Patent classifications
C10M145/38
Engine oil lubricant compositions and methods for making same with superior engine wear protection and corrosion protection
Provided is an engine oil lubricant composition with improved fuel efficiency and engine wear protection. The lubricant composition may include a major amount of an oil basestock from any one or more Group I, Group II, Group III, Group IV or Group V base oils. The resulting engine oil lubricant composition may have a kinematic viscosity at 100° C. of 6 cSt or less, and a corrosion protection of at least 90, as measured according the ASTM D6557 Ball Rust Test. The resulting engine oil lubricant composition may also have a kinematic viscosity at 100° C. of 6 cSt or less, an HTHS (ASTM D4683) of less than or equal to 2.2 cP at 150° C. and a FZG failure load stage of at least 6, as measured by the FZG A10/16.6R/130 test procedure.
Hydrocarbon lubricant compositions and method to make them
A lubricant composition that comprises a hydrocarbon base oil, a polar viscosity improver; and an esterified polyalkylene glycol: R.sup.1[O(R.sup.2O).sub.n(R.sup.3O).sub.m(C═O)R.sup.4].sub.p, wherein R.sup.1 is a linear alkyl having 1 to 18 carbon atoms, a branched alkyl having 4 to 18 carbon atoms or an aryl with 6 to 30 carbon atoms; R.sup.2O is an oxypropylene moiety derived from 1, 2-propylene oxide; R.sup.3O is an oxybutylene moiety derived from butylene oxide, wherein R.sup.2O and R.sup.3O are in a block or a random distribution; R.sup.4 is a linear alkyl with 1 to 18 carbon atoms, a branched alkyl with 4 to 18 carbon atoms or an aryl with 6 to 18 carbon atoms; n and m are each independently integers ranging from 0 to 20 wherein n+m is greater than 0, and p is an integer from 1 to 4. The lubricant composition may have a viscosity index of at least 150, a kinematic viscosity at 100° C. from 2 to 5 centistokes and a kinematic viscosity at −20° C. of at most 600 centistokes.
Hydrocarbon lubricant compositions and method to make them
A lubricant composition that comprises a hydrocarbon base oil, a polar viscosity improver; and an esterified polyalkylene glycol: R.sup.1[O(R.sup.2O).sub.n(R.sup.3O).sub.m(C═O)R.sup.4].sub.p, wherein R.sup.1 is a linear alkyl having 1 to 18 carbon atoms, a branched alkyl having 4 to 18 carbon atoms or an aryl with 6 to 30 carbon atoms; R.sup.2O is an oxypropylene moiety derived from 1, 2-propylene oxide; R.sup.3O is an oxybutylene moiety derived from butylene oxide, wherein R.sup.2O and R.sup.3O are in a block or a random distribution; R.sup.4 is a linear alkyl with 1 to 18 carbon atoms, a branched alkyl with 4 to 18 carbon atoms or an aryl with 6 to 18 carbon atoms; n and m are each independently integers ranging from 0 to 20 wherein n+m is greater than 0, and p is an integer from 1 to 4. The lubricant composition may have a viscosity index of at least 150, a kinematic viscosity at 100° C. from 2 to 5 centistokes and a kinematic viscosity at −20° C. of at most 600 centistokes.
Coating composition, method of making a hydrophilic coating on a substrate, and medical device comprising such coating
The disclosure relates to a coating composition comprising a polymerizable compound of formula [1], wherein G is a residue of a hydrophobic hydroxy-functional oligomer, n is 1-10, each R1 independently is a residue of a C.sub.6-C.sub.20 aliphatic, cycloaliphatic, or aromatic hydrocarbon compound, and Z is a moiety having a polymerizable group; Formula [1] a hydrophilic polymer; a photo-initiator; optionally one or more further components, and a solvent. The polymerizable compound of formula [1] is typically present in an amount of 2.0-30 mass % based on total dry mass of the composition. Such coating composition can be made into a well-adhering single-layer hydrophilic coating on a surface of polymer substrates without providing a primer layer or chemically modifying the surface of the substrate. Upon wetting, the coating shows excellent lubricity and durability. In further aspects, the disclosure provides a method of applying a hydrophilic and optionally lubricious coating to an article; and an article like a medical device having on at least part of its surface a single-layer, hydrophilic and optionally lubricious coating, like a catheter, guidewire, or a delivery device for an implant.
##STR00001##
Coating composition, method of making a hydrophilic coating on a substrate, and medical device comprising such coating
The disclosure relates to a coating composition comprising a polymerizable compound of formula [1], wherein G is a residue of a hydrophobic hydroxy-functional oligomer, n is 1-10, each R1 independently is a residue of a C.sub.6-C.sub.20 aliphatic, cycloaliphatic, or aromatic hydrocarbon compound, and Z is a moiety having a polymerizable group; Formula [1] a hydrophilic polymer; a photo-initiator; optionally one or more further components, and a solvent. The polymerizable compound of formula [1] is typically present in an amount of 2.0-30 mass % based on total dry mass of the composition. Such coating composition can be made into a well-adhering single-layer hydrophilic coating on a surface of polymer substrates without providing a primer layer or chemically modifying the surface of the substrate. Upon wetting, the coating shows excellent lubricity and durability. In further aspects, the disclosure provides a method of applying a hydrophilic and optionally lubricious coating to an article; and an article like a medical device having on at least part of its surface a single-layer, hydrophilic and optionally lubricious coating, like a catheter, guidewire, or a delivery device for an implant.
##STR00001##
Completion Fluid Friction Reducer
A method and composition for reducing a coefficient of friction are disclosed. In an embodiment, a method for reducing a coefficient of friction between two surfaces in a borehole includes preparing a mixture comprising a primary lubricating agent, a primary surfactant, a spreading agent, and an aqueous fluid. The method also includes pumping the mixture into the borehole such that the mixture contacts the two surfaces and reduces the coefficient of friction for the two surfaces.
Modified oil soluble polyalkylene glycols
The present disclosure provides for a lubricant formulation and a method of forming the lubricant formulation for use in an internal combustion engine. The lubricant formulation includes a base oil and an esterified oil-soluble polyalkylene glycol (E-OSP) of Formula (I): R.sup.1 [O(R.sup.2O).sub.n(R.sup.3O).sub.m(C═O)R.sup.4].sub.p wherein R.sup.1 is a linear alkyl having 1 to 18 carbon atoms, a branched alkyl having 4 to 18 carbon atoms or an aryl with 6 to 30 carbon atoms; R.sup.2O is an oxypropylene moiety derived from 1, 2-propylene oxide; R.sup.3O is an oxybutylene moiety derived from butylene oxide, wherein R.sup.2O and R.sup.3O are in a block or a random distribution; R.sup.4 is a linear alkyl with 1 to 18 carbon atoms, a branched alkyl with 4 to 18 carbon atoms or an aryl with 6 to 18 carbon atoms; n and m are each independently integers ranging from 0 to 20 wherein n+m is greater than 0, and p is an integer from 1 to 4.
Modified oil soluble polyalkylene glycols
The present disclosure provides for a lubricant formulation and a method of forming the lubricant formulation for use in an internal combustion engine. The lubricant formulation includes a base oil and an esterified oil-soluble polyalkylene glycol (E-OSP) of Formula (I): R.sup.1 [O(R.sup.2O).sub.n(R.sup.3O).sub.m(C═O)R.sup.4].sub.p wherein R.sup.1 is a linear alkyl having 1 to 18 carbon atoms, a branched alkyl having 4 to 18 carbon atoms or an aryl with 6 to 30 carbon atoms; R.sup.2O is an oxypropylene moiety derived from 1, 2-propylene oxide; R.sup.3O is an oxybutylene moiety derived from butylene oxide, wherein R.sup.2O and R.sup.3O are in a block or a random distribution; R.sup.4 is a linear alkyl with 1 to 18 carbon atoms, a branched alkyl with 4 to 18 carbon atoms or an aryl with 6 to 18 carbon atoms; n and m are each independently integers ranging from 0 to 20 wherein n+m is greater than 0, and p is an integer from 1 to 4.
Lubricant additive, lubricant additive composition, and lubricating oil composition containing the same
A lubricant additive includes a monoester carboxylic acid salt (A) represented by formula (1). ##STR00001## In formula (1), R.sup.1 represents a single bond between carbon atoms of carbonyl groups, or a divalent hydrocarbon group having 1 to 4 carbon atoms, and R.sup.2 represents a hydrocarbon group having 1 to 22 carbon atoms. AO represents an oxyalkylene group of one type selected from oxyalkylene groups having 2 to 4 carbon atoms, or a mixed oxyalkylene group of two or more types selected from oxyalkylene groups having 2 to 4 carbon atoms, and n is an average number of added moles of the oxyalkylene group represented by AO and is 0 to 5. M represents organic ammonium.
LUBRICANT ADDITIVE, LUBRICANT ADDITIVE COMPOSITION, AND LUBRICATING OIL COMPOSITION CONTAINING THE SAME
A lubricant additive includes a monoester carboxylic acid salt (A) represented by formula (1).
##STR00001##
In formula (1), R.sup.1 represents a single bond between carbon atoms of carbonyl groups, or a divalent hydrocarbon group having 1 to 4 carbon atoms, and R.sup.2 represents a hydrocarbon group having 1 to 22 carbon atoms. AO represents an oxyalkylene group of one type selected from oxyalkylene groups having 2 to 4 carbon atoms, or a mixed oxyalkylene group of two or more types selected from oxyalkylene groups having 2 to 4 carbon atoms, and n is an average number of added moles of the oxyalkylene group represented by AO and is 0 to 5. M represents organic ammonium.