A process and apparatus for producing pure hydrogen from a syngas generated by the high temperature gasification of municipal, agricultural or industrial derived wastes. The process is able to make pure hydrogen to be further reacted with nitrogen to make ammonia and urea.

Various embodiments of a system for the removal of particulate emissions from an electric generating unit are provided, comprising: a gas producer; a primary particulate collector unit including: a primary collection hopper field each including at least one primary collection hopper, wherein each primary collection hopper includes a primary collection hopper outlet, each primary collection hopper outlet fluidically connected to a particulate discharge duct; a flue duct inlet oriented upstream of the at least one primary collection hopper field; a flue duct outlet oriented downstream of the primary collection hopper field; wherein the gas producer is fluidically connected to the primary particulate collector unit by a flue duct; and a particulate recirculation duct fluidically connected at a first end to the primary collection hopper and/or the particulate discharge duct, and fluidically connected at a second end to the flue duct upstream of the primary particulate collector unit.

The present invention is directed to a pyrolysis method. The method involves providing a biomass and subjecting the biomass, in a reactor operating under conditions of parasitic heat loss of less than 1% of the biomass' chemical energy content, to partial oxidation where, during steady state operation of the reactor, oxygen is provided to the reactor in sufficient quantity to achieve an equivalence ratio of 0.06 to 0.15 to release sufficient energy to support endothermic pyrolysis reactions and produce condensable organic compounds as the major portion of the pyrolysis products.

A raw syngas coming from HT gasification of organic wastes, once cooled in a proper heat recovery boiler or in a quencher is treated in a scrubbing section where, by adding an acidic solution followed by alkaline solution and by a WESP, particulate and chlorine compounds are removed and the syngas is ready for conversion, after its compression. In the conversion step CO is converted into C02 and H2 by adding steam; H2S is reduced to sulphur in a solid form, C02 is removed via cryogenic unit or an amine unit and pure H2 is produced.

Various embodiments of a system for the removal of particulate emissions from an electric generating unit are provided, comprising: a gas producer; a primary particulate collector unit including: a primary collection hopper field each including at least one primary collection hopper, wherein each primary collection hopper includes a primary collection hopper outlet, each primary collection hopper outlet fluidically connected to a particulate discharge duct; a flue duct inlet oriented upstream of the at least one primary collection hopper field; a flue duct outlet oriented downstream of the primary collection hopper field; wherein the gas producer is fluidically connected to the primary particulate collector unit by a flue duct; and a particulate recirculation duct fluidically connected at a first end to the primary collection hopper and/or the particulate discharge duct, and fluidically connected at a second end to the flue duct upstream of the primary particulate collector unit.

The present invention is directed to a pyrolysis method. The method involves providing a biomass and subjecting the biomass, in a reactor operating under conditions of parasitic heat loss of less than 1% of the biomass' chemical energy content, to partial oxidation where, during steady state operation of the reactor, oxygen is provided to the reactor in sufficient quantity to achieve an equivalence ratio of 0.06 to 0.15 to release sufficient energy to support endothermic pyrolysis reactions and produce condensable organic compounds as the major portion of the pyrolysis products.

A method of removing impurities from black water associated with a gasifier includes adding a flocculant to the black water to create a black water and flocculant mixture, settling the black water and flocculant mixture in a gravity settling device to separate the black water and flocculant mixture into clarified water, a froth phase, and a heavy phase, the froth phase comprising soot, water, and air or gas, the heavy phase comprising soot and water, drawing off the clarified water from the settled black water and flocculant mixture, collecting a dilute slurry comprising the froth phase and the heavy phase, and phase separating the dilute slurry in a high-speed centrifuge to provide additional clarified water and a concentrated slurry, wherein the black water is obtained from wet gas scrubbing of syngas.