Patent classifications
C10M125/08
SLIDING SYSTEM
[Technical Problem] An object is to provide a sliding system which can achieve both the reduced friction and the enhanced wear resistance by means of a novel combination of a sliding film and a lubricant oil.
[Solution to Problem] The sliding system of the present invention comprises: a pair of sliding members having sliding surfaces that can relatively move while facing each other; and a lubricant oil interposed between the sliding surfaces facing each other. At least one of the sliding surfaces comprises a coating surface of a crystalline chromium carbide film. The lubricant oil contains an oil-soluble molybdenum compound that has a chemical structure of a trinuclear of Mo. When the chromium carbide film as a whole is 100 at %, the chromium carbide film contains 40-75 at % of Cr. The chromium carbide film in contact with the lubricant oil containing a Mo-trinuclear appears to react with the Mo-trinuclear adsorbed during the sliding to generate a layered structural body (boundary film) similar to MoS.sub.2 on the surface, thereby developing a considerably low friction property.
SLIDING SYSTEM
[Technical Problem] An object is to provide a sliding system which can achieve both the reduced friction and the enhanced wear resistance by means of a novel combination of a sliding film and a lubricant oil.
[Solution to Problem] The sliding system of the present invention comprises: a pair of sliding members having sliding surfaces that can relatively move while facing each other; and a lubricant oil interposed between the sliding surfaces facing each other. At least one of the sliding surfaces comprises a coating surface of a crystalline chromium carbide film. The lubricant oil contains an oil-soluble molybdenum compound that has a chemical structure of a trinuclear of Mo. When the chromium carbide film as a whole is 100 at %, the chromium carbide film contains 40-75 at % of Cr. The chromium carbide film in contact with the lubricant oil containing a Mo-trinuclear appears to react with the Mo-trinuclear adsorbed during the sliding to generate a layered structural body (boundary film) similar to MoS.sub.2 on the surface, thereby developing a considerably low friction property.
SLIDING MEMBER
A sliding member includes a back metal layer and a sliding layer on the back metal layer. The sliding layer includes a synthetic resin matrix and graphite particles dispersed in the matrix in a volume ratio of 5-50% of that of the sliding layer. The graphite particles are composed of spheroidal and flake-like particles. The flake-like particles have a volume ratio of 10-40% of total graphite particles. The spheroidal particles have a cross-sectional structure with a plurality of AB planes of a graphite crystal laminated along a curved particle surface, from the surface toward a center direction. The flake-like graphite particles have a cross-sectional structure with the plurality of AB planes laminated in a thickness direction of the thin plate shape. The spheroidal particles have an average particle size of 3-50 μm, and the flake-like graphite particles have an average particle size of 1-25 μm.
Composition, film formed from the composition, sliding member having the film, and method for producing the same
A film is formed by use of a composition containing (A) a binder resin, (B) a hard particle, and (C) a solid lubricant selected from the group containing molybdenum disulfide and graphite, wherein the composition contains tungsten carbide as the hard particle, and wherein weight ratio of (B) the hard particles and (C) the solid lubricant, (B)/(C), is in the range of 1 to 3.
Composition, film formed from the composition, sliding member having the film, and method for producing the same
A film is formed by use of a composition containing (A) a binder resin, (B) a hard particle, and (C) a solid lubricant selected from the group containing molybdenum disulfide and graphite, wherein the composition contains tungsten carbide as the hard particle, and wherein weight ratio of (B) the hard particles and (C) the solid lubricant, (B)/(C), is in the range of 1 to 3.
GREASE COMPOSITION FOR A CONSTANT-VELOCITY JOINT
A grease composition for a constant-velocity joint includes a mineral oil, a thickener, a molybdenum dithiocarbamate, a potassium borate hydrate, and a zinc dialkyldithiophosphate, wherein a content of the molybdenum dithiocarbamate is 1.2% by mass or more and 8% by mass or less, a content of the zinc dialkyldithiophosphate is 0.3% by mass or more and 2.0% by mass or less, and a content of the potassium borate hydrate is 0.28% by mass or more and 1.9% by mass or less, and wherein a mass ratio of the content of the molybdenum dithiocarbamate to the content of the potassium borate hydrate (molybdenum dithiocarbamate/potassium borate hydrate) is 2 or more and 13 or less, and a mass ratio of the content of the zinc dialkyldithiophosphate to the content of the potassium borate hydrate (zinc dialkyldithiophosphate/potassium borate hydrate) is 0.5 or more and 3.6 or less.
COMPOSITION, FILM FORMED FROM THE COMPOSITION, SLIDING MEMBER HAVING THE FILM, AND METHOD FOR PRODUCING THE SAME
A film is formed by use of a composition containing (A) a binder resin, (B) a hard particle, and (C) a solid lubricant selected from the group containing molybdenum disulfide and graphite, wherein the composition contains tungsten carbide as the hard particle, and wherein weight ratio of (B) the hard particles and (C) the solid lubricant, (B)/(C), is in the range of 1 to 3.
COMPOSITION, FILM FORMED FROM THE COMPOSITION, SLIDING MEMBER HAVING THE FILM, AND METHOD FOR PRODUCING THE SAME
A film is formed by use of a composition containing (A) a binder resin, (B) a hard particle, and (C) a solid lubricant selected from the group containing molybdenum disulfide and graphite, wherein the composition contains tungsten carbide as the hard particle, and wherein weight ratio of (B) the hard particles and (C) the solid lubricant, (B)/(C), is in the range of 1 to 3.
Oilfield Drilling Lubricant for Water-Based and Oil-Based Systems
This disclosure provides compositions comprising a suspension package, wherein the suspension packaging consists of solids for suspending in one or more liquids, wherein the solids comprise at least one of: (1) diamond dust, nano-diamonds, or combinations thereof; (2) tungsten; (3) graphite, graphene, or combinations thereof; and (4) silicon carbide. Further, 0.25% through 6% by volume of the composition, with the one or more liquids being present, in a 14.0 ppg aqueous CaBr.sub.2 solution, provides a coefficient of friction of less than 0.06 at a temperature between 250° F. and 400° F. at any time up through 10 minutes after combination of the 0.25% through 6% by volume of the composition to the 14.0 ppg aqueous CaBr.sub.2.
COMPOSITION AND METHOD FOR PREVENTING OR REDUCING LOW SPEED PRE-IGNITION IN DIRECT INJECTED SPARK-IGNITED ENGINES
Disclosed is a lubricating engine oil composition comprising a lubricating oil base stock as a major component, and at least one metal or metalloid hydrogen atom donor compound. Also disclosed is a method for preventing or reducing low speed pre-ignition in a direct injected, boosted, spark ignited internal combustion engine, and the use of at least one metal or metalloid hydrogen atom donor compound in a lubricating engine oil composition for preventing or reducing low speed pre-ignition in a direct injected, boosted, spark ignited internal combustion engine.