Patent classifications
C10G47/30
Configuration for olefins production
Processes herein may be used to thermally crack various hydrocarbon feeds, and may eliminate the refinery altogether while making the crude to chemicals process very flexible in terms of crude. In embodiments herein, crude is progressively separated into at least light and heavy fractions. Depending on the quality of the light and heavy fractions, these are routed to one of three upgrading operations, including a fixed bed hydroconversion unit, a fluidized catalytic conversion unit, or a residue hydrocracking unit that may utilize an ebullated bed reactor. Products from the upgrading operations may be used as feed to a steam cracker.
Configuration for olefins production
Processes herein may be used to thermally crack various hydrocarbon feeds, and may eliminate the refinery altogether while making the crude to chemicals process very flexible in terms of crude. In embodiments herein, crude is progressively separated into at least light and heavy fractions. Depending on the quality of the light and heavy fractions, these are routed to one of three upgrading operations, including a fixed bed hydroconversion unit, a fluidized catalytic conversion unit, or a residue hydrocracking unit that may utilize an ebullated bed reactor. Products from the upgrading operations may be used as feed to a steam cracker.
Overpressure protection in hot high pressure processing systems in multi-stage up-flow reactor systems
The invention relates to an improved system and method for relief of hot, high pressure, fouling fluid from the 1.sup.st Stage Reactor and the ISS in case of an unintended overpressure situation while allowing the quick establishing of normal fluid flow path once the overpressure situation has been corrected. This allows for rapid cooling of all subsequent reactor stages while minimizing VGO slop generation that needs reprocessing.
Compositions and methods of using fine mineral matter as a catalyst for chemical recycling
The presently disclosed embodiments relate to the utilization of coal-derived fine mineral matter in chemical recycling of plastics or of solid mixed plastic waste. The instantly disclosed mineral based catalyst benefits the processes of catalytic cracking, gasification and steam reforming to maximize carbon utilization and production of plastics of original quality from recycled or renewable feedstocks while reducing the plastic pollution in the environment. The catalyst can be based on inorganic fine mineral matter, a natural ancient mineral mixture found in coal deposits and containing a plurality of transition metals, such as iron, copper, and manganese, as well as calcium, barium, magnesium, potassium, sodium, which can act as co-catalysts. Addition of the catalyst can convert plastic to syngas at a faction of the energy of conventional technologies.
Compositions and methods of using fine mineral matter as a catalyst for chemical recycling
The presently disclosed embodiments relate to the utilization of coal-derived fine mineral matter in chemical recycling of plastics or of solid mixed plastic waste. The instantly disclosed mineral based catalyst benefits the processes of catalytic cracking, gasification and steam reforming to maximize carbon utilization and production of plastics of original quality from recycled or renewable feedstocks while reducing the plastic pollution in the environment. The catalyst can be based on inorganic fine mineral matter, a natural ancient mineral mixture found in coal deposits and containing a plurality of transition metals, such as iron, copper, and manganese, as well as calcium, barium, magnesium, potassium, sodium, which can act as co-catalysts. Addition of the catalyst can convert plastic to syngas at a faction of the energy of conventional technologies.
METHOD FOR PRODUCING LIGHT AROMATIC
A method for producing light aromatics, includes the steps of: i) contacting a feedstock comprising heavy aromatic(s) with a catalyst in a fluidized reactor for aromatics lightening reaction in the presence of hydrogen to obtain a product rich in C6-C8 light aromatic(s) and a spent catalyst, wherein the heavy aromatic is one or more selected from C9+ aromatics; ii) separating the resulted product rich in C6-C8 light aromatic(s) to obtain hydrogen, a non-aromatic component, C6-C8 light aromatic(s) and a C9+ aromatic component; and iii) recycling at least a part of the C9+ aromatic component to the fluidized reactor. The method has strong adaptability to feedstocks and high flexibility in operation and allows a long-period stable operation. The method can produce high-value light aromatics from heavy aromatics that are difficult to be treated and utilized.
Method for converting residues incorporating deep hydroconversion steps and a deasphalting step
The invention concerns a method for converting heavy hydrocarbon feedstocks of which at least 50% by weight boils at a temperature of at least 300° C., and in particular vacuum residues. The feedstocks are subjected to a first step a) of deep hydroconversion, optionally followed by a step b) of separating a light fraction, and a heavy residual fraction is obtained from step b) of which at least 80% by weight has a boiling temperature of at least 250° C. Said fraction from step b) or the effluent from step a) is then subjected to a second step c) of deep hydroconversion. The overall hourly space velocity for steps a) to c) is less than 0.1 h.sup.−1. The effluent from step c) is fractionated to separate a light fraction. The heavy fraction obtained, of which 80% by weight boils at a temperature of at least 300° C., is sent to a deasphalting step e). The deasphalted fraction DAO is then preferably converted in a step f) chosen from ebullated bed hydroconversion, fluidised bed catalytic cracking and fixed bed hydrocracking.
Method for converting residues incorporating deep hydroconversion steps and a deasphalting step
The invention concerns a method for converting heavy hydrocarbon feedstocks of which at least 50% by weight boils at a temperature of at least 300° C., and in particular vacuum residues. The feedstocks are subjected to a first step a) of deep hydroconversion, optionally followed by a step b) of separating a light fraction, and a heavy residual fraction is obtained from step b) of which at least 80% by weight has a boiling temperature of at least 250° C. Said fraction from step b) or the effluent from step a) is then subjected to a second step c) of deep hydroconversion. The overall hourly space velocity for steps a) to c) is less than 0.1 h.sup.−1. The effluent from step c) is fractionated to separate a light fraction. The heavy fraction obtained, of which 80% by weight boils at a temperature of at least 300° C., is sent to a deasphalting step e). The deasphalted fraction DAO is then preferably converted in a step f) chosen from ebullated bed hydroconversion, fluidised bed catalytic cracking and fixed bed hydrocracking.
METHOD FOR PREPARING HIGH-QUALITY FUEL OIL AND/OR CHEMICAL RAW MATERIAL FROM BIOMASS PYROLYSIS LIQUID
A method for preparing a high-quality fuel oil and/or chemical raw material from a biomass pyrolysis liquid. In the method, a biomass pyrolysis liquid undergoes a hydrodeoxygenation reaction in a catalyst full mixing flow circulation system in a fluidized bed reactor to obtain deoxygenated oil, and the obtained deoxygenated oil undergoes a hydrocracking reaction in a fixed bed reactor to obtain high-quality fuel oil and/or a chemical raw material. The method may prevent the condensation and coking of a biomass pyrolysis liquid, solve the problem of rapid catalyst deactivation, and may convert a biomass pyrolysis liquid into a high-quality fuel oil that may be directly used by vehicles and into a chemical product.
METHOD FOR PREPARING HIGH-QUALITY FUEL OIL AND/OR CHEMICAL RAW MATERIAL FROM BIOMASS PYROLYSIS LIQUID
A method for preparing a high-quality fuel oil and/or chemical raw material from a biomass pyrolysis liquid. In the method, a biomass pyrolysis liquid undergoes a hydrodeoxygenation reaction in a catalyst full mixing flow circulation system in a fluidized bed reactor to obtain deoxygenated oil, and the obtained deoxygenated oil undergoes a hydrocracking reaction in a fixed bed reactor to obtain high-quality fuel oil and/or a chemical raw material. The method may prevent the condensation and coking of a biomass pyrolysis liquid, solve the problem of rapid catalyst deactivation, and may convert a biomass pyrolysis liquid into a high-quality fuel oil that may be directly used by vehicles and into a chemical product.