Processes and systems for converting a hydrocarbon-containing feed. The feed and heated particles can be contacted within a pyrolysis zone to effect pyrolysis of at least a portion of the feed to produce a pyrolysis zone effluent and a first gaseous stream rich in olefins and a first particle stream rich in the particles can be obtained therefrom. At least a portion of the first particle stream, an oxidant, and steam can be fed into a gasification zone and contacted therein to effect gasification of at least a portion of coke disposed on the surface of the particles to produce a gasification zone effluent. A second gaseous stream rich in a synthesis gas and a second particle stream rich in heated and regenerated particles can be obtained from the gasification zone effluent. At least a portion of the second particle stream can be fed into the pyrolysis zone.

The invention relates to a method and an apparatus for producing hydrocarbons from plastic containing material, wherein the plastic containing material (1) is subjected into a pyrolysis reactor (2), steam (3) is fed into the pyrolysis reactor, and the plastic containing material is pyrolyzed with the steam by using a catalytic pyrolysis with a basic catalyst to convert the plastic containing material to a product (4) comprising hydrocarbons. Further, the invention relates to the use of the product obtained by the method.

The invention relates to a method and an apparatus for producing hydrocarbons from plastic containing material, wherein the plastic containing material (1) is subjected into a pyrolysis reactor (2), steam (3) is fed into the pyrolysis reactor, and the plastic containing material is pyrolyzed with the steam by using a catalytic pyrolysis with a basic catalyst to convert the plastic containing material to a product (4) comprising hydrocarbons. Further, the invention relates to the use of the product obtained by the method.

The furnace of a delayed coking unit which is utilized for heating residue feeds to high temperatures can suffer from decrease in run length and fouling caused by caustic carryover from the upstream desalter unit. An antifoulant additive for preventing caustic induced fouling of thermal cracker furnace tubes is disclosed. The described antifoulant additive acts by converting the inorganic caustic compound such as NaOH to naphthenate salt of the metal as well as by reducing the fouling tendency of the whole feedstock, thereby making it ineffective in causing coking reaction. The additive finds application in thermal residue upgradation furnaces such as delayed coking unit, visbreaker, etc.

In a ferrocoke manufacturing method by shaping and carbonizing a mixture of coal and iron ore, a hardly softening coal having a button index (CSN) of not more than 2.0 is used as the coal. The coal can be a blend of hardly softening coal and easily softening coal, and the hardly softening coal can be a coal having a button index (CSN) of 1.0 and a volatile matter of not less than 17%, and the easily softening coal can be a coal satisfying that a value obtained by multiplying CSN of easily softening coal by a blending ratio of easily softening coal in all coals is a range of 0.3-5.2. The coal can also be a blend of hardly softening coal and easily softening coal, and the hardly softening coal can be a coal having a button index (CSN) of 1.5-2.0, and the easily softening coal can be a coal satisfying that a value obtained by multiplying CSN of easily softening coal by a blending ratio of easily softening coal in all coals is nit more than 5.0.

In a ferrocoke manufacturing method by shaping and carbonizing a mixture of coal and iron ore, a hardly softening coal having a button index (CSN) of not more than 2.0 is used as the coal. The coal can be a blend of hardly softening coal and easily softening coal, and the hardly softening coal can be a coal having a button index (CSN) of 1.0 and a volatile matter of not less than 17%, and the easily softening coal can be a coal satisfying that a value obtained by multiplying CSN of easily softening coal by a blending ratio of easily softening coal in all coals is a range of 0.3-5.2. The coal can also be a blend of hardly softening coal and easily softening coal, and the hardly softening coal can be a coal having a button index (CSN) of 1.5-2.0, and the easily softening coal can be a coal satisfying that a value obtained by multiplying CSN of easily softening coal by a blending ratio of easily softening coal in all coals is nit more than 5.0.

This disclosure provides a method of making a high-fixed-carbon material comprising pyrolyzing biomass to generate intermediate solids and a pyrolysis vapor; condensing the pyrolysis vapor to generate pyrolysis liquid; blending the pyrolysis liquid with the intermediate solids, to generate a mixture; and further pyrolyzing the mixture to generate a high-fixed-carbon material. A process can comprise: pyrolyzing a biomass-comprising feedstock in a first pyrolysis reactor to generate a first biogenic reagent and a first pyrolysis vapor; introducing the first pyrolysis vapor to a condensing system to generate a condenser liquid; contacting the first biogenic reagent with the condenser liquid, thereby generating an intermediate material; further pyrolyzing the intermediate material in a second pyrolysis reactor to generate a second biogenic reagent and a second pyrolysis vapor; and recovering the second biogenic reagent as a high-yield biocarbon composition. The process can further comprise pelletizing the intermediate material. Many process and system configurations are disclosed.

This invention provides processes and systems for converting biomass into high-carbon biogenic reagents that are suitable for a variety of commercial applications. Some embodiments employ pyrolysis in the presence of an inert gas to generate hot pyrolyzed solids, condensable vapors, and non-condensable gases, followed by separation of vapors and gases, and cooling of the hot pyrolyzed solids in the presence of the inert gas. Additives may be introduced during processing or combined with the reagent, or both. The biogenic reagent may include at least 70 wt %, 80 wt %, 90 wt %, 95 wt %, or more total carbon on a dry basis. The biogenic reagent may have an energy content of at least 12,000 Btu/lb, 13,000 Btu/lb, 14,000 Btu/lb, or 14,500 Btu/lb on a dry basis. The biogenic reagent may be formed into fine powders, or structural objects. The structural objects may have a structure and/or strength that derive from the feedstock, heat rate, and additives.

This invention provides processes and systems for converting biomass into high-carbon biogenic reagents that are suitable for a variety of commercial applications. Some embodiments employ pyrolysis in the presence of an inert gas to generate hot pyrolyzed solids, condensable vapors, and non-condensable gases, followed by separation of vapors and gases, and cooling of the hot pyrolyzed solids in the presence of the inert gas. Additives may be introduced during processing or combined with the reagent, or both. The biogenic reagent may include at least 70 wt %, 80 wt %, 90 wt %, 95 wt %, or more total carbon on a dry basis. The biogenic reagent may have an energy content of at least 12,000 Btu/lb, 13,000 Btu/lb, 14,000 Btu/lb, or 14,500 Btu/lb on a dry basis. The biogenic reagent may be formed into fine powders, or structural objects. The structural objects may have a structure and/or strength that derive from the feedstock, heat rate, and additives.

The present disclosure provides a method of preparing a carbonaceous material capable of fixing arsenic and an application thereof. Through biomass pretreatment, biomass pyrolysis and arsenite fixation, a biochar activated by potassium carbonate and an arsenic-containing wastewater containing sulfur-containing substances are mixed and deoxidized, and an anaerobic culture is carried out, to fix arsenic by the biochar activated by potassium carbonate. The present disclosure solves the problems that arsenic is released from the soil and groundwater under anaerobic conditions, the ability of conventional passivatingagents to fix arsenic under anaerobic conditions is weakened, and the conventional carbonaceous materials not only cannot fix arsenic, but also accelerate the release of anaerobic arsenic.