Disclosed herein are polyketone triglyceride compositions containing 8 to 16 ketone carbonyl moieties per triglyceride unit and methods of making. Also disclosed are polyimine triglyceride compositions having has 8 to 16 nitrogen moieties per triglyceride unit and methods of making. Also disclosed are polyamine triglyceride compositions containing 8 to 16 nitrogen moieties per triglyceride unit and methods of making.

There is provided a fluorine-containing ether compound represented by the following formula. R.sup.1—R.sup.2—CH.sub.2—R.sup.3—CH.sub.2—OCH.sub.2CH(OH)CH.sub.2O—CH.sub.2—R.sup.3—CH.sub.2—R.sup.4—R.sup.5 (in the formula, R.sup.3 represents a perfluoropolyether chain; R.sup.2 and R.sup.4 represent a divalent linking group having a polar group and may be the same or different from each other; R.sup.1 and R.sup.5 represent a terminal group bonded to an oxygen atom of R.sup.2 or R.sup.4 and may be the same or different from each other; and at least one of R.sup.1 and R.sup.5 is an organic group having 1 to 8 carbon atoms and at least one of hydrogens included in the organic group is substituted by a cyano group).

There is provided a fluorine-containing ether compound represented by the following formula. R.sup.1—R.sup.2—CH.sub.2—R.sup.3—CH.sub.2—OCH.sub.2CH(OH)CH.sub.2O—CH.sub.2—R.sup.3—CH.sub.2—R.sup.4—R.sup.5 (in the formula, R.sup.3 represents a perfluoropolyether chain; R.sup.2 and R.sup.4 represent a divalent linking group having a polar group and may be the same or different from each other; R.sup.1 and R.sup.5 represent a terminal group bonded to an oxygen atom of R.sup.2 or R.sup.4 and may be the same or different from each other; and at least one of R.sup.1 and R.sup.5 is an organic group having 1 to 8 carbon atoms and at least one of hydrogens included in the organic group is substituted by a cyano group).

An ionic liquid comprising: a cation (or conjugate acid), wherein the cation (or conjugate acid) is represented by General Formula (A) below or General Formula (B) below or General Formula (C) or General Formula (D) below or General Formula (E) below: ##STR00001## wherein R.sub.1 represents CH.sub.2CH.sub.2(CF.sub.2).sub.nCF.sub.3, where n is an integer ranging from 0 to 7, or an alkyl chain CH.sub.3, or CH.sub.2OH, or CH.sub.2CH.sub.2OH; R.sub.2 represents CH.sub.2CH.sub.2(CF.sub.2).sub.nCF.sub.3, where n is an integer ranging from 0 to 7, or a hydrogen atom H, or CH.sub.2OH, or CH.sub.2CH.sub.2OH; and R.sub.3 represents CH.sub.2CH.sub.2(CF.sub.2).sub.nCF.sub.3, where n is an integer ranging from 0 to 7.

Disclosed herein are polyketone triglyceride compositions containing 8 to 16 ketone carbonyl moieties per triglyceride unit and methods of making. Also disclosed are polyimine triglyceride compositions having has 8 to 16 nitrogen moieties per triglyceride unit and methods of making. Also disclosed are polyamine triglyceride compositions containing 8 to 16 nitrogen moieties per triglyceride unit and methods of making.

A coated sliding member 10 for use under an environment where it is in contact with lubricant, comprising: a base material 12; and a first hard carbon layer 14 having a thickness of 3 μm or more formed on a surface of the base material by a vacuum arc method using carbon and consisting of diamond-like carbon, containing substantially no hydrogen and being configured only of carbon, and a second hard carbon layer 15 formed on a surface of the first hard carbon layer by a vacuum arc method using carbon and consisting of diamond-like carbon, containing substantially no hydrogen and being configured only of carbon and nitrogen, the film thickness of the second hard carbon layer being 3 to 35% of the film thickness of the first hard carbon layer.

A coated sliding member 10 for use under an environment where it is in contact with lubricant, comprising: a base material 12; and a first hard carbon layer 14 having a thickness of 3 μm or more formed on a surface of the base material by a vacuum arc method using carbon and consisting of diamond-like carbon, containing substantially no hydrogen and being configured only of carbon, and a second hard carbon layer 15 formed on a surface of the first hard carbon layer by a vacuum arc method using carbon and consisting of diamond-like carbon, containing substantially no hydrogen and being configured only of carbon and nitrogen, the film thickness of the second hard carbon layer being 3 to 35% of the film thickness of the first hard carbon layer.

An industrial oil composition contains a mineral or a synthetic oil as a base oil, and a neutral phosphite ester derivative represented by the following formula (B) and a 2,6-di-t-butylphenol derivative represented by the following formula (C) as antioxidants. In the formula (B), R.sup.b21 to R.sup.b24 each independently represent an aliphatic hydrocarbon group of 10 to 16 carbon atoms. In the formula (C), R.sup.c1 represents a straight-chain or a branched alkyl group of 1 to 12 carbon atoms.

##STR00001##

##STR00002##

An industrial oil composition contains a mineral or a synthetic oil as a base oil, and a neutral phosphite ester derivative represented by the following formula (B) and a 2,6-di-t-butylphenol derivative represented by the following formula (C) as antioxidants. In the formula (B), R.sup.b21 to R.sup.b24 each independently represent an aliphatic hydrocarbon group of 10 to 16 carbon atoms. In the formula (C), R.sup.c1 represents a straight-chain or a branched alkyl group of 1 to 12 carbon atoms.

##STR00001##

##STR00002##

The present disclosure describes a strategy to create self-healing, slippery liquid-infused porous surfaces. Roughened (e.g., porous) surfaces can be utilized to lock in place a lubricating fluid, referred to herein as Liquid B to repel a wide range of materials, referred to herein as Object A (Solid A or Liquid A). Slippery liquid-infused porous surfaces outperforms other conventional surfaces in its capability to repel various simple and complex liquids (water, hydrocarbons, crude oil and blood), maintain low-contact-angle hysteresis (<2.5°), quickly restore liquid-repellency after physical damage (within 0.1-1 s), resist ice, microorganisms and insects adhesion, and function at high pressures (up to at least 690 atm). Some exemplary application where slippery liquid-infused porous surfaces will be useful include energy-efficient fluid handling and transportation, optical sensing, medicine, and as self-cleaning, and anti-fouling materials operating in extreme environments.