A supercritical water separation process and system is disclosed for the removal of metals, minerals, particulate, asphaltenes, and resins from a contaminated organic material. The present invention takes advantage of the physical and chemical properties of supercritical water to effect the desired separation of contaminants from organic materials and permit scale-up. At a temperature and pressure above the critical point of water (374° C., 22.1 MPa), nonpolar organic compounds become miscible in supercritical water (SCW) and polar compounds and asphaltenes become immiscible. The process and system disclosed continuously separates immiscible contaminants and solids from the supercritical water and clean oil product solution. The present invention creates a density gradient that enables over 95% recovery of clean oil and over 99% reduction of contaminants such as asphaltenes and particulate matter depending on the properties of the contaminated organic material.

A supercritical water separation process and system is disclosed for the removal of metals, minerals, particulate, asphaltenes, and resins from a contaminated organic material. The present invention takes advantage of the physical and chemical properties of supercritical water to effect the desired separation of contaminants from organic materials and permit scale-up. At a temperature and pressure above the critical point of water (374° C., 22.1 MPa), nonpolar organic compounds become miscible in supercritical water (SCW) and polar compounds and asphaltenes become immiscible. The process and system disclosed continuously separates immiscible contaminants and solids from the supercritical water and clean oil product solution. The present invention creates a density gradient that enables over 95% recovery of clean oil and over 99% reduction of contaminants such as asphaltenes and particulate matter depending on the properties of the contaminated organic material.

The present invention relates to the extraction of gasoline from a gas G, with (a) a step of extracting gasoline from the gas to be treated comprising methanol GM obtained from step (d), (b) a step of separating said fluid GL1 partially condensed in step (a), producing a first aqueous liquid phase A1, a first liquid phase H1 of hydrocarbon(s) a gaseous phase G1 obtained from the gas G; (c) a step of contacting a portion of the gas G to be treated with said first aqueous liquid phase A1, producing a second aqueous liquid phase A2, a gaseous phase of gas to be treated comprising methanol GM′; (d) a step of mixing said gaseous phase of gas to be treated comprising methanol GM′ with the remainder of the gas G to be treated, producing a gas to be treated comprising methanol GM, (e) a step of stabilizing said first liquid phase H1 of hydrocarbon(s).

The present invention relates to the extraction of gasoline from a gas G, with (a) a step of extracting gasoline from the gas to be treated comprising methanol GM obtained from step (d), (b) a step of separating said fluid GL1 partially condensed in step (a), producing a first aqueous liquid phase A1, a first liquid phase H1 of hydrocarbon(s) a gaseous phase G1 obtained from the gas G; (c) a step of contacting a portion of the gas G to be treated with said first aqueous liquid phase A1, producing a second aqueous liquid phase A2, a gaseous phase of gas to be treated comprising methanol GM′; (d) a step of mixing said gaseous phase of gas to be treated comprising methanol GM′ with the remainder of the gas G to be treated, producing a gas to be treated comprising methanol GM, (e) a step of stabilizing said first liquid phase H1 of hydrocarbon(s).

Disclosed herein is a system comprising: a) a separator tank comprising a first inlet, a second inlet, a first outlet, and a second outlet, b) a heat exchanger, and c) a holding tank comprising a third inlet and a third outlet, wherein the separator tank is in fluid communication with the holding tank via a first connector and via a second connector, wherein the first connector is connected to the first outlet of the separator tank and to the third inlet of the holding tank, wherein the second connector is connected to the first inlet of the separator tank and to the third outlet of the holding tank, and wherein the first connector and the second connector are in communication with the heat exchanger.

Disclosed herein is a system comprising: a) a separator tank comprising a first inlet, a second inlet, a first outlet, and a second outlet, b) a heat exchanger, and c) a holding tank comprising a third inlet and a third outlet, wherein the separator tank is in fluid communication with the holding tank via a first connector and via a second connector, wherein the first connector is connected to the first outlet of the separator tank and to the third inlet of the holding tank, wherein the second connector is connected to the first inlet of the separator tank and to the third outlet of the holding tank, and wherein the first connector and the second connector are in communication with the heat exchanger.

A system and method for cleaning sulfur and other pollutants from bunker oil to be used for fuel in large cargo ships is described. Preferably, the system includes two or more stages having a mixer to create an emulsion of oil and water. One or more treatment chemicals are added to the water before it is mixed with the oil in order to assist in separating the sulfur from the oil and freeing it up so that it can combine with various other molecules present in the water or be dissolved in the water. The emulsion may pass through a microcavitation chamber as well as an electrolysis reactor chamber in order to further clean the fuel oil by removing additional sulfur content. The clean fuel is sent to a fuel service tank for use in a diesel engine combustion cycle.

A system and method for cleaning sulfur and other pollutants from bunker oil to be used for fuel in large cargo ships is described. Preferably, the system includes two or more stages having a mixer to create an emulsion of oil and water. One or more treatment chemicals are added to the water before it is mixed with the oil in order to assist in separating the sulfur from the oil and freeing it up so that it can combine with various other molecules present in the water or be dissolved in the water. The emulsion may pass through a microcavitation chamber as well as an electrolysis reactor chamber in order to further clean the fuel oil by removing additional sulfur content. The clean fuel is sent to a fuel service tank for use in a diesel engine combustion cycle.

The removal of poisonous metalloids from crude oil is a method of removing naturally occurring arsenic (As), antimony (Sb), and bismuth (Bi) from crude oil before the crude oil is processed through a refinery. The removal of poisonous metalloids from crude oil entails forming an emulsion comprising the crude oil and an inorganic salt or mineral acid solution prepared by recirculation and agitation. The agitation of the emulsion causes arsenic (As), antimony (Sb), and bismuth (Bi) containing compounds to dissolve in the inorganic salt or mineral acid solution. The crude oil is separated from the inorganic salt or mineral acid solution by settling. The treated crude oil has a poisonous metalloid concentration of less than 1 ppm making it acceptable for oil refining operations. Optionally, any inorganic salt or mineral acid solution remaining in the crude oil after separation can be removed using a silica gel dryer.

A method may include: introducing a fluid comprising a first immiscible phase and a second immiscible phase into a contacting vessel comprising multiple contact stages: flowing the fluid through a first fiber bundle disposed in the contacting vessel; separating at least a portion of the first immiscible phase from the second immiscible phase; and flowing the separated portion of the first immiscible phase through a second fiber bundle disposed in the contacting vessel.