Amines and amine derivatives that improve the buffering range, and/or reduce the chelation and other negative interactions of the buffer and the system to be buffered. The reaction of amines or polyamines with various molecules to form polyamines with differing pKa's will extend the buffering range, derivatives that result in polyamines that have the same pKa yields a greater buffering capacity. Derivatives that result in zwitterionic buffers improve yield by allowing a greater range of stability.

Amines and amine derivatives that improve the buffering range, and/or reduce the chelation and other negative interactions of the buffer and the system to be buffered. The reaction of amines or polyamines with various molecules to form polyamines with differing pKa's will extend the buffering range, derivatives that result in polyamines that have the same pKa yields a greater buffering capacity. Derivatives that result in zwitterionic buffers improve yield by allowing a greater range of stability.

A method for reducing NOx emissions during operation of an internal combustion engine in commerce which, when burning hydrocarbon fuel as a primary fuel, in the absence of any secondary fuel, has a characteristic stoichiometric ration. The method includes the following: in the absence of electrolytic activity, providing and entraining a quenching species in a gaseous medium and then interacting the quenching species with constituents present during oxidation of the primary fuel in a combustion chamber of the engine.

A method for reducing NOx emissions during operation of an internal combustion engine in commerce which, when burning hydrocarbon fuel as a primary fuel, in the absence of any secondary fuel, has a characteristic stoichiometric ration. The method includes the following: in the absence of electrolytic activity, providing and entraining a quenching species in a gaseous medium and then interacting the quenching species with constituents present during oxidation of the primary fuel in a combustion chamber of the engine.

The present disclosure provides fuel additives including Mannich-based quaternary ammonium salt additives, fuel compositions including such additives, and Methods of improving performance of fuel injector using such additives.

The present disclosure provides fuel additives including Mannich-based quaternary ammonium salt additives, fuel compositions including such additives, and Mehtods of improving performance of fuel injector using such additives.

An olefin-carboxylic acid copolymer, containing at least one free carboxylic acid side group, or a nitrogen compound quaternized with epoxide in the presence of an olefin-carboxylic acid copolymer, containing at least one free carboxylic acid side group, can be used as a fuel additive or lubricant additive. Processes can be used for preparing additives of this kind and fuels and lubricants additized therewith, such as a detergent additive. These additives, fuels, and lubricants can be used for reduction or prevention of deposits in injection systems of direct injection diesel engines, especially in common rail injection systems; for reduction of fuel consumption of direct injection diesel engines, especially of diesel engines with common rail injection systems; and for minimization of power loss in direct injection diesel engines, especially in diesel engines with common rail injection systems. The additives can also be used for gasoline fuels, especially for operation of DISI engines.

The present invention relates to a fuel additive composition comprising at least a first additive chosen from quaternary ammonium salts different from betaines, and at least a second additive chosen from amido alkyl betaines, wherein the weight ratio of the amount of the first additive to the amount of the second additive is within the range of from 1:4 to 4:1. The invention also relates to an additive concentrate and to a fuel composition comprising this additive composition, and also to the use thereof for preventing and/or eliminating the deposits in at least one of the internal parts of an engine.

The use as a valve deposit controlling additive in a fuel composition for a direct injection spark-ignition internal combustion engine of a combination of: a) at least one hydrocarbyl-substituted aromatic compound; and b) at least one polyalkylene amine.

The use as a valve deposit controlling additive in a fuel composition for a direct injection spark-ignition internal combustion engine of a combination of: a) at least one hydrocarbyl-substituted aromatic compound; and b) at least one polyalkylene amine.