Provided is a continuous process for converting waste plastic into recycle for polyethylene polymerization. In one embodiment, the process comprises selecting waste plastics containing polyethylene and/or polypropylene and passing the waste plastics through a pyrolysis reactor to thermally crack at least a portion of the polyolefin waste and produce a pyrolyzed effluent. The pyrolyzed effluent is separated into offgas, a naphtha/diesel fraction, a heavy fraction, and char. The naphtha/diesel fraction is passed to a crude unit distillation column in a refinery where a straight run naphtha (C.sub.5-C.sub.8) fraction or a propane/butane (C.sub.3-C.sub.4) fraction is recovered. The straight run naphtha fraction (C.sub.5-C.sub.8) or the propane/butane (C.sub.3-C.sub.4) fraction is passed to a steam cracker for ethylene production. The heavy fraction from the pyrolysis unit can also be passed to an isomerization dewaxing unit to produce a base oil.

A process for extracting fuel products from waste rubber, comprising the steps of subjecting the waste rubber to pyrolysis to produce a pyrolysis vapour, subjecting the pyrolysis vapour to a condensation step to produce a pyrolytic oil having a boiling point range of 45-400° C. and a flash point below 25° C., and then subjecting the pyrolytic oil to a vacuum steam stripping step so as to recover a fraction having a flash point of at least 40° C. but no higher than 55° C., a boiling point range starting at 100° C. or higher, a density at 15° C. of less than 990 kg/m.sup.3, a total acid number TAN of up to 12, a styrene content of less than 7000 ppm, and an organic halogen (as Cl) content of less than 50 ppm.

Provided are an apparatus and a method for refining pyrolysis oil in which a dechlorination reaction is performed at a first temperature under a first hydrotreating catalyst, denitrification reaction is performed at a second temperature higher than the first temperature under a second hydrotreating catalyst, and chlorine adsorption by an adsorbent is performed after the dechlorination reaction, thereby preventing production of an ammonium salt (NH.sub.4Cl), and providing refined oil which is excellent in prevention of corrosion of a reactor, improvement of durability, occurrence of differential pressure, and process efficiency, has very low contents of impurities such as chlorine, nitrogen, and metal and olefin, and has excellent quality.

A method of upgrading an overflash stream from a vacuum distillation unit comprising the steps of separating the overflash stream from an atmospheric residue stream, the overflash stream comprises an overflash fraction having a T10% between 475 and 530° C. and a T90% between 600 and 700° C.; introducing the reactor feed to a supercritical reactor at a temperature between 380° C. and 500° C. and a pressure between 25 MPa and 30 MPa; maintaining upgrading reactions in the supercritical reactor to upgrade the overflash fraction such that a reactor effluent comprises upgraded hydrocarbons relative to the overflash fraction; reducing a temperature of a reactor effluent in a cooling device to produce a cooled stream; reducing a pressure of the cooled stream in a depressurizing device to produce a discharged stream; and separating the discharged stream in a gas-liquid separator to produce a liquid phase product.

A process for treating effluent streams in a naphtha complex is described. One or more of the sour water stripping unit for the NHT sour water from the NHT, the amine treatment unit and the caustic treatment unit for the NHT stripper off-gas, the caustic scrubber unit or other chloride treatment unit for the off-gas from the C.sub.5-C.sub.6 isomerization zone and the C.sub.4 isomerization zone, and the caustic scrubber unit or other chloride treatment unit for the regenerator off-gas are replaced with a thermal oxidation system.

The invention relates to producing upgraded renewable oil. Renewable crude oil is provided whose oxygen content, water content, and total acid number are within predetermined ranges. Respective fractions of the oil have boiling points below 350° C. and above 450° C. After the oil is pressurized, and hydrogen is added, the mixture is heated and contacted with a heterogeneous catalyst in a first reaction zone with weight based hourly space velocity (WHSV) of 0.1 to 1 h-1. The resultant partially hydrogenated and deoxygenated oil is further heated and contacted with a heterogeneous catalyst in a second reaction zone at WHSV of 0.1 to 1.5 h-1. Low and high boiling point liquid hydrocarbon fractions of the product of the second reaction zone are sent to third and fourth reaction zones, respectively, to be contacted with hydrogen and a heterogeneous catalyst under respective heating conditions and WHSV of 0.1 to 1 h-1.

A petroleum hydrocarbon multi-stage fluid catalytic reaction method and reactor are described. The method implements a sectional multi-stage reaction in one reactor and comprises primary-stage and secondary-stage catalytic cracking reactions of feedstock oil and primary-stage and secondary-stage catalytic cracking reactions of light hydrocarbons and/or cycle oil, which occur in different reaction regions of the reactor. The primary-stage reaction of the light hydrocarbon and/or circulation oil is carried out in an independent reaction region. The reactor comprises a first reaction section, a catalyst splitter, a third reaction section, a second reaction section and a settler.

The present invention discloses an integrated process scheme for producing (i) high-octane gasoline blending stream (ii) high aromatic heavy naphtha stream which is a suitable feedstock for benzene, toluene, and xylene (BTX) production and (iii) high cetane ultra-low sulphur diesel (ULSD) stream suitable for blending in refinery diesel pool.

Catalyst containing an active phase which contains a group VIB element, at least one group VIII element and phosphorus, and a support containing alumina, the catalyst being characterized in that at least 80% by weight of the group VIB elements, of the group VIII elements and of the phosphorus are distributed in the form of a crust at the periphery of said support, the thickness of said crust being between 100 and 1200 μm, the content of group VIB element being between 1% and 8% by weight relative to the total weight of the catalyst, the content of group VIII element being between 0.5% and 5% by weight relative to the total weight of the catalyst, and the content of phosphorus being between 0.2% and 3% by weight relative to the total weight of the catalyst, and the support having a specific surface area of between 100 m.sup.2/g and 250 m.sup.2/g.

The present disclosure refers to a process of obtaining a biocrude from biomass, where said process comprises the solvothermal liquefaction of the biomass in the presence of a mixture of solvents, until obtaining a gaseous phase, a solid phase, an aqueous liquid phase and an organic liquid phase comprising the biocrude. Wherein the mixture of solvents comprises between 0.5% w/w to 99.5% w/w of water and at least one solvent; and wherein the solvent is selected from alcohols, ketones, aldehydes, or precursors thereof under the processing conditions. The process described herein allows the use of biomass for the production of renewable fuels, as well as obtaining a biocrude with a yield greater than or equal to 30%, with a calorific value between 20 and 35 MJ/Kg and with a sulfur percentage lower than 1% w/w.