Herein disclosed is a method of producing value-added product from light gases, the method comprising: (a) providing light gases comprising at least one compound selected from the group consisting of C1-C6 compounds and combinations thereof; (b) intimately mixing the light gases with a liquid carrier in a high shear device to form a dispersion of gas in the liquid carrier, wherein the dispersion is supersaturated with the light gases and comprises gas bubbles at least some of which have a mean diameter of less than or equal to about 5 micron(s); (c) allowing the value-added product to form and utilizing vacuum to extract unreacted light gases from the liquid carrier; (d) extracting the value-added product; wherein the value-added product comprises at least one component selected from the group consisting of higher hydrocarbons, hydrogen, olefins, alcohols, aldehydes, and ketones. A system for producing value-added product from light gases is also disclosed.

Herein disclosed is a method of producing value-added product from light gases, the method comprising: (a) providing light gases comprising at least one compound selected from the group consisting of C1-C6 compounds and combinations thereof; (b) intimately mixing the light gases with a liquid carrier in a high shear device to form a dispersion of gas in the liquid carrier, wherein the dispersion is supersaturated with the light gases and comprises gas bubbles at least some of which have a mean diameter of less than or equal to about 5 micron(s); (c) allowing the value-added product to form and utilizing vacuum to extract unreacted light gases from the liquid carrier; (d) extracting the value-added product; wherein the value-added product comprises at least one component selected from the group consisting of higher hydrocarbons, hydrogen, olefins, alcohols, aldehydes, and ketones. A system for producing value-added product from light gases is also disclosed.

Nonabsorptive presulfided catalyst particles are provided which are coated with a suitable coating material such as paraffinic oil/wax, or a suitable polymer material, to prevent water adsorption on the catalyst particles.

Provided is a structured catalyst for hydrodesulfurization that suppresses the decline in catalytic activity and achieves efficient hydrodesulfurization. The structured catalyst for hydrodesulfurization (1) includes a support (10) of a porous structure composed of a zeolite-type compound, and at least one catalytic substance (20) present in the support (10), the support (10) having channels (11) connecting with each other, and the catalytic substance (20) being present at least in the channels (11) of the support (10).

Provided is a structured catalyst for hydrodesulfurization that suppresses the decline in catalytic activity and achieves efficient hydrodesulfurization. The structured catalyst for hydrodesulfurization (1) includes a support (10) of a porous structure composed of a zeolite-type compound, and at least one catalytic substance (20) present in the support (10), the support (10) having channels (11) connecting with each other, and the catalytic substance (20) being present at least in the channels (11) of the support (10).

A catalytic cracking gasoline prehydrogenation method is provided. Thiol etherification and double bond isomerization reactions are carried out on catalytic cracking gasoline through a prehydrogenation reactor. The reaction conditions are as follows: the reaction temperature is between 80° C. and 160° C., the reaction pressure is between 1 MPa and 5 MPa, the liquid-volume hourly space velocity is from 1 to 10 h.sup.−1, and the hydrogen-oil volume ratio is (3-8):1; a prehydrogenation catalyst comprises a carrier and active ingredients, the carrier contains an aluminium oxide composite carrier with a macroporous structure and one or more of ZSM-5, ZSM-11, ZSM-12, ZSM-35, mordenite, amorphous form aluminum silicon, SAPO-11, MCM-22, a Y molecular sieve and a beta molecular sieve, the surface of the carrier is loaded with one or more of the active ingredients cobalt, molybdenum, nickel and tungsten; based on oxides, the content of the active ingredients is between 0.1% and 15.5%.

A catalytic cracking gasoline prehydrogenation method is provided. Thiol etherification and double bond isomerization reactions are carried out on catalytic cracking gasoline through a prehydrogenation reactor. The reaction conditions are as follows: the reaction temperature is between 80° C. and 160° C., the reaction pressure is between 1 MPa and 5 MPa, the liquid-volume hourly space velocity is from 1 to 10 h.sup.−1, and the hydrogen-oil volume ratio is (3-8):1; a prehydrogenation catalyst comprises a carrier and active ingredients, the carrier contains an aluminium oxide composite carrier with a macroporous structure and one or more of ZSM-5, ZSM-11, ZSM-12, ZSM-35, mordenite, amorphous form aluminum silicon, SAPO-11, MCM-22, a Y molecular sieve and a beta molecular sieve, the surface of the carrier is loaded with one or more of the active ingredients cobalt, molybdenum, nickel and tungsten; based on oxides, the content of the active ingredients is between 0.1% and 15.5%.

A process is disclosed for producing distillate range hydrocarbons using MTW and/or SSZ-41x catalysts.

The invention provides a process for the preparation of an olefinic product, comprising: (a) reacting an oxygenate feedstock, in a reaction zone in the presence of a molecular sieve catalyst, at a temperature from 350 to 1000° C., to produce a reaction effluent stream, comprising at least oxygenate, olefin, water and acidic by-products; (b) cooling the reaction effluent stream by means of an indirect heat exchange to a temperature greater than the dew point temperature of reaction effluent stream; (c) further rapidly cooling the reaction effluent stream to a temperature lower than the dew point temperature of the reaction effluent stream by direct injection of an aqueous liquid into the reaction effluent stream, to form a first quench effluent stream; and (d) separating the first quench effluent stream into a first liquid quench effluent stream and a first gaseous quench effluent stream, comprising the olefinic product.

The invention provides a process for the preparation of an olefinic product, comprising: (a) reacting an oxygenate feedstock, in a reaction zone in the presence of a molecular sieve catalyst, at a temperature from 350 to 1000° C., to produce a reaction effluent stream, comprising at least oxygenate, olefin, water and acidic by-products; (b) cooling the reaction effluent stream by means of an indirect heat exchange to a temperature greater than the dew point temperature of reaction effluent stream; (c) further rapidly cooling the reaction effluent stream to a temperature lower than the dew point temperature of the reaction effluent stream by direct injection of an aqueous liquid into the reaction effluent stream, to form a first quench effluent stream; and (d) separating the first quench effluent stream into a first liquid quench effluent stream and a first gaseous quench effluent stream, comprising the olefinic product.