Disclosed is a device for treating high-concentration organic wastewater by catalyst hydrothermal gasification, including a CHG reactor, a temporary wastewater storage tank and a condensing heat exchanger which are sequentially in loop connection. The CHG reactor includes a shell, a thermocouple, a water distribution device, and a packing support. The device of the present disclosure can quickly convert the high-concentration organic wastewater into clean energy or harmless gas at a low temperature under the action of a catalyst, so that the energy consumption of a treatment process is greatly reduced, and the treatment efficiency is improved. The device has potential application prospect.

A process for producing syngas from pre-treated recovery plastic polymers comprising:

a) gasifying said recovery pre-treated polymers according to the following reaction scheme R1:

[—CH.sub.2—]+H.sub.2O═CO+2H.sub.2;  R1:

b) hydrogenating said pre-treated polymers to higher hydrocarbons and methane by using hydrogen produced in R1, according to the following reaction scheme R3:

[—CH.sub.2—].sub.n+H.sub.2═C.sub.nH.sub.(2n+2)  R3:

wherein n is an integer of from 1 to 3, said reaction being optionally combined with oligomers and olefin formation reactions;
c) steam reforming of methane according to the following reaction scheme R4:

CH.sub.4+H.sub.2O═CO+3H.sub.2;  R4:

and optionally
d) reforming reaction of methane according to the following reaction scheme R5:

CH.sub.4+CO.sub.2=2CO+2H.sub.2;  R5:

said process being carried out in a plant (10), (20), (30), (40), (50) comprising a gasification section (11), (21), (31), (41), (51) and a reforming section (12), (22), (32), (42), (52) comprising a tube bundle (13), (23), (33), (43), (53) provided with a catalyst wherein,
i) said gasification (11), (21), (31) and reforming sections (12),(22), (32) are part of a sole reactive unit (10), (20), (30), or said gasification (41), (51) and reforming section (42), (52) are two physically distinct reactive units (40), (50),
ii) the gasification section (11), (21) or the reactive unit (41) provides respectively the energetical support to the reforming section (12), (22) or to the reforming reactive unit (42), thanks to the exothermic combustion reaction scheme R2:

[—CH.sub.2-]+1.5O.sub.2═CO.sub.2+H.sub.2O;  R2:

or in alternative: the reforming section (

A combined hydrothermal liquefaction (HTL) and catalytic hydrothermal gasification (CHG) system and process are described that convert various biomass-containing sources into separable bio-oils and aqueous effluents that contain residual organics. Bio-oils may be converted to useful bio-based fuels and other chemical feedstocks. Residual organics in HTL aqueous effluents may be gasified and converted into medium-BTU product gases and directly used for process heating or to provide energy.

A method and apparatus for gasifying raw material. The method includes feeding the raw material into an upper part of a fixed-bed gasifier, introducing the raw material from the upper part of the gasifier to a pyrolysis zone of the gasifier to form the fixed-bed and pyrolyzing the raw material in the presence of pyrolysis air to form a pyrolysis product. Introducing the pyrolysis product from the pyrolysis zone to a lower part of the gasifier, introducing primary air countercurrently to the lower part, carrying out a final gasification in a lower part of the gasifier in order to form a gasified gas. Introducing the gasified gas to a catalytic oxidation part and through a catalyst layer of the catalytic oxidation part, and reforming the gasified gas by way of the catalytic oxidation in the presence of reforming air in the catalytic oxidation part, forming a gaseous product.

A two-reactor catalytic system including a catalytic membrane gasification reactor and a catalytic membrane water gas shift reactor. The catalytic system, for converting biomass to hydrogen gas, features a novel gasification reactor containing both hollow fiber membranes that selectively allow O.sub.2 to permeate therethrough and a catalyst that facilitates tar reformation. Also disclosed is a process of converting biomass to H2. The process includes the steps of, among others, introducing air into a hollow fiber membrane; mixing the O.sub.2 permeating through the hollow fiber membrane and steam to react with biomass to produce syngas and tar; and reforming the tar in the presence of a catalyst to produce more syngas.

Combining multiple subsystems involving biomass processing, biomass gasification of the processed biomass where a synthesis gas is produced then converted to hydrogen fuels or other transportation fuels for use in coupled transportation systems sized to consume all the transportation fuel produced. Carbon in the biomass is converted to CO.sub.2 in the conversion process and a portion of that CO.sub.2 is captured and sequestrated for long term storage.

The present disclosure provides a method for preparing hydrogen-rich gas by solid organics. For example, solid organic raw materials are heated in a pyrolysis reaction device to perform pyrolysis reaction, and gaseous product generated from the pyrolysis reaction performs gasification with steam in a moving bed gasification reaction device to generate hydrogen-rich product. The present disclosure also provides a system for preparing hydrogen-rich gas by solid organics, and the system may include a solid heat carrier grading-dedusting device; a pyrolysis reaction device; a moving bed gasification reaction device; and a riser and combustion reactor. The present disclosure may operate at atmospheric pressure, and the technology is simple and suitable for the gasification and co-gasification of various high-volatile solid organics, such as raw materials containing a relatively large amount of moisture, mineral substance, and sulfur content.

A combined hydrothermal liquefaction (HTL) and catalytic hydrothermal gasification (CHG) system and process are described that convert various biomass-containing sources into separable bio-oils and aqueous effluents that contain residual organics. Bio-oils may be converted to useful bio-based fuels and other chemical feedstocks. Residual organics in HTL aqueous effluents may be gasified and converted into medium-BTU product gases and directly used for process heating or to provide energy.

The invention relates to a catalyst regeneration process for a tar reforming catalyst within a catalyst bed in a tar reformer. The process comprises the steps of:—Admitting a main gas stream with controlled temperature and oxygen content to an inlet into the tar reformer;—Passing the main gas stream through the catalyst bed to form an oxygen depleted gas stream;—Exiting the oxygen depleted gas stream from the tar reformer; and—Recycling at least a part of the oxygen depleted gas stream exiting from the tar reformer back into said main gas stream upstream said tar reformer. The temperature of said main gas stream at the inlet is controlled to be within the range from about 500° C. to about 1000° C.

A process for processing carbonaceous material, the process comprising: delivering a carbonaceous material to a reactor; delivering a catalyst to the reactor; processing the carbonaceous material at a relatively low temperature within the reactor to decompose the carbonaceous material to base compounds.