Patent classifications
C10G3/42
Process for upgrading oxygen containing renewable oil
The invention relates to producing upgraded renewable oil. Renewable crude oil is provided whose oxygen content, water content, and total acid number are within predetermined ranges. Respective fractions of the oil have boiling points below 350° C. and above 450° C. After the oil is pressurized, and hydrogen is added, the mixture is heated and contacted with a heterogeneous catalyst in a first reaction zone with weight based hourly space velocity (WHSV) of 0.1 to 1 h-1. The resultant partially hydrogenated and deoxygenated oil is further heated and contacted with a heterogeneous catalyst in a second reaction zone at WHSV of 0.1 to 1.5 h-1. Low and high boiling point liquid hydrocarbon fractions of the product of the second reaction zone are sent to third and fourth reaction zones, respectively, to be contacted with hydrogen and a heterogeneous catalyst under respective heating conditions and WHSV of 0.1 to 1 h-1.
HYDROGEN REJECTION IN METHANOL TO HYDROCARBON PROCESS
The present application relates to a process for production of hydrocarbons comprising the steps of —converting a feed stream comprising alcohols, ethers or mixtures hereof over a metal-containing zeolite based catalyst, active in dehydrogenation of hydrocarbons, in a conversion step thereby obtaining a conversion effluent, —separating said effluent to obtain an aqueous process condensate stream, a liquid hydrocarbon stream and a gaseous stream, —removing part of the hydrogen formed in the conversion step, and recycling at least part of the gaseous and/or liquid hydrocarbon stream to the conversion step.
SELECTIVE PRODUCTION OF LIGHT SYNTHETIC GASOLINE
A production plant and a method for production of a synthetized gasoline product from a synthetic hydrocarbon mixture produced from a mixture of reactive oxygenates, the method including a. separating the synthetic hydrocarbon mixture in at least a light hydrocarbon fraction, and a higher boiling hydrocarbon fraction, wherein the higher boiling fraction comprises at least 70% of the molecules including 10 or more carbon atoms and less than 20% of the molecules comprising exactly 9 carbon atoms, b. directing at least an amount of said higher boiling hydrocarbon fraction as a hydrocracking feedstock to contact a material catalytically active in hydrocracking under effective hydrocracking conditions providing a hydrocracked hydrocarbon stream, wherein at least an amount of said hydrocracked hydrocarbon stream is combined with at least an amount of said light hydrocarbon fraction, to provide said synthetized gasoline product having a T.sub.90 being below T.sub.90 of said synthetic hydrocarbon mixture.
PROCESS FOR THE MANUFACTURE OF DIESEL RANGE HYDROCARBONS
The invention relates to a process for the manufacture of diesel range hydrocarbons wherein a feed is hydrotreated in a hydrotreating step and isomerised in an isomerisation step, and a feed comprising fresh feed containing more than 5 wt % of free fatty acids and at least one diluting agent is hydrotreated at a reaction temperature of 200-400° C., in a hydrotreating reactor in the presence of catalyst, and the ratio of the diluting agent/fresh feed is 5-30:1.
Preparation of a fuel blend
A method is disclosed for preparing a renewable fuel blend. The method includes subjecting at least two feedstocks of different biological origins to catalytic cracking in a catalytic cracking unit and to hydrotreatment in a hydrotreatment unit to form a fuel blend having an aromatic hydrocarbon content from 26 to 42 wt-% and a paraffinic hydrocarbon content of less than 53 wt-%, as measured according to ASTM D2425-04 (2011). The fuel blend is formed by mixing the at least two feedstocks together before subjecting them to the catalytic cracking and hydrotreatment, or by obtaining a first fuel component and at least one further fuel component from the catalytic cracking and hydrotreatment of the at least two feedstocks, and mixing the first fuel component and the at least one further fuel component together.
UPGRADING BIO-WASTE IN FCC
A method may include: providing bio waste stream wherein the bio waste stream comprises at least one bio waste selected from the group consisting of palm oil mill effluent, soapstock, and combinations thereof; introducing the bio waste effluent stream into a fluidized catalytic cracking unit; contacting the bio waste with a catalyst in the fluidized catalytic cacking unit; and cracking at least a portion of the bio waste stream to form cracked products that comprise a cracked product stream.
PROCESSES FOR REFINING BIOCOMPONENT FEEDSTOCK AND MINERAL HYDROCARBON FEEDSTOCK AND APPARATUS THEREOF
The present disclosure provides processes for refining hydrocarbon feedstocks and apparatus thereof. In at least one embodiment, a process includes hydroprocessing a mineral hydrocarbon feedstock in the presence of a first catalyst in a first reactor, and removing a first reactor effluent from the first reactor. The process includes hydroprocessing a biocomponent feedstock in the presence of a second catalyst in a second reactor, and removing a second reactor effluent from the second reactor. The process includes mixing the first reactor effluent and the second reactor effluent to form a mixture. The process includes introducing the mixture to a separation unit to form a fuel product. In at least one embodiment, an apparatus includes a first hydroprocess reactor. The apparatus includes a second hydroprocess reactor coupled with the first hydroprocess reactor. The apparatus includes a separation unit coupled with the second hydroprocess reactor.
PROCESS FOR MANUFACTURING ORGANIC CHEMICALS AND/OR DISTILLATE HYDROCARBON FUELS FROM WASTE TEXTILES
The present disclosure relates to a process for manufacturing organic chemicals and/or distillate hydrocarbon fuels from waste textiles comprising cellulosic fibers, wherein the process includes providing waste textiles comprising cellulosic fibers, processing the waste textiles into an aqueous slurry of comminuted waste textiles, saccharification of the comminuted waste textiles into monomer sugars in the presence of a catalyst; and processing the monomer sugars into organic chemicals and/or distillate hydrocarbon fuels.
RENEWABLE HYDROCARBON COMPOSITION HAVING GOOD CETANE NUMBER AND GOOD COLD PROPERTIES
A renewable hydrocarbon composition as disclosed includes monobranched isoparaffins, dibranched isoparaffins, tribranched isoparaffins multibranched isoparaffins, and n-paraffins, having carbon numbers from C8 to C30. Said renewable hydrocarbon composition has high cetane number and excellent cold properties. The renewable hydrocarbon composition can be used as diesel fuel or as a diesel fuel component.
RENEWABLE CHEMICAL PRODUCTION ENGAGING METATHESIS AND MICROBIAL OXIDATION
A process for combined renewable 1-decene and renewable carboxylic diacid production from a fatty acid ester containing feedstock, wherein the feedstock is first subjected to metathesis reaction conditions, recovery of 1-decene and then to microbial oxidation to yield diacids in a fermentation broth. Diacids of unusual carbon chains lengths are thereby obtainable.