(C═O)—O.sup.−) or R—SO.sub.3.sup.−, where R represents a hydrogen atom or a monovalent hydrocarbon group, and R′ represents a single bond or a divalent hydrocarbon group. ##STR00001##

Polarizing plate and optical display device comprising same

A polarizing plate and an optical display comprising the same are disclosed. The polarizing plate includes: a polarizer and a first protective layer stacked on one surface of the polarizer via a bonding layer, wherein the bonding layer is formed of a bonding layer composition including an epoxy compound and a photocationic initiator, and the polarizing plate has a chrominance variation ΔE of 5.2 or less, as calculated by Equation 1.

Optical multilayer film, and optical component and display device comprising the same
11614565 · 2023-03-28 · ·

The optical multilayer film, which comprises a laminate in which a base layer, a primer layer, a hard coat layer, a first refractive layer, and a second refractive layer are sequentially laminated, has a very low reflectance and enhanced optical characteristics by adjusting the in-plane retardation of the base layer and the refractive indices of the respective layers. Thus, the optical component and the display device, which comprise the optical multilayer film, have a low reflectance and excellent other optical characteristics.