Patent classifications
C10L1/1985
Macromolecular corrosion (McIn) inhibitors: structures, methods of making and using the same
Disclosed are multifunctional compounds represented by structural formula (I): ##STR00001##
methods of producing compounds represented by structural formula (I) and their use in inhibiting corrosion in corrodible material.
Polymers as additives for fuels
A method minimizes power loss in a direct injection diesel engine by adding a copolymer to a diesel fuel composition. The copolymer contains, in a copolymerized form, (A) maleic anhydride, (B) an α-olefin having from 12 to 30 carbon atoms, (C) optionally an additional aliphatic or cycloaliphatic olefin which has at least 4 carbon atoms and is different from monomer (B), and (D) optionally an additional copolymerizable monomer other than monomers (A), (B) and (C). Monomer (D) can be a vinyl ester, a vinyl ether, a (meth)acrylic ester of an alcohol having at least 5 carbon atoms, an allyl alcohol or an ester thereof, a N-vinyl compound, an ethylenically unsaturated aromatic, an α,β-ethylenically unsaturated nitrile, a (meth)acrylamide, or an allylamine. Anhydride functionalities present in the copolymer are partly reacted with at least one compound (E) comprising an alcohol group and/or an amino group, and the anhydride functionalities present are hydrolyzed.
Quaternary ammonium compound and fuel composition
A quaternary ammonium compound of formula (I): wherein R.sup.0, R.sup.1, R.sup.2 and R.sup.3 is each independently an optionally substituted hydrocarbyl group; X is a linking group; R.sup.4 is an optionally substituted alkylene group; n is a positive integer; W is O.sup.− or OH; b is 1 when W is OH, and b is 2 when W is O.sup.−. ##STR00001##
Emulsification dispersants, a method for emulsification and dispersion using the emulsification dispersants, emulsions, and emulsion fuels
An emulsifying dispersant includes, as the main component, vesicles formed from an amphiphilic substance capable of self-assembly or an emulsifying dispersant comprising single particles of a biopolymer as the main component. The particles made from amphiphilic substances capable of self-assembly are used. The amphiphilic substances are selected from among polyoxyethylene-hydrogenated castor oil derivatives wherein the average number of added ethylene oxide molecule is 5 to 15, dialkyldimethyl-ammonium halides wherein the chain length of the alkyl or alkenyl is 8 to 22, and phospholipids or phospholipid derivatives. According to the invention a three-phase structure composed of an aqueous phase, an emulsifying dispersant phase and an oil phase is formed on the surface of an emulsion to give an emulsion (such as emulsion fuel) excellent in thermal stability and long-term stability.
FUEL STABILIZER
A fuel stabilizer formulation includes a hybrid component that acts as an antioxidant, a chelating agent, and lubricant when added to the fuel, one or more vapor suppressants, and a water scavenger. Furthermore, the formulation may include components that bond with gasoline compounds to prevent evaporation of low-end components, form a layer along with the engine metal that prevents condensed water from corroding the metal, prevent corroded metal ions from destabilizing gasoline compounds into resin, and scavenge water to prevent water deposits at the bottom of the tank which limits biological activity, resulting in an overall improvement in oxidation stability over conventional fuel stabilizers.
Nitrogen-containing Diesel Solidification Point Depressant Composition, and Preparation and Application Thereof
The present invention relates to a nitrogen-containing diesel solidification point depressant composition, and preparation and application thereof. The nitrogen-containing diesel solidification point depressant composition includes the following components in percentage by weight: 10-40% of monoisopropanolamine; 10-40% of cyclohexane; 0-20% of polyethylene glycol; and 40-60% of N-tetradecyl methacrylamide-tetradecyl methacrylate. After the prepared diesel solidification point depressant composition is added to commercially available 0 #diesel, a solidification point and a cold filter plugging point of the diesel are respectively depressed by 21-25° C. and 9-13° C.
Water in fuel nanoemulsion and method of making the same
A method of producing a nanoemulsion is disclosed that provides an oleaginous base fuel, and water in an amount of at least 10 wt %. A first nonionic surfactant, a second nonionic surfactant and a third nonionic surfactant are mixed in substantially equal weight ratios into a surfactant mixture. The surfactant mixture is mixed with the water and the base fuel to form the nanoemulsion fuel. A nanoemulsion fuel composition can comprise an external oleaginous phase comprised of base fuel, an internal aqueous phase comprised of water, and a surfactant mixture comprised of a plurality of surfactants. The first surfactant can be derived from ethylene oxide, the second surfactant and the third surfactant are detergents having a fatty acid.
METHOD FOR REDUCING INTAKE VALVE DEPOSITS
Method for reducing intake valve deposits in a spark ignition internal combustion engine which is fuelled with a gasoline fuel composition, wherein the method comprises introducing into the engine an aqueous based composition, wherein the aqueous based composition comprises (i) water, (ii) from 0 vol % to 40 vol % freezing point suppression agent, (iii) from 0 vol % to 10 vol % of surfactant, and (iv) an amine compound in a blending amount of from 0 ppmw to 1000 ppmw.
METHOD, SYSTEM, APPARATUS AND FORMULATIONS FOR PRODUCING OIL-BASED BLENDS AND MICROEMULSIONS AND NANOEMULSIONS
A process for producing a microemulsion or nanoemulsion comprising water and at least one hydrocarbon or oil, comprising the steps of: a) providing the hydrocarbon or oil, water, one or more additives, a solvent, and a hydrophilic surfactant formulation comprising an amine or amide derivative non-ionic surfactant which is a fatty acid alkanolamide, one or more ethoxylated alcohols and/or ethoxylated alkylphenols, and a non-ionic fatty acid ester; b) by a mixing or stirring device operating at a mixing or stirring speed in the range 100 rpm and 15000 rpm, mixing or stirring the hydrophilic surfactant formulation and additive into the solvent, to produce a hydrophilic self-emulsifying blend; c) adding water to the hydrophilic self-emulsifying blend and the hydrocarbon or oil to produce a water-in-hydrocarbon/oil microemulsion or nanoemulsion, wherein the microemulsion or nanoemulsion comprises: 46% or more by mass of the hydrocarbon or oil, 4% to 36% by mass of water, a mass ratio of hydrophilic surfactant formulation to water in the range 1:10 to 1:2, 0.1% to 5% by mass of additive, 1.2% or more by mass of the solvent, a dispersed particle size in the range 1 nm to 500 nm, and a polydispersity index of 35% PdI or less, wherein the percentages by mass of the hydrocarbon or oil, water, formulation, additive and solvent together add up to 100%.
ADDITIVES FOR WINTERIZATION OF PARAFFIN INHIBITORS
A winterized paraffin inhibitor, which is capable of being used for preventing the deposition of paraffins in hydrocarbon streams and capable of withstanding freezing or crystallization at freezing or sub-freezing temperatures, may be formed by adding an oxyalkylated branched aliphatic compound having 12 or more carbons to a high molecular weight aliphatic polymer paraffin inhibitor, the oxyalkylated branched aliphatic compound having 12 or more carbons being produced by the oxyalkylation of the branched aliphatic compound having 12 or more carbon atoms in which the branched aliphatic compound having 12 or more carbon atoms is grafted with a polyether via a ring-opening reaction, wherein the polyether is a polymer of ethylene oxide, propylene oxide, butylene oxide, and combinations thereof.