A method and a device for preparing graphene and hydrogen gas by converting waste plastics with Joule heat are provided according to the present application. The method uses the Joule heat generated when a strong current passes through the mixed plastic material mixed with conductive additive, as the reaction driving energy. By Joule heating, carbon-carbon bonds and carbon-hydrogen bonds are broken, amorphous carbon is converted into sp.sup.2 hybridized high-purity graphene, and hydrogen atoms are converted into hydrogen gas. The reaction device used by the method is mainly composed of three parts: an airtight reaction chamber, a gas collecting system and a power control system.

A process for the manufacture of a useful product from carbonaceous feedstock of fluctuating compositional characteristics, the process comprising the steps of: continuously providing the carbonaceous feedstock of fluctuating compositional characteristics to a gasification zone; gasifying the carbonaceous feedstock in the gasification zone to obtain raw synthesis gas; sequentially removing ammoniacal, sulphurous and carbon dioxide impurities from the raw synthesis gas to form desulphurised gas and recovering carbon dioxide in substantially pure form; converting at least a portion of the desulphurised synthesis gas to a useful product. Despite having selected a more energy intensive sub-process i.e. physical absorption for removal of acid gas impurities, the overall power requirement of the facility is lower on account of lower steam requirements and thereby leading to a decrease in the carbon intensity score for the facility.

gasifier and a gasification process provides a long, uniform temperature zone in the gasifier, regardless of the particle size, chemical composition, and moisture content of the fuel by sandwiching a reduction zones between two oxidation zones. The gasifier and gasification process produces a char that is more energy-dense and almost devoid of moisture, affording an additional (char) oxidation zone with a temperature that is higher than a first oxidation zone which is closer to an evaporation and devolatilization zone. As such, the additional (char) oxidation zone contributes to augmenting the reduction zone temperature, providing a favorable dual impact in improving syngas composition and near-complete conversion of the tar.

The present invention provides a process and apparatus for converting feedstock comprising biomass and/or carbon-containing solid waste material to synthesis gas. The process comprises supplying the feedstock to a gasifier comprising a fluidized bed zone and a post-gasification zone and contacting the feedstock with a gasification agent at a plurality of different operating temperatures based on the ash softening temperature of the feedstock and finally recovering the synthesis gas. The apparatus is configured to perform the process and comprises a plurality of nozzles arranged at an acute angle relative to a horizontal plane of the gasifier.

Disclosed herein is a method for making hydrogen with carbon sequestration. The method may comprise using a biomass hydroconverter product to fuel a steam reformer that converts a hydrocarbon fuel stream into a gas mixture that contains at least hydrogen and carbon dioxide. The gas stream is separated to form a hydrogen-enriched gas stream and at least one hydrogen-depleted stream. The hydrogen-depleted stream may be stored or further processed to sequester the carbon contained therein. Additionally, or alternatively, the solid residue from the biomass hydroconverter also may be stored for further sequester carbon generated by the method.

Chemical recycling facilities for processing mixed waste plastic are provided herein. Such facilities have the capability of processing mixed plastic waste streams and utilize a variety of recycling facilities, such as, for example, solvolysis facility, a pyrolysis facility, a cracker facility, a partial oxidation gasification facility, an energy recovery facility, and a solidification facility. Streams from one or more of these individual facilities may be used as feed to one or more of the other facilities, thereby maximizing recovery of valuable chemical components and minimizing unusable waste streams.

Provided herein are methods of producing synthesis gas (syngas) from aplastic material. The methods generally comprise feeding a wet waste plastic and/or liquified plastic stream and molecular oxygen (O2) into a partial oxidation (POX) gasifier. The wet waste plastic generally comprises the plastic material mixed with a liquid medium and has a liquid content of at least 2 weight percent. The wet waste plastic may be in the form of a plastic-containing slurry and/or may be derived from other processes that produce plastic-containing streams. The wet waste plastic may also be combined with a quantity of coal (or pet coke) before being fed to the gasifier. A partial oxidation reaction is performed within the gasifier by reacting at least a portion of the plastic material and the molecular oxygen to form the syngas.

A chemical recycling process and facility for turning one or more waste plastics into syngas are provided. Generally, the chemical recycling process involves: (a) liquefying at least one solid waste plastic to form a liquefied waste plastic; (b) introducing at least a portion of the liquefied waste plastic into a partial oxidation (POX) gasifier; and (c) converting at least a portion of the liquefied waste plastic in the POX gasifier into a syngas composition.

The presently disclosed embodiments relate to the utilization of coal-derived fine mineral matter in chemical recycling of plastics or of solid mixed plastic waste. The instantly disclosed mineral based catalyst benefits the processes of catalytic cracking, gasification and steam reforming to maximize carbon utilization and production of plastics of original quality from recycled or renewable feedstocks while reducing the plastic pollution in the environment. The catalyst can be based on inorganic fine mineral matter, a natural ancient mineral mixture found in coal deposits and containing a plurality of transition metals, such as iron, copper, and manganese, as well as calcium, barium, magnesium, potassium, sodium, which can act as co-catalysts. Addition of the catalyst can convert plastic to syngas at a faction of the energy of conventional technologies.

The invention provides a system for pyrolysis, comprising: (i) a gas producer comprising a gasification zone and a producer gas outlet, wherein the gas producer is configured to: oxidise at least one carbon-containing feed in the presence of an oxidising gas in the gasification zone to form a producer gas; and discharge the producer gas from the gasification zone via the producer gas outlet, wherein a residual oxygen content of the producer gas is substantially depleted or maintained below a maximum predetermined amount by controlling a ratio of oxygen fed to the gasification zone to the carbon-containing feed, (ii) a pyrolyzer comprising a pyrolysis zone and one or more pyrolyzer gas outlets, wherein the pyrolyzer is configured to: feed the producer gas discharged from the gasification zone to the pyrolysis zone; pyrolyze a pyrolyzable organic feed in the pyrolysis zone in the presence of the producer gas to produce a carbonaceous pyrolysis product and a gas mixture comprising combustible components comprising pyrolysis gas; and discharge the gas mixture from the pyrolysis zone via the one or more pyrolyzer gas outlets, and (iii) a first combustor comprising a combustion zone, wherein the first combustor is configured to: receive the gas mixture discharged from the pyrolysis zone in the combustion zone; feed an oxygen-containing gas to the combustion zone; and combust at least a portion of the combustible components present in the gas mixture in the combustion zone to produce a combustion product gas.