Apparatuses, systems, and methods are disclosed for producing and liberating hydrogen gas and sequestering carbon dioxide through sequential serpentinization and carbonation (mineralization) reactions conducted in situ via one or more wellbores that at least partially traverse subterranean geological formations having large concentrations of mafic igneous rock, ultramafic igneous rock, or a combination thereof.

Apparatuses, systems, and methods are disclosed for producing and liberating hydrogen gas and sequestering carbon dioxide through sequential serpentinization and carbonation (mineralization) reactions conducted in situ via one or more wellbores that at least partially traverse subterranean geological formations having large concentrations of mafic igneous rock, ultramafic igneous rock, or a combination thereof.

A system and method of hydraulic fracturing, including providing a fracturing fluid having a nitrite-containing compound through a wellbore into a subterranean formation to hydraulically fracture the subterranean formation, thereby forming fractures in the subterranean formation. The technique includes generating nitrogen gas (and thus foam) in the fractures via the nitrite-containing compound, and in which generating the nitrogen gas facilitates flowback.

An omniphobic emulsion comprising an aqueous continuous phase having dispersed therein a plurality of non-aqueous discontinuous phase droplets; wherein the non-aqueous discontinuous phase droplets are characterized by a droplet size of less than about 100 micrometers (μm); wherein each of the plurality of non-aqueous discontinuous phase droplets comprises a plurality of surfactant molecules and an omniphobic agent, wherein each surfactant molecule has a hydrophilic head portion and a hydrophobic tail portion; wherein each of the plurality of non-aqueous discontinuous phase droplets comprises the plurality surfactant molecules having the hydrophilic head portions disposed into a droplet outer layer with the hydrophobic tail portions extending inward from the droplet outer layer toward the omniphobic agent; and wherein the droplet outer layer encloses the omniphobic agent.

Disclosed are surface-modified nanoparticles and surfactants used in compositions and methods for enhancing hydro-carbon recovery from subterranean formations.

A method for acid treatment of a wellbore in a carbonate formation is provided. The method includes dropping spacer solids into the well to fill the wellbore to perforations in a casing, dropping acidic solids into the wellbore on the top of the spacer solids, allowing the acidic solids to dissolve on top of the spacer solids forming an acidic solution, and injecting water into the wellbore to force the acidic solution into the carbonate formation.

A method for acid treatment of a wellbore in a carbonate formation is provided. The method includes dropping spacer solids into the well to fill the wellbore to perforations in a casing, dropping acidic solids into the wellbore on the top of the spacer solids, allowing the acidic solids to dissolve on top of the spacer solids forming an acidic solution, and injecting water into the wellbore to force the acidic solution into the carbonate formation.

Rheology modifiers comprising cross-linked poly(amino acid) and methods of their use in aqueous compositions. The modifiers comprise cross-linked poly(amino acid) microparticles having a mean equivalent diameter when fully swollen in deionized water of up to 1000 μm, as measured by laser diffraction. In particular, the poly(amino acid) is D-, L- or D,L-Y-poly(glutamic acid). A method of preparing the modifier comprises cross-linking a poly(amino acid), drying the cross-linked poly(amino acid) and grinding the cross-linked poly(amino acid) to have the required diameter.

Rheology modifiers comprising cross-linked poly(amino acid) and methods of their use in aqueous compositions. The modifiers comprise cross-linked poly(amino acid) microparticles having a mean equivalent diameter when fully swollen in deionized water of up to 1000 μm, as measured by laser diffraction. In particular, the poly(amino acid) is D-, L- or D,L-Y-poly(glutamic acid). A method of preparing the modifier comprises cross-linking a poly(amino acid), drying the cross-linked poly(amino acid) and grinding the cross-linked poly(amino acid) to have the required diameter.

The disclosure relates to a method of delaying viscosification of a well treatment fluid within a well or within a subterranean formation penetrated by a well by introducing into the well a hydratable viscosifying agent of particulates having a minimum of 40% retention on a 60 mesh screen and a minimum of 1% retention on a 20 mesh screen.