Provided are an apparatus and a method for refining pyrolysis oil in which a dechlorination reaction is performed at a first temperature under a first hydrotreating catalyst, denitrification reaction is performed at a second temperature higher than the first temperature under a second hydrotreating catalyst, and chlorine adsorption by an adsorbent is performed after the dechlorination reaction, thereby preventing production of an ammonium salt (NH.sub.4Cl), and providing refined oil which is excellent in prevention of corrosion of a reactor, improvement of durability, occurrence of differential pressure, and process efficiency, has very low contents of impurities such as chlorine, nitrogen, and metal and olefin, and has excellent quality.

A multi-stage process for the production of an ISO 8217 compliant Product Heavy Marine Fuel Oil from ISO 8217 compliant Feedstock Heavy Marine Fuel Oil involving a Reaction System composed of one or more reactor vessels selected from a group reactor wherein said one or more reactor vessels contains one or more reaction sections configured to promote the transformation of the Feedstock Heavy Marine Fuel Oil to the Product Heavy Marine Fuel Oil. The Product Heavy Marine Fuel Oil has a Environmental Contaminate level has a maximum sulfur content (ISO 14596 or ISO 8754) between the range of 0.05 mass % to 1.0 mass. A process plant for conducting the process for conducting the process is disclosed that can utilize a modular reactor vessel.

The present disclosure provides an automatic separation apparatus for four fractions of heavy oil and a separation method thereof, wherein the apparatus includes a solvent reservoir tank (1), a separation unit for four fractions of heavy oil (100) and a receiving apparatus (9). The separation unit for four fractions of heavy oil (100) includes: a filter disc (4) having one end in communication with the solvent reservoir tank (1), and the other end in communication with an inlet of a pre-column flow path switching valve (5); a chromatographic column (6) having an inlet in communication with an outlet of the pre-column flow path switching valve (5), and an outlet in communication with an inlet of a post-column flow path switching valve (8). The receiving apparatus is in communication with an outlet of the post-column flow path switching valve (8).

Provided is a mercury adsorbent that can efficiently adsorb and remove mercury and/or a mercury compound contained in a liquid hydrocarbon and can suppress corrosive action even when used for a long time. The mercury adsorbent comprises an activated carbon including a mineral acid supported thereon, the activated carbon having a specific surface area of 1000 m.sup.2/g or larger and a volume of micropores of 80 cm.sup.3/g or larger, each of the micropores having a pore radius of 8 Å or smaller, and the mercury adsorbent has a moisture content of from 0.1 to 3 wt %.

The invention describes a mass for scavenging mercaptans which is particularly suitable for the treatment of olefinic gasoline cuts containing sulfur such as gasolines resulting from catalytic cracking. The scavenging mass comprises an active phase based on group VIII, IB or IIB metal particles which is prepared by a step of bringing a porous support into contact with a metal salt of said group VIII, IB or IIB metal and a step heating the resulting mixture to a temperature above the melting point of said metal salt. The invention also relates to a process for using said scavenging mass for the adsorption of mercaptans.

A system for upgrading heavy hydrocarbon feeds, such as crude oil, include a hydrotreating unit, a hydrotreated effluent separation system, a solvent-assisted adsorption system, and a hydrocracking unit. Processes for upgrading heavy hydrocarbon feeds include hydrotreating the hydrocarbon feed to produce a hydrotreated effluent that includes asphaltenes, separating the hydrotreated effluent into a lesser boiling hydrotreated effluent and a greater boiling hydrotreated effluent comprising the asphaltenes, combining the greater boiling hydrotreated effluent with a light paraffin solvent to produce a combined stream, adsorbing the asphaltenes from the combined stream to produce an adsorption effluent, and hydrocracking the lesser boiling hydrotreated effluent and at least a portion of the adsorption effluent to produce a hydrocracked effluent with hydrocarbons boiling less than 180° C. The systems and processes increase the hydrocarbon conversion and yield of hydrocarbons boiling less than 180° C.

Hydrocracked bottoms fractions are treated to separate HPNA compounds and/or HPNA precursor compounds and produce a reduced-HPNA hydrocracked bottoms fraction effective for recycle. A process for separation of HPNA and/or HPNA precursor compounds from a hydrocracked bottoms fraction of a hydroprocessing reaction effluent comprises contacting the hydrocracked bottoms fraction with heteropoly acid compounds to promote adsorption of HPNAs onto the heteropoly acids and to produce a heteropoly acid treated hydrocracked bottoms fraction, that is recycled within the hydrocracking operation.

The present invention relates to a sequential thermo-chemical treatment along with adsorption-based pre-treatment process for residual oils having a very high naphthenic acid content. First stage of the process is a thermal pre-treatment step which results into generation of hydrocarbon stream with a reduced naphthenic acid content due to high temperature. In second stage of pre-treatment, generated hydrocarbon stream from stage-1 is subjected to esterification reaction with alcohol, such as methanol, to further reduce the TAN of hydrocarbon stream. After recovery of alcohol from the reaction mixture, depending on TAN reduction required reaction mixture may be subjected to an adsorption stage, third stage pre-treatment, where an adsorbent mixture comprising of FCC spent catalyst is used to adsorb the TAN of feed hydrocarbon stream. The treated hydrocarbon stream is then co-processed with DCU feed stock for producing lighter hydrocarbons.

Disclosed are systems and methods for processing liquefied natural gas (LNG). A LNG production system may include a contaminant removal process with one or more sets of sorbent beds co-loaded with a metal sulfide sorbent and/or metal oxide sorbent. In some examples, the contaminant removal process may include one or more molecular sieve dehydrators co-loaded with a 3A or 4A sieve and a 3A or 4A sieve impregnated with silver. The one or more sets of sorbent beds may be arranged at various locations throughout the LNG production system including upstream of or downstream of heavy component removal beds having activated carbon. In some instances, the LNG production system may include a regeneration process for moving heated fluid, typically feed gas, through a first heavy component removal bed while maintaining other heavy component removal beds online to reduce downtime for the LNG production system, increase production efficiency, and decrease an amount of greenhouse gases released from defrost and flare-offs.

A metal trap for an FCC catalyst include pre-formed microspheres impregnated with an organic acid salt of a rare earth element.