Medical articles formed from a polyurethane-based resin including a modifying oligomer provide enhanced properties. A modifying oligomer incorporated into a backbone, as a side chain, or both of the polyurethane-based resin formed by a diisocyanate, a polyglycol, and a diol chain extender has at least one, preferably two, alcohol moieties (C—OH) and a functional moiety. Exemplary modifying oligomers are: a diol-containing perfluoropolyether incorporated into the backbone, a monofunctional polysiloxane (e.g., monodialcohol-terminated polydimethylsiloxane) incorporated as the side chain, and combinations thereof. Medical articles herein are self-lubricating and/or anti-fouling.

Medical articles formed from a polyurethane-based resin including a modifying oligomer provide enhanced properties. A modifying oligomer incorporated into a backbone, as a side chain, or both of the polyurethane-based resin formed by a diisocyanate, a polyglycol, and a diol chain extender has at least one, preferably two, alcohol moieties (C—OH) and a functional moiety. Exemplary modifying oligomers are: a diol-containing perfluoropolyether incorporated into the backbone, a monofunctional polysiloxane (e.g., monodialcohol-terminated polydimethylsiloxane) incorporated as the side chain, and combinations thereof. Medical articles herein are self-lubricating and/or anti-fouling.

Medical articles formed from a polyurethane-based resin including a modifying oligomer provide enhanced properties. A modifying oligomer incorporated into a backbone, as a side chain, or both of the polyurethane-based resin formed by a diisocyanate, a polyglycol, and a diol chain extender has at least one, preferably two, alcohol moieties (C—OH) and a functional moiety. Exemplary modifying oligomers are: a diol-containing perfluoropolyether incorporated into the backbone, a monofunctional polysiloxane (e.g., monodialcohol-terminated polydimethylsiloxane) incorporated as the side chain, and combinations thereof. Medical articles herein are self-lubricating and/or anti-fouling.

Medical articles formed from a polyurethane-based resin including a modifying oligomer provide enhanced properties. A modifying oligomer incorporated into a backbone, as a side chain, or both of the polyurethane-based resin formed by a diisocyanate, a polyglycol, and a diol chain extender has at least one, preferably two, alcohol moieties (C—OH) and a functional moiety. Exemplary modifying oligomers are: a diol-containing perfluoropolyether incorporated into the backbone, a monofunctional polysiloxane (e.g., monodialcohol-terminated polydimethylsiloxane) incorporated as the side chain, and combinations thereof. Medical articles herein are self-lubricating and/or anti-fouling.

This disclosure provides low viscosity, low volatility alkylated siloxane compounds and alkylated alkoxy silane compounds. This disclosure also provides processes for producing the alkylated siloxane compounds and alkylated alkoxy silane compounds, and lubricating oil basestocks and lubricating oils containing one or more of the alkylated siloxane compounds or one or more of the alkylated alkoxy silane compounds. This disclosure further provides a method for improving one or more of solubility and dispersancy of polar additives and/or sludge in a lubricating oil by using as the lubricating oil a formulated oil containing one or more of the alkylated siloxane compounds or one or more of the alkylated alkoxy silane compounds.

This disclosure provides low viscosity, low volatility alkylated siloxane compounds and alkylated alkoxy silane compounds. This disclosure also provides processes for producing the alkylated siloxane compounds and alkylated alkoxy silane compounds, and lubricating oil basestocks and lubricating oils containing one or more of the alkylated siloxane compounds or one or more of the alkylated alkoxy silane compounds. This disclosure further provides a method for improving one or more of solubility and dispersancy of polar additives and/or sludge in a lubricating oil by using as the lubricating oil a formulated oil containing one or more of the alkylated siloxane compounds or one or more of the alkylated alkoxy silane compounds.

Disclosed is a method of lubrication including a step of lubricating a machine with a lubricating composition, the lubricating composition including 20-100% ionic liquid or of a mixture of several ionic liquids. The ionic liquid or the mixture is selected from at least: an anion A.sup.− chosen from sulfonylimides, the substituent(s) of which is (are) independently chosen from a fluoroalkyl, fluoroether, perfluorinated alkyl or perfluoroether group; and a cation C.sup.+ including a nitrogen-containing heterocycle or a quaternary ammonium, the substituent(s) of which is (are) independently chosen from: a hydrogen atom or alkyl, alkoxy, fluorinated alkyl, perfluorinated alkyl, alkylsilane, alkyl alcohol, vinyl, alkyl allyl, ether or polyether groups having a linear or branched chain having 1-3 carbon atoms. The deposition start temperature in thin film of the ionic liquid or of the mixture of ionic liquids is at least equal to 330° C. The lubricating composition reduces deposits formed in the machine.

Disclosed is a method of lubrication including a step of lubricating a machine with a lubricating composition, the lubricating composition including 20-100% ionic liquid or of a mixture of several ionic liquids. The ionic liquid or the mixture is selected from at least: an anion A.sup.− chosen from sulfonylimides, the substituent(s) of which is (are) independently chosen from a fluoroalkyl, fluoroether, perfluorinated alkyl or perfluoroether group; and a cation C.sup.+ including a nitrogen-containing heterocycle or a quaternary ammonium, the substituent(s) of which is (are) independently chosen from: a hydrogen atom or alkyl, alkoxy, fluorinated alkyl, perfluorinated alkyl, alkylsilane, alkyl alcohol, vinyl, alkyl allyl, ether or polyether groups having a linear or branched chain having 1-3 carbon atoms. The deposition start temperature in thin film of the ionic liquid or of the mixture of ionic liquids is at least equal to 330° C. The lubricating composition reduces deposits formed in the machine.

A hydrophilic slippery treatment agent which allows for the formation of a coating having hydrophilicity concurrently with water droplet removability via drying at lower temperatures, a surface treatment method using the hydrophilic slippery treatment agent, a substrate having a hydrophilic slippery coating formed thereon by the surface treatment method, and a fin material for a heat exchanger having a hydrophilic slippery coating formed thereon by the surface treatment method are provided. The treatment agent contains an organosilicon compound with a specific structure including both a hydrophilic-chain-containing group and a hydrolyzable group, and a metal alkoxide.

A hydrophilic slippery treatment agent which allows for the formation of a coating having hydrophilicity concurrently with water droplet removability via drying at lower temperatures, a surface treatment method using the hydrophilic slippery treatment agent, a substrate having a hydrophilic slippery coating formed thereon by the surface treatment method, and a fin material for a heat exchanger having a hydrophilic slippery coating formed thereon by the surface treatment method are provided. The treatment agent contains an organosilicon compound with a specific structure including both a hydrophilic-chain-containing group and a hydrolyzable group, and a metal alkoxide.