The present invention addresses to obtaining a support of hydrorefining catalysts by an innovative preparation route that reduces the problem of loss (or leaching) of boron over the operating time of industrial units. As the presence of boron in catalysts contributes to increased activity (hydrogenating and acidic) and stability for the hydrorefining reactions (hydrotreating and hydrocracking), its maintenance in the catalyst guarantees the preservation of the properties in operation, throughout the entire cycle of campaign of industrial units.

The present invention addresses to obtaining a support of hydrorefining catalysts by an innovative preparation route that reduces the problem of loss (or leaching) of boron over the operating time of industrial units. As the presence of boron in catalysts contributes to increased activity (hydrogenating and acidic) and stability for the hydrorefining reactions (hydrotreating and hydrocracking), its maintenance in the catalyst guarantees the preservation of the properties in operation, throughout the entire cycle of campaign of industrial units.

A process for hydroprocessing a hydrocarbon feed of the present disclosure includes contacting the hydrocarbon feed with hydrogen in the presence of at least one hydroprocessing catalyst in a two-phase hydroprocessing unit, where the at least one hydroprocessing catalyst is a solid catalyst and contacting produces a hydroprocessed effluent having a reduced concentration of one or more of metals, nitrogen, sulfur, aromatic compounds, or combinations of these. The process further includes combining the hydroprocessed effluent with make-up hydrogen downstream of the two-phase hydroprocessing unit to produce a hydrogen saturated hydroprocessed effluent, separating the hydrogen saturated hydroprocessed effluent in a separation system to produce a hydrogen-saturated high-pressure bottom stream, a hydroprocessed product stream, and a gaseous effluent, and passing at least a portion of the hydrogen-saturated high-pressure bottom stream back to the two-phase hydroprocessing unit.

A process for hydroprocessing a hydrocarbon feed of the present disclosure includes contacting the hydrocarbon feed with hydrogen in the presence of at least one hydroprocessing catalyst in a two-phase hydroprocessing unit, where the at least one hydroprocessing catalyst is a solid catalyst and contacting produces a hydroprocessed effluent having a reduced concentration of one or more of metals, nitrogen, sulfur, aromatic compounds, or combinations of these. The process further includes combining the hydroprocessed effluent with make-up hydrogen downstream of the two-phase hydroprocessing unit to produce a hydrogen saturated hydroprocessed effluent, separating the hydrogen saturated hydroprocessed effluent in a separation system to produce a hydrogen-saturated high-pressure bottom stream, a hydroprocessed product stream, and a gaseous effluent, and passing at least a portion of the hydrogen-saturated high-pressure bottom stream back to the two-phase hydroprocessing unit.

A multi-stage process for the production of an ISO 8217 compliant Product Heavy Marine Fuel Oil from ISO 8217 compliant Feedstock Heavy Marine Fuel Oil involving a Reaction System composed of one or more reactor vessels selected from a group reactor wherein said one or more reactor vessels contains one or more reaction sections configured to promote the transformation of the Feedstock Heavy Marine Fuel Oil to the Product Heavy Marine Fuel Oil. The Product Heavy Marine Fuel Oil has a Environmental Contaminate level has a maximum sulfur content (ISO 14596 or ISO 8754) between the range of 0.05 mass % to 1.0 mass. A process plant for conducting the process for conducting the process is disclosed that can utilize a modular reactor vessel.

A multi-stage process for the production of an ISO 8217 compliant Product Heavy Marine Fuel Oil from ISO 8217 compliant Feedstock Heavy Marine Fuel Oil involving a Reaction System composed of one or more reactor vessels selected from a group reactor wherein said one or more reactor vessels contains one or more reaction sections configured to promote the transformation of the Feedstock Heavy Marine Fuel Oil to the Product Heavy Marine Fuel Oil. The Product Heavy Marine Fuel Oil has a Environmental Contaminate level has a maximum sulfur content (ISO 14596 or ISO 8754) between the range of 0.05 mass % to 1.0 mass. A process plant for conducting the process for conducting the process is disclosed that can utilize a modular reactor vessel.

Generally, it is disclosed a catalyst for use in a hydrotreating hydrocarbon feedstocks and the method of making such catalyst. It is generically provided that the catalyst comprises at least one Group VIB metal component, at least one Group VIII metal component, about (1) to (about (30) wt % C, and preferably about (1) to about (20) wt % C, and more preferably about (5) to about 15 wt % C of one or more sulfur containing organic additive and a titanium-containing carrier component, wherein the amount of the titanium component is in the range of about (3) to (about (60) wt %, expressed as an oxide (Ti0.sub.2) and based on the total weight of the catalyst. The titanium-containing carrier is formed by co-extruding or precipitating a titanium source with a Al203 precursor to form a porous support material comprising Al.sub.20.sub.3 or by impregnating a titanium source onto a porous support material comprising Al.sub.20.sub.3.

A highly active hydroprocessing catalyst that comprises an inorganic oxide support particle having been impregnated with a metals-impregnation solution comprising a complexing agent and a hydrogenation metal that is further incorporated with an organic additive blend.

A multi-stage process for the production of an ISO 8217 Table 2 residual marine fuel Product Heavy Marine Fuel Oil from a Feedstock Heavy Marine Fuel Oil that is ISO 8217:2017 Table 2 compliant except for the Environmental Contaminants involves a Reaction System composed of one or more reactor vessels selected from a group reactor wherein said one or more reactor vessels contains one or more reaction sections configured to promote the transformation of the Feedstock Heavy Marine Fuel Oil to the Product Heavy Marine Fuel Oil. The Product Heavy Marine Fuel Oil has an Environmental Contaminant level less than 0.5 wt % and preferably a maximum sulfur content (ISO 14596 or ISO 8754) between the range of 0.05 mass % to 0.5 mass %. A process plant for conducting the process for conducting the process is also disclosed.

Embodiments of the present disclosure are directed to a process for modifying catalysts comprising introducing a precursor agent and hydrogen gas to a conversion reactor; contacting the precursor agent with a conversion catalyst in the conversion reactor, thereby producing an active agent; introducing the active agent to a production reactor; and contacting the active agent with a hydroprocessing catalyst in the production reactor, thereby producing a modified hydroprocessing catalyst.