Patent classifications
C10J2300/1869
Systems and methods for processing carbonaceous feedstock
A system for producing high purity carbon monoxide and hydrogen as well as activated carbon includes a pyrolysis reactor, a gasifier, a combustion turbine, a boiler, a steam turbine, a combined cycle unit and an electrolysis unit. Liquid fuel from the pyrolysis reactor is provided to the combustion turbine. Liquid and gaseous fuels are provided to the boiler. Compressed oxygen from the electrolysis unit is provided to the combustion turbine. Electric power from the combustion turbine and steam turbine are provided to the electrolysis unit. The gasifier includes a preheat region, a gasification region, and a cooling region. CO.sub.2 and O.sub.2 are injected into the gasifier at multiple injection levels to create an isothermal gasification region to produce CO. The CO.sub.2 and O.sub.2 are preheated in a heat exchanger using the CO exiting from the gasifier prior to injection.
Method for reducing NOx emissions from gasification power plants
A method is provided for thermally processing waste to produce steam and generate energy while minimizing air pollutants in a staged thermal reactor. The method includes gasifying the waste to convert the waste to a fuel gas and a substantially carbon free, inert, granulated, sintered mineral ash and reforming the fuel gas auto-thermally to minimize creation of nitrogen oxide when the fuel gas is combusted. The method further includes burning the reformed fuel gas to minimize creation of nitrogen oxide in a flame region of a fuel gas burner and recirculating cooled flue gas to control oxygen content and temperature during the reforming operation and the burning operation. In one example, reforming the fuel gas converts non-molecular nitrogen species into molecular nitrogen in an auto-thermal non-catalytic reformer unit by decomposition reactions promoted by a prevailing reducing gas atmosphere.
THERMAL INTEGRATION IN SYNTHESIS GAS PRODUCTION BY PARTIAL OXIDATION
A process and a plant are proposed for producing a synthesis gas including hydrogen and carbon oxides by partial oxidation of carbon-containing fuel in the presence of an oxygen-containing oxidant and a moderator, wherein the obtained raw synthesis gas is laden with soot particles. According to the invention the cooling of the raw synthesis gas is carried out using a crossflow heat exchanger, a shell and tube heat exchanger or a spiral heat exchanger, wherein the carbon-containing input stream or the oxidant stream or the moderator stream or a plurality of these streams serve as the first coolant and are thus preheated before introduction into the partial oxidation plant.
SYSTEMS AND METHODS FOR PROCESSING CARBONACEOUS FEEDSTOCK
A system for producing high purity carbon monoxide and hydrogen as well as activated carbon includes a pyrolysis reactor, a gasifier, a combustion turbine, a boiler, a steam turbine, a combined cycle unit and an electrolysis unit. Liquid fuel from the pyrolysis reactor is provided to the combustion turbine. Liquid and gaseous fuels are provided to the boiler. Compressed oxygen from the electrolysis unit is provided to the combustion turbine. Electric power from the combustion turbine and steam turbine are provided to the electrolysis unit. The gasifier includes a preheat region, a gasification region, and a cooling region. CO.sub.2 and O.sub.2 are injected into the gasifier at multiple injection levels to create an isothermal gasification region to produce CO. The CO.sub.2 and O.sub.2 are preheated in a heat exchanger using the CO exiting from the gasifier prior to injection.
Integrated coal gasification combined power generation process with zero carbon emission
The present disclosure relates to the technical field of coal chemical industry, and particularly discloses an integrated coal gasification combined power generation process with zero carbon emission, the process comprising: pressurizing air for performing air separation to obtain liquid oxygen and liquid nitrogen, wherein the liquid oxygen is used for gasification and power generation, the liquid nitrogen is applied as the coolant for the gasification and power generation, the liquid nitrogen and a part of liquid oxygen stored during the valley period with low electricity load are provided for use during the peak period with high electricity load; the pulverized coal delivered under pressure and high-pressure oxygen enter a coal gasification furnace for gasification, so as to generate high-temperature fuel gas, which subjects to heat exchange and purification, and then the high-pressure fuel gas enters into a combustion gas turbine along with oxygen and recyclable CO.sub.2 for burning and driving an air compressor and a generator to rotate at a high speed; the air compressor compresses the air to a pressure of 0.40.8 MPa, and the generator generates electricity; the high-temperature combustion flue gas performs the supercritical CO.sub.2 power generation, its coolant is liquid oxygen or liquid nitrogen; the heat exchanged combustion fuel gas subsequently perform heat exchange with liquid nitrogen, the liquid nitrogen vaporizes to drive a nitrogen turbine generator for generating electricity, the cooled flue gas is dehydrated and distilled to separate CO.sub.2, a part of CO.sub.2 is used for circulation and temperature control, and another portion of CO.sub.2 is sold outward as liquid CO.sub.2 product. The power generation process provided by the present disclosure not only solves the difficult problems of high water consumption, low power generation efficiency and small range of peak load adjustment capacity of the existing IGCC technology; but also can compress air with high unit volume for energy storage with a high conversion efficiency, and greatly reduce load of the air compressor, thereby perform CO.sub.2 capture and utilization with low-cost, zero NO.sub.x emission and discharging fuel gas at a normal temperature, and significantly improve the power generation efficiency.
THERMOCHEMICAL CONVERSION OF BIOMASS
The present invention is directed to a process for the production of a syngas suited for further conversion to fine chemicals and/or automotive fuels from biomass by a thermochemical process conducted in a several steps procedure, said process comprising; a) Providing a stream of biomass material; b) Providing an aqueous alkaline catalyst stream comprising sodium and/or potassium compounds; c) Mixing comminuted biomass and alkaline catalyst and optional additives to form an alkaline biomass slurry or suspension; d) Treating alkaline biomass slurry or suspension in a hydrothermal treatment reactor at a temperature in the range of 200-400 C. and a pressure from 10-500 bar, forming a bio-oil suspension comprising liquefied biomass and spent alkali catalyst; e) Directly or indirectly charging the bio-oil suspension from step d), after optional depressurization to a pressure in the range 10-100 bar, heat exchange and separation of gases, such as CO2, steam and aqueous spent catalyst into a gasification reactor operating in the temperature range of 600-1250 C. thereby forming a syngas and alkali compounds; and f) Separating alkali compounds from a gasification reactor or from syngas and recycling alkali compounds directly or indirectly to be present to treat new biomass in the hydrothermal biomass treatment reactor of step d) and/or recycling aqueous alkali salts to a pulp mill chemicals recovery cycle.
Method and arrangement for burning lime mud
An arrangement for burning lime mud into lime in a lime kiln. The lime mud flows counter-currently to flue gases from a feed end to a firing end and the fuel used is flue gas that is produced by gasifying a fuel in the presence of combustion air in a gasifier. The combustion air for gasification is preheated with heat generated in lime mud combustion. The arrangement is provided with a conduit between the lime kiln and the gasifier for leading air from the lime kiln into the gasifier as combustion air. At least a portion of the combustion air for gasification is preheated with heat generated in the lime mud combustion so that air is led into cooling of lime obtained in the combustion and further into the kiln, from or through the firing end of which air is taken into the gasification.
INTEGRATED COAL GASIFICATION COMBINED POWER GENERATION PROCESS WITH ZERO CARBON EMISSION
The present disclosure relates to the technical field of coal chemical industry, and particularly discloses an integrated coal gasification combined power generation process with zero carbon emission, the process comprising: pressurizing air for performing air separation to obtain liquid oxygen and liquid nitrogen, wherein the liquid oxygen is used for gasification and power generation, the liquid nitrogen is applied as the coolant for the gasification and power generation, the liquid nitrogen and a part of liquid oxygen stored during the valley period with low electricity load are provided for use during the peak period with high electricity load; the pulverized coal delivered under pressure and high-pressure oxygen enter a coal gasification furnace for gasification, so as to generate high-temperature fuel gas, which subjects to heat exchange and purification, and then the high-pressure fuel gas enters into a combustion gas turbine along with oxygen and recyclable CO.sub.2 for burning and driving an air compressor and a generator to rotate at a high speed; the air compressor compresses the air to a pressure of 0.40.8 MPa, and the generator generates electricity; the high-temperature combustion flue gas performs the supercritical CO.sub.2 power generation, its coolant is liquid oxygen or liquid nitrogen; the heat exchanged combustion fuel gas subsequently perform heat exchange with liquid nitrogen, the liquid nitrogen vaporizes to drive a nitrogen turbine generator for generating electricity, the cooled flue gas is dehydrated and distilled to separate CO.sub.2, a part of CO.sub.2 is used for circulation and temperature control, and another portion of CO.sub.2 is sold outward as liquid CO.sub.2 product. The power generation process provided by the present disclosure not only solves the difficult problems of high water consumption, low power generation efficiency and small range of peak load adjustment capacity of the existing IGCC technology; but also can compress air with high unit volume for energy storage with a high conversion efficiency, and greatly reduce load of the air compressor, thereby perform CO.sub.2 capture and utilization with low-cost, zero NO.sub.x emission and discharging fuel gas at a normal temperature, and significantly improve the power generation efficiency.
Polygeneration method of biomass downflow circulation bed millisecond pyrolysis liquefaction-gasification coupling
A polygeneration method of biomass downflow circulation bed millisecond pyrolysis liquefaction-gasification coupling is provided.
COMPACT GASIFIER-GENSET ARCHITECTURE
A compact biomass gasification-based power generation system that converts carbonaceous material into electrical power, including an enclosure that encases: a gasifier including a pyrolysis module coaxially arranged above a reactor module, a generator including an engine and an alternator, and a hopper. The generator system additionally includes a first heat exchanger fluidly connected to an outlet of the reactor module and thermally connected to the drying module, a second heat exchanger fluidly connected to an outlet of the engine and thermally connected to the pyrolysis module, and a third heat exchanger fluidly connected between the outlet of the reactor module and the first heat exchanger, the third heat exchanger thermally connected to an air inlet of the reactor module. The system can additionally include a central wiring conduit electrically connected to the pyrolysis module, reactor module, and engine, and a control panel connected to the conduit that enables single-side operation.