Patent classifications
C10G21/30
Method and System for Removing Hydrogen Sulfide from Sour Oil and Sour Water
Embodiments of the present invention are generally related to a system and method to remove hydrogen sulfide from sour water and sour oil. Particularly, hydrogen sulfide is removed from sour water and sour oil without the need for special chemicals, such as catalyst chemicals, scavenger chemicals, hydrocarbon sources, or a large-scale facility. The system and method in the present invention is particularly useful in exploratory oil and gas fields, where large facilities to remove hydrogen sulfide may be inaccessible. The present invention addresses the need for safe and cost-effective transport of the deadly neurotoxin. Particular embodiments involve a system and method that can be executed both on a small and large scale to sweeten sour water and sour oil.
Method and System for Removing Hydrogen Sulfide from Sour Oil and Sour Water
Embodiments of the present invention are generally related to a system and method to remove hydrogen sulfide from sour water and sour oil. Particularly, hydrogen sulfide is removed from sour water and sour oil without the need for special chemicals, such as catalyst chemicals, scavenger chemicals, hydrocarbon sources, or a large-scale facility. The system and method in the present invention is particularly useful in exploratory oil and gas fields, where large facilities to remove hydrogen sulfide may be inaccessible. The present invention addresses the need for safe and cost-effective transport of the deadly neurotoxin. Particular embodiments involve a system and method that can be executed both on a small and large scale to sweeten sour water and sour oil.
Process of coprocessing a lignocellulosic liquid stream and an intermediate fossil stream in an oil refining process and a process for producing fuel from a deasphalted oil stream
The present invention describes the coprocessing of a lignocellulosic liquid stream and an intermediate fossil stream in the oil refining process comprising the steps of (a) contacting said intermediate fossil stream and said lignocellulosic liquid stream with a stream of solvent of C.sub.3-C.sub.10 hydrocarbons in an extraction section, obtaining a stream of extract with solvent and a stream of raffinate with solvent; and (b) sending said stream of extract with solvent to a separation section, obtaining a deasphalted oil stream comprising solvent-free carbon of renewable origin and a stream of recovered solvent. The present invention further relates to a process for producing fuels from the deasphalted oil stream comprising carbon of renewable origin, wherein the process comprises sending the deasphalted oil stream to a conversion section of an oil refinery. The conversion section is selected from catalytic hydrocracking unit, thermal cracking, fluidized-bed catalytic cracking, visbreaking, delayed coking and catalytic reforming.
Process of coprocessing a lignocellulosic liquid stream and an intermediate fossil stream in an oil refining process and a process for producing fuel from a deasphalted oil stream
The present invention describes the coprocessing of a lignocellulosic liquid stream and an intermediate fossil stream in the oil refining process comprising the steps of (a) contacting said intermediate fossil stream and said lignocellulosic liquid stream with a stream of solvent of C.sub.3-C.sub.10 hydrocarbons in an extraction section, obtaining a stream of extract with solvent and a stream of raffinate with solvent; and (b) sending said stream of extract with solvent to a separation section, obtaining a deasphalted oil stream comprising solvent-free carbon of renewable origin and a stream of recovered solvent. The present invention further relates to a process for producing fuels from the deasphalted oil stream comprising carbon of renewable origin, wherein the process comprises sending the deasphalted oil stream to a conversion section of an oil refinery. The conversion section is selected from catalytic hydrocracking unit, thermal cracking, fluidized-bed catalytic cracking, visbreaking, delayed coking and catalytic reforming.
LIQUID-LIQUID EXTRACTION TECHNIQUES
A liquid-liquid extraction system includes extraction stages, a pumping system, and a controller. Each extraction stage has a chamber, a primary input, a raffinate output, and an extract output. An input liquid (e.g., either a source liquid or raffinate from a preceding extraction stage, mixed with an extraction liquid) is presented to the chamber via the primary input. The chamber enables phase separation of liquid therein, into a raffinate and a extract, where the raffinate exits the separation vessel at the raffinate output, and the extract exits the separation vessel at the extract output. A level sensor is coupled to the chamber and the controller is operatively programmed to read an output of the level sensor, compare the output of the level sensor to a target, and cause the associated chamber to receive additional liquid if the output is lower than the target.
LIQUID-LIQUID EXTRACTION TECHNIQUES
A liquid-liquid extraction system includes extraction stages, a pumping system, and a controller. Each extraction stage has a chamber, a primary input, a raffinate output, and an extract output. An input liquid (e.g., either a source liquid or raffinate from a preceding extraction stage, mixed with an extraction liquid) is presented to the chamber via the primary input. The chamber enables phase separation of liquid therein, into a raffinate and a extract, where the raffinate exits the separation vessel at the raffinate output, and the extract exits the separation vessel at the extract output. A level sensor is coupled to the chamber and the controller is operatively programmed to read an output of the level sensor, compare the output of the level sensor to a target, and cause the associated chamber to receive additional liquid if the output is lower than the target.
Deasphalting process for production of feedstocks for dual applications
The invention concerns with improved and more flexible deasphalting process for production of lube oil base stock as well as feed stock for secondary processes depending on requirement from heavy residual hydrocarbon oil containing saturates, aromatics, resins and asphaltenes etc by contacting the oil with a solvent comprising of hydrocarbon containing two to six carbon atoms, preferably LPG having C3-C4 hydrocarbons and mixture thereof at predetermined deasphalting conditions wherein the yield of deasphalted oil including its quality is controlled by varying the deasphalting conditions including the operating temperature. The yield variations of 15 to 60 wt % is achieved by swinging the temperature by about 10-20° C. within the operative temperature range of 70-130° C. keeping the rest of the operating conditions including solvent to feed ratio same. The LPG solvent can be recovered using supercritical mode of operation using technology known in the art and recycled.
Deasphalting process for production of feedstocks for dual applications
The invention concerns with improved and more flexible deasphalting process for production of lube oil base stock as well as feed stock for secondary processes depending on requirement from heavy residual hydrocarbon oil containing saturates, aromatics, resins and asphaltenes etc by contacting the oil with a solvent comprising of hydrocarbon containing two to six carbon atoms, preferably LPG having C3-C4 hydrocarbons and mixture thereof at predetermined deasphalting conditions wherein the yield of deasphalted oil including its quality is controlled by varying the deasphalting conditions including the operating temperature. The yield variations of 15 to 60 wt % is achieved by swinging the temperature by about 10-20° C. within the operative temperature range of 70-130° C. keeping the rest of the operating conditions including solvent to feed ratio same. The LPG solvent can be recovered using supercritical mode of operation using technology known in the art and recycled.
Monitoring of residual metals in paraffinic froth treatment operations and process control
Techniques provided herein relate to regulating at least one operating parameter of a paraffinic froth treatment (PFT) operation and controlling the quality of the produced bitumen in response to a determined concentration of at least one residual metal in a PFT process stream. Determination of the residual metal concentration is based on acquired NIR spectral measurements of the PFT process stream. An alkaline agent dosage in primary extraction operation can be for example regulated in response to a difference between a determined calcium concentration and a calcium concentration specification.
Monitoring of residual metals in paraffinic froth treatment operations and process control
Techniques provided herein relate to regulating at least one operating parameter of a paraffinic froth treatment (PFT) operation and controlling the quality of the produced bitumen in response to a determined concentration of at least one residual metal in a PFT process stream. Determination of the residual metal concentration is based on acquired NIR spectral measurements of the PFT process stream. An alkaline agent dosage in primary extraction operation can be for example regulated in response to a difference between a determined calcium concentration and a calcium concentration specification.