Process for producing biomethane from a biogas stream including methane, carbon dioxide and at least one impurity chosen from ammonia, volatile organic compounds, water, sulfur-based impurities (H.sub.2S) and siloxanes. A biogas stream is dried, the at least one impurity is at least partially removed by solidification and removal of the impurity. The methane and the carbon dioxide contained in the biogas obtained from the second step are separated so as to produce a biomethane stream and a CO.sub.2 stream.

A method and a system of properly utilizing CO2 captured from the atmosphere as an agricultural fertilizer and a fuel for electric generation. The recycling method comprises: collecting information relating to demand for the CO2 to be utilized as the fertilizer and demand for the CO2 to be utilized as the fuel; calculating a ratio between an amount of the CO2 to be utilized as the fertilizer and an amount of the CO2 to be utilized as the fuel, based on the collected information; and thereafter utilizing the CO2 as the fertilizer and as the fuel based on the calculated ratio.

Embodiments of the present disclose provide a method of sorbing one or more compounds from a fluid, wherein the method may include contacting a M-soc-MOF composition with a fluid containing at least H.sub.2S and one or more of CO.sub.2 and CH.sub.4; and sorbing at least H.sub.2S from the fluid. Embodiments of the present disclosure provide a membrane that may include a metal-organic framework (MOF) composition, wherein the MOF composition includes a M-soc-MOF composition, where M is a metal and soc is a square-octahedral topology, and wherein the M-soc-MOF composition is a continuous thin film on a support.

Provided are apparatus and systems for performing a swing adsorption process. This swing adsorption process may involve performing dampening for fluctuations in the streams conducted away from the adsorbent bed unit. The process may be utilized for swing adsorption processes, such as rapid cycle TSA and/or rapid cycle PSA, which are utilized to remove one or more contaminants from a gaseous feed stream.

Provided are apparatus and systems for performing a swing adsorption process. This swing adsorption process may involve performing dampening for fluctuations in the streams conducted away from the adsorbent bed unit. The process may be utilized for swing adsorption processes, such as rapid cycle TSA and/or rapid cycle PSA, which are utilized to remove one or more contaminants from a gaseous feed stream.

A co-current contacting system for removing impurities from a gas stream is described herein. The co-current contacting system includes a co-current contactor configured to co-currently flow a gas stream including impurities and a liquid stream through the co-current contactor. The co-current contactor is also configured to incorporate liquid droplets formed from the liquid stream into the gas stream, such that the impurities from the gas stream are absorbed by the liquid droplets. The co-current contacting system also includes a separator configured to remove the gas stream from the liquid droplets including the impurities, generating a purified gas stream and a rich liquid stream. The co-current contacting system is configured to recycle the rich liquid stream for reuse as a portion of the liquid stream flowing into the co-current contactor.

Disclosed are methods for removing acid gas from a feed stream of natural gas including acid gas, methane and ethane. The methods include alternating input of the feed stream between at least two beds of adsorbent particles comprising zeolite SSZ-13 such that the feed stream contacts one of the at least two beds at a given time in an adsorption step and a tail gas stream is simultaneously vented from another of the at least two beds in a desorption step. The contact occurs at a feed pressure of from about 50 to about 1000 psia for a sufficient period of time to preferentially adsorb acid gas from the feed stream. A product gas stream is produced containing no greater than about 2 mol % carbon dioxide and at least about 65 mol % of methane recovered from the feed stream and at least about 25 mol % of ethane recovered from the feed stream. The feed stream is input at a feed end of each bed. The product gas stream is removed from a product end of each bed. The tail gas stream is vented from the feed end of each bed. The methods require lower vacuum power consumption and allow improved hydrocarbon recoveries compared with known methods.

Embodiments of the present disclose provide a method of sorbing one or more compounds from a fluid, wherein the method may include contacting a M-soc-MOF composition with a fluid containing at least H.sub.2S and one or more of CO.sub.2 and CH.sub.4; and sorbing at least H.sub.2S from the fluid. Embodiments of the present disclosure provide a membrane that may include a metal-organic framework (MOF) composition, wherein the MOF composition includes a M-soc-MOF composition, where M is a metal and soc is a square-octahedral topology, and wherein the M-soc-MOF composition is a continuous thin film on a support.

Use of pyrolysis oil (commonly referred to as bio-oil, bio-crude or tire oil) in combination with naphtha or liquified petroleum gas (LPG) can be utilized to reduce viscosity, increase API gravity and/or liquify paraffin and/or asphaltene in heavy crude oil at a reduced, overall percentage of naphtha.

Terpene, citrus isolates and/or non-ionic surfactants can be added to pyrolysis oil to form an additive. The additive can be combined with naphtha or LPG and added to heavy crude oil to reduce viscosity, increase API gravity, and/or liquify paraffin and/or asphaltene at a reduced, overall percentage of naphtha.

Embodiments of the present disclosure describe a method of sorbing one or more compounds from a H.sub.2S-containing fluid comprising contacting a M-soc-MOF composition with a fluid containing at least H.sub.2S and one or more C.sub.2+ compounds; and sorbing at least one of the one or more C.sub.2+ compounds from the fluid. Embodiments of the present disclosure further describe a method of sorbing one or more compounds from a fluid comprising contacting a M-soc-MOF composition with a fluid containing at least H.sub.2S and one or more of CO.sub.2 and CH.sub.4; and sorbing at least H.sub.2S from the fluid.