Patent classifications
C10G45/36
METHOD OF PRODUCING PYROLYSIS PRODUCTS FROM A MIXED PLASTICS STREAM AND INTEGRATION OF THE SAME IN A REFINERY
Method of producing pyrolysis products from mixed plastics along with an associated system for processing mixed plastics. The method includes conducting pyrolysis of a plastic feedstock to produce plastic pyrolysis oil; feeding the plastic pyrolysis oil to a first fractionator to separate the plastic pyrolysis oil into a distillate fraction including naphtha and diesel and a vacuum gas oil fraction; and feeding the distillate fraction to a three step hydrotreating operation. The three step hydrotreating operation includes feeding the distillate fraction to a first hydrotreating unit to remove di-olefins to produce a first product stream, feeding the first product stream to a second hydrotreating unit to remove mono-olefins to produce a second product stream; and feeding the second product stream to a third hydrotreating unit to remove sulfur and nitrogen by hydrodesulfurization and hydrodenitrogenation to produce a third product stream. Such system may be integrated with a conventional refinery.
METHOD OF PRODUCING PYROLYSIS PRODUCTS FROM A MIXED PLASTICS STREAM AND INTEGRATION OF THE SAME IN A REFINERY
Method of producing pyrolysis products from mixed plastics along with an associated system for processing mixed plastics. The method includes conducting pyrolysis of a plastic feedstock to produce plastic pyrolysis oil; feeding the plastic pyrolysis oil to a first fractionator to separate the plastic pyrolysis oil into a distillate fraction including naphtha and diesel and a vacuum gas oil fraction; and feeding the distillate fraction to a three step hydrotreating operation. The three step hydrotreating operation includes feeding the distillate fraction to a first hydrotreating unit to remove di-olefins to produce a first product stream, feeding the first product stream to a second hydrotreating unit to remove mono-olefins to produce a second product stream; and feeding the second product stream to a third hydrotreating unit to remove sulfur and nitrogen by hydrodesulfurization and hydrodenitrogenation to produce a third product stream. Such system may be integrated with a conventional refinery.
METHOD FOR PREPARING A CATALYST CONTAINING AN ACTIVE NICKEL PHASE DISTRIBUTED IN A SHELL AND A NICKEL-COPPER ALLOY
A process for preparing a catalyst comprising nickel and copper, comprising the following steps: impregnating the porous support with a volume of a butanol solution of between 0.2 and 0.8 times the total pore volume of the support; maturing the impregnated porous support for 0.5 to 40 hours; impregnating the matured impregnated support with a solution comprising a precursor of the nickel active phase; impregnating the support with a solution containing a copper precursor and a nickel precursor.
METHOD FOR PREPARING A CATALYST COMPRISING AN ACTIVE NICKEL PHASE DISTRIBUTED IN A SHELL
A process for preparing a catalyst comprising an active phase based on nickel and an alumina support, which process comprises the following steps: a) said support is impregnated with a volume V1 of a butanol solution of between 0.2 and 0.8 times the total pore volume TPV of said support in order to obtain an impregnated support; b) the impregnated support obtained at the end of step a) is left to mature for 0.5 to 40 hours; c) the matured impregnated support obtained at the end of step b) is impregnated with a solution comprising at least one precursor of the nickel active phase in order to obtain a catalyst precursor; d) the catalyst precursor obtained at the end of step c) is dried at a temperature below 250° C.
Method for selective hydrogenation using a catalyst containing copper and at least one metal selected from between nickel or cobalt
The invention relates to a method for selective hydrogenation of a hydrocarbon feedstock that contains at least 2 carbon atoms per molecule and that has a final boiling point that is less than or equal to 250° C. and that comprises at least one polyunsaturated compound, in which in the presence of hydrogen, said feedstock is brought into contact with at least one catalyst that comprises a substrate and an active metal phase deposited on said substrate; said active metal phase comprises copper and at least one metal that is selected from between nickel and cobalt in a molar ratio of Cu:(Ni and/or Co) of greater than 1.
Method for selective hydrogenation using a catalyst containing copper and at least one metal selected from between nickel or cobalt
The invention relates to a method for selective hydrogenation of a hydrocarbon feedstock that contains at least 2 carbon atoms per molecule and that has a final boiling point that is less than or equal to 250° C. and that comprises at least one polyunsaturated compound, in which in the presence of hydrogen, said feedstock is brought into contact with at least one catalyst that comprises a substrate and an active metal phase deposited on said substrate; said active metal phase comprises copper and at least one metal that is selected from between nickel and cobalt in a molar ratio of Cu:(Ni and/or Co) of greater than 1.
Process for the production of a gasoline with a low sulfur content
This invention relates to a process for treatment of a gasoline that comprises diolefins, olefins and sulfur-containing compounds including mercaptans, consisting of a stage for treatment of the gasoline in a distillation column (2) comprising at least one reaction zone (3) including at least one catalyst that makes it possible to carry out the addition of mercaptans to the olefins that are contained in the gasoline that distills toward the top of the catalytic column.
Process for the production of a gasoline with a low sulfur content
This invention relates to a process for treatment of a gasoline that comprises diolefins, olefins and sulfur-containing compounds including mercaptans, consisting of a stage for treatment of the gasoline in a distillation column (2) comprising at least one reaction zone (3) including at least one catalyst that makes it possible to carry out the addition of mercaptans to the olefins that are contained in the gasoline that distills toward the top of the catalytic column.
CATALYST COMPRISING AN ACTIVE NICKEL PHASE IN THE FORM OF SMALL PARTICLES DISTRIBUTED IN A SHELL AND A NICKEL-COPPER ALLOY
Nickel and copper catalyst, and an alumina support: nickel distributed both in the core of and on a crust at the periphery of the support, crust thickness being 2% to 15% of catalyst diameter; nickel density ratio between the crust and the core greater than 3; crust contains more than 25% by weight of nickel element relative to total weight of nickel in the catalyst; mole ratio between nickel and copper is 0.5 to 5, at least one portion of nickel and copper is a nickel-copper alloy; nickel content in the nickel-copper alloy is 0.5% to 15% by weight of nickel element relative to total weight of the catalyst; size of the nickel particles in the catalyst is less than 7 nm.
CATALYST COMPRISING AN ACTIVE NICKEL PHASE IN THE FORM OF SMALL PARTICLES DISTRIBUTED IN A SHELL AND A NICKEL-COPPER ALLOY
Nickel and copper catalyst, and an alumina support: nickel distributed both in the core of and on a crust at the periphery of the support, crust thickness being 2% to 15% of catalyst diameter; nickel density ratio between the crust and the core greater than 3; crust contains more than 25% by weight of nickel element relative to total weight of nickel in the catalyst; mole ratio between nickel and copper is 0.5 to 5, at least one portion of nickel and copper is a nickel-copper alloy; nickel content in the nickel-copper alloy is 0.5% to 15% by weight of nickel element relative to total weight of the catalyst; size of the nickel particles in the catalyst is less than 7 nm.