Methods are provided for using a molecular sieve catalyst for dewaxing formed using a synthesis mixture comprising a morphology modifier. The catalyst may be used, for example, for production of a lubricant base stock. For example, ZSM-48 crystals formed using the morphology modifier (and/or formulated catalysts made using such crystals) can have an increased activity and/or can provide an improved yield during catalytic dewaxing of lubricant base stocks.

Systems and methods for producing an isomerization product. One or more isomerization reactors comprising a catalyst may be used to process an isomerization feedstock comprising a primary n-paraffin reactant and hydrogen gas, and the isomerization reactor may be operated at a pressure parameter at which the partial pressure of the primary n-paraffin is within about 70% to about 130% of its equilibrium vapor pressure to isomerize the primary n-paraffin reactant.

The invention provides a process for the preparation of an olefinic product, comprising: (a) reacting an oxygenate feedstock, in a reaction zone in the presence of a molecular sieve catalyst, at a temperature from 350 to 1000° C., to produce a reaction effluent stream, comprising at least oxygenate, olefin, water and acidic by-products; (b) cooling the reaction effluent stream by means of an indirect heat exchange to a temperature greater than the dew point temperature of reaction effluent stream; (c) further rapidly cooling the reaction effluent stream to a temperature lower than the dew point temperature of the reaction effluent stream by direct injection of an aqueous liquid into the reaction effluent stream, to form a first quench effluent stream; and (d) separating the first quench effluent stream into a first liquid quench effluent stream and a first gaseous quench effluent stream, comprising the olefinic product.

The present invention relates to a process for the production of propylene-based polymers from waste plastics feedstocks comprising the steps in this order of: (a) providing a hydrocarbon stream A obtained by treatment of a waste plastics feedstock; (b) providing a hydrocarbon stream B; (c) supplying a feed C comprising a fraction of the hydrocarbon stream A and a fraction of the hydrocarbon stream B to a thermal cracker furnace comprising cracking coil(s); (d) performing a thermal cracking operation in the presence of steam to obtain a cracked hydrocarbon stream D; (e) supplying the cracked hydrocarbon stream D to a separation unit; (f) performing a separation operation in the separation unit to obtain a product stream E comprising propylene; (g) supplying the product stream E to a polymerisation reactor; and (h) performing a polymerisation reaction in the polymerisation reactor to obtain an propylene-based polymer; wherein in step (d): •⋅ the coil outlet temperature is 2:: 800 and:::; 850° C., preferably 2:: 805 and:::; 835° C.; and •⋅ the weight ratio of steam to feed C is >0.3 and <0.8.

A process for producing olefins comprising the steps of separating the liquid oil in the fractionator to produce a light oil product; separating the light oil product in the extractor to produce a paraffin fraction stream; increasing a pressure of the paraffin fraction stream in a paraffin pump to produce a pressurized paraffin stream; mixing the pressurized paraffin stream with a pressurized water feed in the water mixer to produce a paraffin-containing water stream; heating the paraffin-containing water stream in the water heater to produce a hot paraffin-water stream, wherein a temperature of the hot paraffin-water stream is greater than 450 deg C, wherein the short chain paraffins are operable to crack at the temperature of the hot paraffin-water stream; mixing the hot paraffin-water stream and the hot feedstock in the feed mixer to produce a mixed feed stream; and introducing the mixed feed stream to the supercritical unit.

An improved alkylation process with improved octane number and lower final boiling point. Further, the present disclosure comprises an alkylation system that allows flexibility in the operating parameters without loss of productivity. This enhances the advantage of the solid acid alkylation process of the invention over the liquid acid processes, as the C9+ alkylate will mainly contain the desired highly branched paraffin's in the case of solid acid alkylation. By fractionation of C9+, the RON number of the gasoline alkylate after fractionation remains very high, while the final boiling point of the gasoline fraction will decrease, improving value and blending flexibility.

A process for producing olefins comprising the steps of separating the liquid oil in the fractionator to produce a light oil product; separating the light oil product in the extractor to produce a paraffin fraction stream; increasing a pressure of the paraffin fraction stream in a paraffin pump to produce a pressurized paraffin stream; mixing the pressurized paraffin stream with a pressurized water feed in the water mixer to produce a paraffin-containing water stream; heating the paraffin-containing water stream in the water heater to produce a hot paraffin-water stream, wherein a temperature of the hot paraffin-water stream is greater than 450 deg C., wherein the short chain paraffins are operable to crack at the temperature of the hot paraffin-water stream; mixing the hot paraffin-water stream and the hot feedstock in the feed mixer to produce a mixed feed stream; and introducing the mixed feed stream to the supercritical unit.

A process for the production of polymers from waste plastics feedstocks includes: providing a hydrocarbon stream A obtained by treatment of a waste plastics feedstock; optionally providing a hydrocarbon stream B; supplying a feed C comprising a fraction of the hydrocarbon stream A and a fraction of the hydrocarbon stream B to a thermal cracker furnace comprising cracking coil(s); performing a thermal cracking operation in the presence of steam to obtain a cracked hydrocarbon stream D; supplying the cracked hydrocarbon stream D to a separation unit; performing a separation operation in the separation unit to obtain a product stream E comprising a monomer; supplying the product stream E to a polymerisation reactor; and performing a polymerisation reaction to obtain an polymer. The process allows for optimisation of the quantity of waste plastic material that finds its way back into a polymer that is produced as outcome of the process.

The present invention relates to a process for the production of ethylene-based polymers from waste plastics feedstocks comprising the steps in this order of: (a) providing a hydrocarbon stream A obtained by hydrotreatment of a pyrolysis oil produced from a waste plastics feedstock; (b) optionally providing a hydrocarbon stream B; (c) supplying a feed C comprising a fraction of the hydrocarbon stream A and optionally a fraction of the hydrocarbon stream B to a thermal cracker furnace comprising cracking coil(s); (d) performing a thermal cracking operation in the presence of steam to obtain a cracked hydrocarbon stream D; (e) supplying the cracked hydrocarbon stream D to a separation unit; (f) performing a separation operation in the separation unit to obtain a product stream E comprising ethylene; (g) supplying the product stream E to a polymerisation reactor; and (h) performing a polymerisation reaction in the polymerisation reactor to obtain an ethylene-based polymer; wherein in step (d): • ⋅ the coil outlet temperature is 2: 800 and; 870° C., preferably 2: 820 and; 870° C.; and • ⋅ the weight ratio of steam to feed C is >0.3 and <0.8.

A fluidized catalytic reactor system cycles from 0.05-5% of catalyst at a time through a rejuvenation unit to be heated in the presence of oxygen to maintain catalyst activity. The use of the rejuvenation unit that may be 2% of the size of the main catalyst regeneration unit allows for reduction in equipment size and in catalyst inventory. The catalyst that is sent to the rejuvenation unit may be spent catalyst but may be partially or fully regenerated catalyst. The rejuvenation unit may be heated by combusting fuel or by hot flue gas.