Patent classifications
C10L9/08
LOW-WATER-INTENSITY BIOCARBON PRODUCTS, AND PROCESSES FOR PRODUCING LOW-WATER-INTENSITY BIOCARBON PRODUCTS
The processes disclosed herein are environmentally friendly technologies to produce biocarbon products with low water intensity as well as low carbon intensity. Some variations provide a low-water-intensity process for producing a biocarbon product, comprising: providing a starting feedstock comprising biomass and water; drying the starting feedstock to generate a dried feedstock and a first vapor; pyrolyzing the dried feedstock to generate hot solids and a second vapor; condensing the first vapor to generate a first condensed liquid having a first pH from about 1 to about 7; condensing the second vapor to generate a second condensed liquid having a second pH from about 1 to about 7; forming acid water comprising the first condensed liquid, the second condensed liquid, or a mixture thereof; washing and cooling the hot solids using the acid water, to generate washed, cooled solids; and recovering the washed, cooled solids as a low-water-intensity biocarbon product.
DIESEL-SOLUBLE LIGNIN OILS AND METHODS OF THEIR PRODUCTION
Solvent consumption in supercritical ethanol, propanol or butanol treatment of either refined pre-extracted lignin or comparatively impure lignin-rich solid residual from hydrothermally pretreated lignocellulosic biomass can be minimized by conducting the reaction at very high loading of lignin to solvent. Comparatively impure, crude lignin-rich solid residual can be directly converted by supercritical alcohol treatment to significantly diesel-soluble lignin oil without requirement for pre-extraction or pre-solubilisation of lignin or for added reaction promoters such as catalysts, hydrogen donor co-solvents, acids, based or H2 gas. O:C ratio of product oil can readily be obtained using crude lignin residual in such a process at levels 0.20 or lower.
Methods of producing calcined coke from bio-oil and calcined coke produced thereby
Disclosed are methods of producing calcined coke from bio-oil from a biomass feedstock. Also disclosed are calcined cokes produced by such methods.
Methods of producing calcined coke from bio-oil and calcined coke produced thereby
Disclosed are methods of producing calcined coke from bio-oil from a biomass feedstock. Also disclosed are calcined cokes produced by such methods.
METHOD AND SLURRY TREATMENT PLANT FOR REDUCING METHANE EMISSION FROM SLURRY PRODUCED IN A LIVESTOCK FARM
Disclosed is a method for reducing methane emission from slurry (2) produced in a livestock farm (1). The method comprises the steps of guiding the slurry (2) from the livestock farm (1) to a dewatering unit (12) in which the slurry (2) is at least partially dewatered by extracting a watery fraction of said slurry (13), guiding the slurry from the dewatering unit (12) to a steam dryer (3), drying the slurry in the steam dryer (3), guiding the dried slurry (4) into a pyrolysis reactor (5) to produce pyrolysis gas (6) and biochar (7) through a pyrolysis process in the pyrolysis reactor (5), guiding at least a portion of the pyrolysis gas (6) to a combustion unit (8) in which the pyrolysis gas portion is combusted to raise the temperature of the combusted pyrolysis gas (9), guiding the combusted pyrolysis gas (9) to the pyrolysis reactor (5) to drive the pyrolysis process, guiding the combusted pyrolysis gas (9) from the pyrolysis reactor (5) to the steam dryer (3) to increase the temperature of steam (10) in the steam dryer (3), and heating the watery fraction of the slurry 13 to a temperature at least above 75° Celsius by means of the steam (10) from said steam dryer (3). Furthermore, a slurry treatment plant (20) for reducing methane emission from slurry (2) is disclosed.
Coal powder pretreatment method and coal powder gasification method
Disclosed are a pulverized coal preprocessing method and a pulverized coal gasifying method. The pulverized coal preprocessing method comprises the following steps: (1) performing pore broadening on pulverized coal to obtain preprocessed pulverized coal; (2) loading alkali metal ions into the preprocessed pulverized coal under an ion exchange condition to obtain alkali metal loaded pulverized coal. The method further comprises loading a chrome complex into the alkali metal loaded pulverized coal obtained in described step (2). In gasification, the pulverized coal loaded with alkali metal potassium and chrome catalysts obtained by the method has the advantages of high sulphur removal rate, high carbon conversion rate, short gasifying reaction time and high methane production.
Process for beneficiating and cleaning biomass
A process for cleaning and beneficiating biomass is described which may allow removal of entrained salts and light volatiles from biomass materials. The process may also minimize energy use through capturing steam and flue gases for re-use. The process may generally comprise the following steps: prewashing and/or preheating a biomass, pressurizing the biomass in a steam explosion vessel, rapidly depressurizing the steam explosion vessel, releasing the steam from the steam explosion vessel entrained with fine lignin-enriched particles into a cyclone-type gas expansion vessel, routing the steam from the gas expansion vessel to the input hopper, subjecting the biomass to a second washing step, mechanically removing a portion of the water from the biomass, and evaporatively heating the biomass.
Process for beneficiating and cleaning biomass
A process for cleaning and beneficiating biomass is described which may allow removal of entrained salts and light volatiles from biomass materials. The process may also minimize energy use through capturing steam and flue gases for re-use. The process may generally comprise the following steps: prewashing and/or preheating a biomass, pressurizing the biomass in a steam explosion vessel, rapidly depressurizing the steam explosion vessel, releasing the steam from the steam explosion vessel entrained with fine lignin-enriched particles into a cyclone-type gas expansion vessel, routing the steam from the gas expansion vessel to the input hopper, subjecting the biomass to a second washing step, mechanically removing a portion of the water from the biomass, and evaporatively heating the biomass.
Biomass treatment method
Provided is a novel carbonization treatment method for carbonizing a biomass material containing a large amount of water at an extremely low temperature, and a method for producing carbonized biomass. A water-containing biomass material is carbonized while maintaining the biomass material under treatment conditions including an oxygen-containing atmosphere and a temperature range of 70° C. or greater and less than 100° C., without a drying step for removing or reducing the water forcibly. At this time, preferably the water content (percentage) of the biomass material at the start of carbonization while maintained under the treatment conditions is within a range of 40 to 80% inclusive, and preferably the biomass material is thus maintained for two weeks or longer. Further, as the biomass material, one material or a mixture of two or more materials selected from waste biomass materials and plant (cultivated crop) biomass materials such as food waste, livestock excrement, agricultural waste, marine waste, and forest waste, can be applied.
Biomass treatment method
Provided is a novel carbonization treatment method for carbonizing a biomass material containing a large amount of water at an extremely low temperature, and a method for producing carbonized biomass. A water-containing biomass material is carbonized while maintaining the biomass material under treatment conditions including an oxygen-containing atmosphere and a temperature range of 70° C. or greater and less than 100° C., without a drying step for removing or reducing the water forcibly. At this time, preferably the water content (percentage) of the biomass material at the start of carbonization while maintained under the treatment conditions is within a range of 40 to 80% inclusive, and preferably the biomass material is thus maintained for two weeks or longer. Further, as the biomass material, one material or a mixture of two or more materials selected from waste biomass materials and plant (cultivated crop) biomass materials such as food waste, livestock excrement, agricultural waste, marine waste, and forest waste, can be applied.