Patent classifications
C10G9/26
Method and apparatus for converting hydrocarbons into olefins
An apparatus and method are provided for processing hydrocarbon feeds. The method may pass a pyrolysis feed to a thermal pyrolysis reactor and expose at least a portion of the pyrolysis feed to high-severity operating conditions in a thermal pyrolysis reactor, wherein the thermal pyrolysis reactor is operated at operating conditions that include pressure ≧36 psig and provide a reactor product that has a C.sub.3+ to C.sub.2 unsaturate weight ratio ≦0.5.
Method and apparatus for converting hydrocarbons into olefins
An apparatus and method are provided for processing hydrocarbon feeds. The method may pass a pyrolysis feed to a thermal pyrolysis reactor and expose at least a portion of the pyrolysis feed to high-severity operating conditions in a thermal pyrolysis reactor, wherein the thermal pyrolysis reactor is operated at operating conditions that include pressure ≧36 psig and provide a reactor product that has a C.sub.3+ to C.sub.2 unsaturate weight ratio ≦0.5.
Reverse flow reactors having high purge efficiencies while containing asymmetric feeds, methods of using same, and pyrolysis products made from same
Reverse flow reactor (RFR) apparatuses exhibiting asymmetric feed profiles and improved purge mode efficiency, and methods of using same to transform a hydrocarbon feed into a pyrolysed hydrocarbon product are disclosed. The RFR apparatus includes an RFR body with a reaction zone having at least one bed. The RFR body has a central vertical axis and flanked by first and second void spaces. The method utilizes at least two oxygen-containing feeds, a combustion fuel feed, a purge feed, and a hydrocarbon pyrolysis feed. The RFR apparatus can cycle between an exothermic heating mode (heated to ≥700° C. while maintaining a pressure drop across the reaction zone of ≤100 kPag), a purge mode (purging oxygen using <6 bed volumes of purge gas to achieve a residual oxygen level of ≤20 ppm while maintaining a pressure drop of ≤35 kPag), and an endothermic pyrolysis mode (feeding pyrolysis hydrocarbons through the reaction zone to form pyrolysis products, while maintaining a pressure drop across the reaction zone of ≤70 kPag).
Reverse flow reactors having high purge efficiencies while containing asymmetric feeds, methods of using same, and pyrolysis products made from same
Reverse flow reactor (RFR) apparatuses exhibiting asymmetric feed profiles and improved purge mode efficiency, and methods of using same to transform a hydrocarbon feed into a pyrolysed hydrocarbon product are disclosed. The RFR apparatus includes an RFR body with a reaction zone having at least one bed. The RFR body has a central vertical axis and flanked by first and second void spaces. The method utilizes at least two oxygen-containing feeds, a combustion fuel feed, a purge feed, and a hydrocarbon pyrolysis feed. The RFR apparatus can cycle between an exothermic heating mode (heated to ≥700° C. while maintaining a pressure drop across the reaction zone of ≤100 kPag), a purge mode (purging oxygen using <6 bed volumes of purge gas to achieve a residual oxygen level of ≤20 ppm while maintaining a pressure drop of ≤35 kPag), and an endothermic pyrolysis mode (feeding pyrolysis hydrocarbons through the reaction zone to form pyrolysis products, while maintaining a pressure drop across the reaction zone of ≤70 kPag).
Reverse flow reactors having low maldistribution parameter while containing asymmetric feeds, methods of using same, and pyrolysis products made from same
Reverse flow reactor (RFR) apparatuses exhibiting asymmetric feed profiles and improved flow distribution during heating mode and/or pyrolysis mode operation, and methods of using same to transform a hydrocarbon feed into a pyrolysed hydrocarbon product are disclosed. The RFR apparatus includes an RFR body with a reaction zone having at least one bed. The RFR body has a central vertical axis and is flanked by first and second void spaces. The method utilizes at least two oxygen-containing feeds, a combustion fuel feed, a purge feed, and a hydrocarbon pyrolysis feed. The RFR apparatus can cycle between an exothermic heating mode (heated to ≥700° C. while maintaining a pressure drop across the reaction zone of ≤100 kPag), a purge mode (purging oxygen using <6 bed volumes of purge gas while maintaining a pressure drop of ≤35 kPag), and an endothermic pyrolysis mode (feeding pyrolysis hydrocarbons through the reaction zone to form pyrolysis products, while maintaining a pressure drop across the reaction zone of ≤70 kPag).
Hydrocarbon conversion
The invention relates to hydrocarbon conversion, to equipment and materials useful for hydrocarbon conversion, and to processes for carrying out hydrocarbon conversion, e.g., hydrocarbon pyrolysis processes. The hydrocarbon conversion is carried out in a reactor which includes at least one channeled member that comprises refractory and has an open frontal area≤55%. The refractory can include non-oxide ceramic.
Hydrocarbon conversion
The invention relates to hydrocarbon conversion, to equipment and materials useful for hydrocarbon conversion, and to processes for carrying out hydrocarbon conversion, e.g., hydrocarbon pyrolysis processes. The hydrocarbon conversion is carried out in a reactor which includes at least one channeled member that comprises refractory and has an open frontal area≤55%. The refractory can include non-oxide ceramic.
Reverse Flow Reactors Having Low Maldistribution Parameter While Containing Asymmetric Feeds, Methods of Using Same, and Pyrolysis Products Made from Same
Reverse flow reactor (RFR) apparatuses exhibiting asymmetric feed profiles and improved flow distribution during heating mode and/or pyrolysis mode operation, and methods of using same to transform a hydrocarbon feed into a pyrolysed hydrocarbon product are disclosed. The RFR apparatus includes an RFR body with a reaction zone having at least one bed. The RFR body has a central vertical axis and is flanked by first and second void spaces. The method utilizes at least two oxygen-containing feeds, a combustion fuel feed, a purge feed, and a hydrocarbon pyrolysis feed. The RFR apparatus can cycle between an exothermic heating mode (heated to ≥700° C. while maintaining a pressure drop across the reaction zone of ≤100 kPag), a purge mode (purging oxygen using <6 bed volumes of purge gas while maintaining a pressure drop of ≤35 kPag), and an endothermic pyrolysis mode (feeding pyrolysis hydrocarbons through the reaction zone to form pyrolysis products, while maintaining a pressure drop across the reaction zone of ≤70 kPag).
Reverse Flow Reactors Having Low Maldistribution Parameter While Containing Asymmetric Feeds, Methods of Using Same, and Pyrolysis Products Made from Same
Reverse flow reactor (RFR) apparatuses exhibiting asymmetric feed profiles and improved flow distribution during heating mode and/or pyrolysis mode operation, and methods of using same to transform a hydrocarbon feed into a pyrolysed hydrocarbon product are disclosed. The RFR apparatus includes an RFR body with a reaction zone having at least one bed. The RFR body has a central vertical axis and is flanked by first and second void spaces. The method utilizes at least two oxygen-containing feeds, a combustion fuel feed, a purge feed, and a hydrocarbon pyrolysis feed. The RFR apparatus can cycle between an exothermic heating mode (heated to ≥700° C. while maintaining a pressure drop across the reaction zone of ≤100 kPag), a purge mode (purging oxygen using <6 bed volumes of purge gas while maintaining a pressure drop of ≤35 kPag), and an endothermic pyrolysis mode (feeding pyrolysis hydrocarbons through the reaction zone to form pyrolysis products, while maintaining a pressure drop across the reaction zone of ≤70 kPag).
Reverse Flow Reactors Having High Purge Efficiencies While Containing Asymmetric Feeds, Methods of Using Same, and Pyrolysis Products Made from Same
Reverse flow reactor (RFR) apparatuses exhibiting asymmetric feed profiles and improved purge mode efficiency, and methods of using same to transform a hydrocarbon feed into a pyrolysed hydrocarbon product are disclosed. The RFR apparatus includes an RFR body with a reaction zone having at least one bed. The RFR body has a central vertical axis and flanked by first and second void spaces. The method utilizes at least two oxygen-containing feeds, a combustion fuel feed, a purge feed, and a hydrocarbon pyrolysis feed. The RFR apparatus can cycle between an exothermic heating mode (heated to ≥700° C. while maintaining a pressure drop across the reaction zone of ≤100 kPag), a purge mode (purging oxygen using <6 bed volumes of purge gas to achieve a residual oxygen level of ≤20 ppm while maintaining a pressure drop of ≤35 kPag), and an endothermic pyrolysis mode (feeding pyrolysis hydrocarbons through the reaction zone to form pyrolysis products, while maintaining a pressure drop across the reaction zone of ≤70 kPag).