Patent classifications
C10K3/02
Induction heating of endothermic reactions
A reactor system for carrying out an endothermic catalytic chemical reaction in a given temperature range upon bringing a reactant into contact with a catalyst material. The reactor system includes a reactor unit arranged to accommodate catalyst material including one or more ferromagnetic macroscopic supports susceptible for induction heating where the one or more ferromagnetic macroscopic supports are ferromagnetic at temperatures up to an upper limit of the given temperature range. The one or more ferromagnetic macroscopic supports are coated with an oxide, and the oxide is impregnated with catalytically active particles. The reactor system moreover includes an induction coil arranged to be powered by a power source supplying alternating current and being positioned so as to generate an alternating magnetic field within the reactor unit upon energization by the power source, whereby the catalyst material is heated to a temperature within the temperature range by the alternating magnetic field.
PROCESS
A process for the manufacture of a useful product from carbonaceous feedstock of fluctuating compositional characteristics, the process comprising the steps of: continuously providing the carbonaceous feedstock of fluctuating compositional characteristics to a gasification zone; gasifying the carbonaceous feedstock in the gasification zone to obtain raw synthesis gas; sequentially removing ammoniacal, sulphurous and carbon dioxide impurities from the raw synthesis gas to form desulphurised gas and recovering carbon dioxide in substantially pure form; converting at least a portion of the desulphurised synthesis gas to a useful product. Despite having selected a more energy intensive sub-process i.e. physical absorption for removal of acid gas impurities, the overall power requirement of the facility is lower on account of lower steam requirements and thereby leading to a decrease in the carbon intensity score for the facility.
Production of aromatics by reverse water gas shift, fermentation and recycling to pyrolysis
Device and process for the conversion of a feedstock of aromatic compounds, in which the feedstock is treated notably by means of a fractionation train (4-7), a xylene separation unit (10) and an isomerization unit (11), and in which a pyrolysis unit (13) treats a second hydrocarbon feedstock, produces a pyrolysis effluent feeding the feedstock, and produces a pyrolysis gas comprising CO, CO.sub.2 and H.sub.2; a reverse water gas shift RWGS reaction section (50) treats the pyrolysis gas and produces an RWGS gas enriched in CO and in water; a fermentation reaction section (52) treats the RWGS gas enriched in CO and in water, to produce ethanol and recycle the ethanol to the inlet of the pyrolysis unit.
ELECTRICALLY HEATED CARBON MONOOXIDE REACTOR
A reactor system and a process for carrying out reverse water gas shift reaction of a feedstock comprising CO.sub.2 and H.sub.2 to a first product gas comprising CO are provided, where a methanation reaction take place in parallel to the reverse water gas shift reaction, and where the heat for the endothermic reverse water gas shift reaction is provided by resistance heating.
METHOD AND APPARATUS FOR REMOVING IMPURITIES FROM GASIFICATION GAS AND USE
The invention relates to a method and an apparatus for removing impurities from a gasification gas, wherein the gasification gas which includes at least tars and/or undesired hydrocarbons is supplied to a catalytic reformer which has at least one catalyst bed, oxygen containing gas is injected onto the surface of the catalyst bed, the gasification gas is arranged to flow through the catalyst bed and arranged to contact with the oxygen containing gas in the catalyst bed, and a purified gas is discharged from the catalytic reformer. Further, the invention relates to the use of the method.
METHOD AND APPARATUS FOR PURIFYING GAS AND USE
The invention relates to a method and an apparatus for purifying gas, wherein the gas which includes at least tars and/or undesired hydrocarbons is supplied to a catalytic treatment reactor which has at least one catalyst zone including at least one catalyst element with a catalyst, oxygen gas is fed into the catalyst element of the catalyst zone in the catalytic treatment reactor and is supplied through the catalyst element, the gas is arranged to flow to the catalyst zone and arranged to contact with the oxygen gas and the catalyst, and a purified gas is discharged from the catalytic treatment reactor. Further, the invention relates to the use of the method.
PROCESS AND INTEGRATED PLANT FOR THE TREATMENT OF THE CARBON OXIDES FORMED IN THE PRODUCTION OF ALUMINUM
A process can be used for the treatment of an offgas stream, which is formed in a plant for the production of aluminum by electrolytic reduction of aluminum oxide in a melt, using at least one anode composed of a carbon-containing material. The offgas stream contains carbon oxides due to the reduction of the aluminum oxide by the carbon. At least a substream of the carbon oxides contained in the offgas stream is reacted with hydrogen or mixed with a hydrogen stream and is subsequently passed to a use. After purification and conditioning of the offgas stream in a device, an enrichment, for example with carbon monoxide, can subsequently be carried out in a reactor and the synthesis gas obtained in this way can be fed to a chemical or biotechnological plant for the synthesis of chemicals of value.
Reverse water gas shift catalytic reactor systems
The present invention describes a processes, systems, and catalysts for the utilization of carbon dioxide into high quality synthesis gas that can then be used to produce fuels (e.g., diesel fuel) and chemicals. In one aspect, the present invention provides a process for the conversion of a feed gas comprising carbon dioxide and hydrogen to a product gas comprising carbon monoxide and water.
PROCESSES FOR PRODUCING SYNGAS STARTING FROM PRETREATED RECOVERY PLASTIC POLYMERS
A process for producing syngas from pre-treated recovery plastic polymers comprising:
a) gasifying said recovery pre-treated polymers according to the following reaction scheme R1:
[—CH.sub.2—]+H.sub.2O═CO+2H.sub.2; R1:
b) hydrogenating said pre-treated polymers to higher hydrocarbons and methane by using hydrogen produced in R1, according to the following reaction scheme R3:
[—CH.sub.2—].sub.n+H.sub.2═C.sub.nH.sub.(2n+2) R3:
wherein n is an integer of from 1 to 3, said reaction being optionally combined with oligomers and olefin formation reactions;
c) steam reforming of methane according to the following reaction scheme R4:
CH.sub.4+H.sub.2O═CO+3H.sub.2; R4:
and optionally
d) reforming reaction of methane according to the following reaction scheme R5:
CH.sub.4+CO.sub.2=2CO+2H.sub.2; R5:
said process being carried out in a plant (10), (20), (30), (40), (50) comprising a gasification section (11), (21), (31), (41), (51) and a reforming section (12), (22), (32), (42), (52) comprising a tube bundle (13), (23), (33), (43), (53) provided with a catalyst wherein,
i) said gasification (11), (21), (31) and reforming sections (12),(22), (32) are part of a sole reactive unit (10), (20), (30), or said gasification (41), (51) and reforming section (42), (52) are two physically distinct reactive units (40), (50),
ii) the gasification section (11), (21) or the reactive unit (41) provides respectively the energetical support to the reforming section (12), (22) or to the reforming reactive unit (42), thanks to the exothermic combustion reaction scheme R2:
[—CH.sub.2-]+1.5O.sub.2═CO.sub.2+H.sub.2O; R2:
or in alternative: the reforming section (
PROCESSES AND SYSTEMS FOR PRODUCING HYDROCARBON FUELS HAVING HIGH CARBON CONVERSION EFFICIENCY
The present disclosure relates to a processes and systems for producing fuels from biomass with high carbon conversion efficiency. The processes and systems described herein provide a highly efficient process for producing hydrocarbons from biomass with very low Green House Gas (GHG) emissions using a specific combination of components, process flows, and recycle streams. The processes and systems described herein provide a carbon conversion efficiency greater than 95% with little to no GHG in the flue gas due to the novel arrangement of components and utilizes renewable energy to provide energy to some components. The system reuses water and carbon dioxide produced in the process flows and recycles naphtha and tail gas streams to other units in the system for additional conversion to syngas to produce hydrocarbon-based fuels.