C10M143/04

Ethylene-propylene linear copolymers as viscosity modifiers

In some embodiments, ethylene-propylene random copolymers as viscosity modifiers were synthesized with pyridyldiamido catalyst systems and a chain transfer agent. In some embodiments, the present disclosure provides for ethylene-propylene random copolymers having an ethylene content between about 45 wt % and about 55 wt %. In some embodiments, the ethylene-propylene random copolymer is used as a viscosity modifier in a lubricating composition and a fuel composition.

Lubricating composition for a marine engine or a stationary engine

Disclosed is a lubricant composition including: at least one base oil; at least one olefin copolymer; at least one detergent; and at least one hydrogenated and linear styrene/butadiene copolymer. Also disclosed is the use of this composition for reducing the fuel consumption of an engine and for improving the cleanliness of a 4-stroke or 2-stroke, preferably 4-stroke marine engine, or of a stationary engine.

Lubricating composition for a marine engine or a stationary engine

Disclosed is a lubricant composition including: at least one base oil; at least one olefin copolymer; at least one detergent; and at least one hydrogenated and linear styrene/butadiene copolymer. Also disclosed is the use of this composition for reducing the fuel consumption of an engine and for improving the cleanliness of a 4-stroke or 2-stroke, preferably 4-stroke marine engine, or of a stationary engine.

LUBRICATING OIL COMPOSITIONS WITH RESISTANCE TO ENGINE DEPOSIT AND VARNISH FORMATION

A lubricating oil composition comprising greater than 50 wt. % of a base oil of lubricating viscosity, and an additive composition comprising: an amount of one or more zinc dialkyl dithiophosphates (ZDDP compounds) and an amount of one or more viscosity modifiers, wherein an amount of phosphorus (P) in weight percent provided to the lubricating oil composition by the one or more ZDDP compounds divided by the amount of the one or more viscosity modifiers (VM) in weight percent based on a total weight of the lubricating oil composition is a PNM quotient of more than about 0.0075. The lubricating oil composition can improve resistance to engine deposits and extend oil drain intervals of an internal combustion engine.

LUBRICATING OIL COMPOSITIONS WITH RESISTANCE TO ENGINE DEPOSIT AND VARNISH FORMATION

A lubricating oil composition comprising greater than 50 wt. % of a base oil of lubricating viscosity, and an additive composition comprising: an amount of one or more zinc dialkyl dithiophosphates (ZDDP compounds) and an amount of one or more viscosity modifiers, wherein an amount of phosphorus (P) in weight percent provided to the lubricating oil composition by the one or more ZDDP compounds divided by the amount of the one or more viscosity modifiers (VM) in weight percent based on a total weight of the lubricating oil composition is a PNM quotient of more than about 0.0075. The lubricating oil composition can improve resistance to engine deposits and extend oil drain intervals of an internal combustion engine.

Hydrocarbon lubricant compositions and method to make them

A lubricant composition that comprises a hydrocarbon base oil, a polar viscosity improver; and an esterified polyalkylene glycol: R.sup.1[O(R.sup.2O).sub.n(R.sup.3O).sub.m(C═O)R.sup.4].sub.p, wherein R.sup.1 is a linear alkyl having 1 to 18 carbon atoms, a branched alkyl having 4 to 18 carbon atoms or an aryl with 6 to 30 carbon atoms; R.sup.2O is an oxypropylene moiety derived from 1, 2-propylene oxide; R.sup.3O is an oxybutylene moiety derived from butylene oxide, wherein R.sup.2O and R.sup.3O are in a block or a random distribution; R.sup.4 is a linear alkyl with 1 to 18 carbon atoms, a branched alkyl with 4 to 18 carbon atoms or an aryl with 6 to 18 carbon atoms; n and m are each independently integers ranging from 0 to 20 wherein n+m is greater than 0, and p is an integer from 1 to 4. The lubricant composition may have a viscosity index of at least 150, a kinematic viscosity at 100° C. from 2 to 5 centistokes and a kinematic viscosity at −20° C. of at most 600 centistokes.

Hydrocarbon lubricant compositions and method to make them

A lubricant composition that comprises a hydrocarbon base oil, a polar viscosity improver; and an esterified polyalkylene glycol: R.sup.1[O(R.sup.2O).sub.n(R.sup.3O).sub.m(C═O)R.sup.4].sub.p, wherein R.sup.1 is a linear alkyl having 1 to 18 carbon atoms, a branched alkyl having 4 to 18 carbon atoms or an aryl with 6 to 30 carbon atoms; R.sup.2O is an oxypropylene moiety derived from 1, 2-propylene oxide; R.sup.3O is an oxybutylene moiety derived from butylene oxide, wherein R.sup.2O and R.sup.3O are in a block or a random distribution; R.sup.4 is a linear alkyl with 1 to 18 carbon atoms, a branched alkyl with 4 to 18 carbon atoms or an aryl with 6 to 18 carbon atoms; n and m are each independently integers ranging from 0 to 20 wherein n+m is greater than 0, and p is an integer from 1 to 4. The lubricant composition may have a viscosity index of at least 150, a kinematic viscosity at 100° C. from 2 to 5 centistokes and a kinematic viscosity at −20° C. of at most 600 centistokes.

Ethylene-propylene branched copolymers as viscosity modifiers with enhanced fuel economy

In some embodiments, ethylene-propylene branched copolymers are synthesized with pyridyldiamido catalysts and a chain transfer agent, and their performance as viscosity modifiers in oil are detailed. In some embodiments, the present disclosure provides for ethylene-propylene branched copolymers having a shear thinning onset of less than about 0.01 rad/s and an HTHS value of less than about 3.3. In some embodiments, the ethylene-propylene branched copolymer is used as a viscosity modifier in a lubricating composition and a fuel composition.

Lubricant composition
11473030 · 2022-10-18 · ·

The present invention relates to a lubricating oil composition containing: (A) a poly-α-olefin base oil obtained by using a metallocene catalyst; (B) a mineral oil-based base oil exhibiting a distillation curve with a temperature gradient Δ|Dt| of distillation temperature between two points 2.0 vol % and 5.0 vol % of distillation amount being 6.8° C./vol % or less; and (C) an ester-based base oil in an amount of 6% by mass or more based on a total amount of the composition.

ENGINE OIL FORMULATION WITH IMPROVED SEQUENCE VIII PERFORMANCE

The present disclosure relates to methods of improving viscosity shear stability of a lubricating oil and lubricating oil composition comprising: a base oil of lubricating viscosity; an amount of one or more zinc dialkyl dithiophosphate compound(s);
wherein the lubricating oil composition has one or both of the following ratios: a) a ratio of KV40° C..sub.fresh to a weight % of zinc contributed by the one or more zinc dialkyl dithiophosphate compound(s) based on a total weight of the lubricating oil composition, of greater than 510, wherein KV40° C..sub.fresh is the kinematic viscosity of the fresh lubricating oil composition at 40° C.; and b) a ratio of KV40° C..sub.fresh to a weight % of phosphorus contributed by the one or more zinc dialkyl dithiophosphate compound(s) based on a total weight of the lubricating oil composition, of greater than 560, wherein KV40° C..sub.fresh is the kinematic viscosity of the fresh lubricating oil composition at 40° C.