Provided is a continuous process for converting waste plastic into recycle for polyethylene polymerization. In one embodiment, the process comprises selecting waste plastics containing polyethylene and/or polypropylene and passing the waste plastics through a pyrolysis reactor to thermally crack at least a portion of the polyolefin waste and produce a pyrolyzed effluent. The pyrolyzed effluent is separated into offgas, a naphtha/diesel fraction, a heavy fraction, and char. The naphtha/diesel fraction is passed to a crude unit distillation column in a refinery where a straight run naphtha (C.sub.5-C.sub.8) fraction or a propane/butane (C.sub.3-C.sub.4) fraction is recovered. The straight run naphtha fraction (C.sub.5-C.sub.8) or the propane/butane (C.sub.3-C.sub.4) fraction is passed to a steam cracker for ethylene production. The heavy fraction from the pyrolysis unit can also be passed to an isomerization dewaxing unit to produce a base oil.

The present invention discloses a process and an apparatus for conversion of waste plastic pyrolysis oil into value added products, wherein, the pyrolysis oil is produced from waste plastics by utilizing HCGO as a preheating stream. The process and apparatus as disclosed improves the conventional DCU process in terms of liquid, gaseous yields and reduction in coke yields and without disturbing the hardware of the conventional process along with energy efficient production of pyrolysis oil. The present process and apparatus include a delayed coking process and a system for the delayed coking process which involves the integration of delayed coking system with pyrolysis section and utilization of produced pyrolysis oil by co-processing it with residual heavy hydrocarbon feedstock.

A method for upgrading pyrolysis oil includes contacting a pyrolysis oil feed with hydrogen in the presence of a mixed metal oxide catalyst in a first slurry reactor, where: the pyrolysis oil feed comprises multi-ring aromatic compounds comprising greater than or equal to sixteen carbon atoms, and contacting the pyrolysis oil feed with hydrogen in the presence of the mixed metal oxide catalyst in the first slurry reactor to convert at least a portion of the multi-ring aromatic compounds in the pyrolysis oil feed to light aromatic compounds comprising di-aromatic compounds, tri-aromatic compounds, or both, passing an intermediate stream comprising the light aromatic compounds to a second slurry reactor downstream of the first slurry reactor; and contacting the intermediate stream with hydrogen in the presence of a mesoporous zeolite supported metal catalyst in a second slurry reactor.

The invention relates to producing upgraded renewable oil. Renewable crude oil is provided whose oxygen content, water content, and total acid number are within predetermined ranges. Respective fractions of the oil have boiling points below 350° C. and above 450° C. After the oil is pressurized, and hydrogen is added, the mixture is heated and contacted with a heterogeneous catalyst in a first reaction zone with weight based hourly space velocity (WHSV) of 0.1 to 1 h-1. The resultant partially hydrogenated and deoxygenated oil is further heated and contacted with a heterogeneous catalyst in a second reaction zone at WHSV of 0.1 to 1.5 h-1. Low and high boiling point liquid hydrocarbon fractions of the product of the second reaction zone are sent to third and fourth reaction zones, respectively, to be contacted with hydrogen and a heterogeneous catalyst under respective heating conditions and WHSV of 0.1 to 1 h-1.

Provided are novel process for upgrading naphtha and increasing the yield of reformate. Olefinic naphtha and light paraffins are combined and fed to a catalytic fluidized bed reactor maintained at a temperature about 775° F. and about 1250° F. and an operating pressure between about 10 psig and about 500 psig to produce a product comprising at least 1 wt. % higher C.sub.5+ hydrocarbon than the combined feed and at least 55 wt. % aromatics.

In some examples, hydrocarbon feed and a diluent such as steam are mixed, and heated. A vapor phase product and a liquid phase product can be separated from the heated mixture. The liquid phase product can be hydroprocessed to produce a first hydroprocessed product. A pitch and one or more hydrocarbon products can be separated from the first hydroprocessed product. The pitch can be contacted with a diluent to produce a pitch-diluent mixture. The pitch-diluent mixture can be hydroprocessed to produce a second hydroprocessed product. A hydroprocessor heavy product and a utility fluid product can be separated from the second hydroprocessed product. The diluent can be or include at least a portion of the utility fluid product. The vapor phase product can be steam cracked to produce a steam cracker effluent. A tar product and a process gas that can include ethylene and propylene can be separated from the steam cracker effluent.

A supercritical water separation process and system is disclosed for the removal of metals, minerals, particulate, asphaltenes, and resins from a contaminated organic material. The present invention takes advantage of the physical and chemical properties of supercritical water to effect the desired separation of contaminants from organic materials and permit scale-up. At a temperature and pressure above the critical point of water (374° C., 22.1 MPa), nonpolar organic compounds become miscible in supercritical water (SCW) and polar compounds and asphaltenes become immiscible. The process and system disclosed continuously separates immiscible contaminants and solids from the supercritical water and clean oil product solution. The present invention creates a density gradient that enables over 95% recovery of clean oil and over 99% reduction of contaminants such as asphaltenes and particulate matter depending on the properties of the contaminated organic material.

Multi-metallic bulk catalysts and methods for synthesizing the same are provided. The multi-metallic bulk catalysts contain nickel, molybdenum tungsten, niobium, and optionally, titanium and/or copper. The catalysts are useful for hydroprocessing, particularly hydrodesulfurization and hydrodenitrogenation, of hydrocarbon feedstocks.

The present technology relates to hydrocarbon fuels comprising renewable content. More particularly, the technology relates to manufacture of renewable diesel for potential use as aviation turbine fuel blendstock.

A multi-stage process for the production of an ISO 8217 compliant Product Heavy Marine Fuel Oil from ISO 8217 compliant Feedstock Heavy Marine Fuel Oil involving a Reaction System composed of one or more reactor vessels selected from a group reactor wherein said one or more reactor vessels contains one or more reaction sections configured to promote the transformation of the Feedstock Heavy Marine Fuel Oil to the Product Heavy Marine Fuel Oil. The Product Heavy Marine Fuel Oil has a Environmental Contaminate level has a maximum sulfur content (ISO 14596 or ISO 8754) between the range of 0.05 mass % to 1.0 mass. A process plant for conducting the process for conducting the process is disclosed that can utilize a modular reactor vessel.