Patent classifications
C10M2203/024
CIRCULAR ECONOMY FOR PLASTIC WASTE TO POLYETHYLENE AND LUBRICATING OIL VIA CRUDE AND ISOMERIZATION DEWAXING UNITS
Provided is a continuous process for converting waste plastic into recycle for polyethylene polymerization. In one embodiment, the process comprises selecting waste plastics containing polyethylene and/or polypropylene and passing the waste plastics through a pyrolysis reactor to thermally crack at least a portion of the polyolefin waste and produce a pyrolyzed effluent. The pyrolyzed effluent is separated into offgas, a naphtha/diesel fraction, a heavy fraction, and char. The naphtha/diesel fraction is passed to a crude unit distillation column in a refinery where a straight run naphtha (C.sub.5-C.sub.8) fraction or a propane/butane (C.sub.3-C.sub.4) fraction is recovered. The straight run naphtha fraction (C.sub.5-C.sub.8) or the propane/butane (C.sub.3-C.sub.4) fraction is passed to a steam cracker for ethylene production. The heavy fraction from the pyrolysis unit can also be passed to an isomerization dewaxing unit to produce a base oil.
GREASE, ANTIFRICTION BEARING, ANTIFRICTION BEARING DEVICE, AND INFORMATION RECORDING/REPRODUCING DEVICE
The invention has an object of providing grease reduced in an amount of the flying grease and an amount of the outgas, and superior in low-temperature characteristic, an antifriction bearing using the grease, an antifriction bearing device, and an information recording/reproducing device. A grease includes a base oil, and a thickener, the base oil includes mineral oil and poly-α-olefin, the poly-α-olefin is higher in mass than the mineral oil, the poly-α-olefin includes poly-α-olefin higher in kinetic viscosity than the mineral oil, the kinetic viscosity of the base oil at 40° C. is in a range of 40 through 90 mm.sup.2/s, and worked penetration is in a range of 200 through 250. Further, an antifriction bearing, an antifriction bearing device, and an information recording/reproducing device use the grease.
Use of Organometallic Salt Compositions for Alleviating the Formation of White Etching Cracks
The present invention relates to the use of organometallic salt compositions as lubricant additives and/or lubricant additive compositions to alleviate the formation of white etching cracks (WEC).
COMPOSITIONS COMPRISING A FLUOROOLEFIN
The present invention relates to compositions for use in refrigeration, air-conditioning, and heat pump systems wherein the composition comprises a fluoroolefin and at least one other component. The compositions of the present invention are useful in processes for producing cooling or heat, as heat transfer fluids, foam blowing agents, aerosol propellants, and fire suppression and fire extinguishing agents.
RENEWABLE ALKENE PRODUCTION ENGAGING METATHESIS
Herein is provided a process for producing renewable products, such as alkenes, from a feedstock of biological origin. The process includes subjecting a feedstock including fatty acid glycerides and optionally free fatty acids, wherein at least one hydrocarbon chain is unsaturated, to esterification reaction in the presence of an alcohol. The ester stream thereby obtained is then fractionated and a fraction including esters of unsaturated C18 fatty acids is subjected to metathesis conditions in the presence of an alkene to obtain metathesis products. Fractionation of the metathesis products includes recovery of at least renewable 1-decene, and unsaturated C10-C15 fatty acid esters.
RENEWABLE BASE OIL PRODUCTION ENGAGING METATHESIS
A process is disclosed for producing renewable products, such as a renewable base oil, from a feedstock of biological origin. The process includes subjecting a feedstock containing free fatty acids and fatty acid glycerides, wherein at least one hydrocarbon chain is unsaturated, to esterification reaction in the presence of an alcohol. An ester stream thereby obtained is then subjected to metathesis conditions in the presence of a renewable alkene to obtain a metathesis product. Separation of the metathesis product includes recovery of a fraction containing or consisting essentially of C16 fatty acid esters, which is subjected to ketonisation reaction conditions to produce long chain ketones, which after hydrotreatment meet requirements for a renewable base oil. Ketonisation reaction produces renewable alkene usable in metathesis reaction.
Method of Producing Lube Base Oil from Middle Distillate in Pyrolysis Oil Derived from Waste Plastic
Provided are a method of producing a Lube base oil composition including a) reacting at least a part of waste plastic pyrolysis oil having a boiling point in a range of 180 to 340° C. to remove impurities and oligomerize the oil; and b) hydroisomerizing at least a part of the product of step a). A lube base oil composition is also produced therefrom.
Base oils and methods of making the same
Aspects of the present disclosure relate to a process for producing synthetic hydrocarbon base oils having advantageous properties for formulation of engine oils, and the base oils obtained by such processes, involving the production of branched alkenes from the oligomerization of C14-C18 olefins. According to one embodiment, the base oils are obtained by first forming a mixture of two or more olefins ranging from C14-C18, where one of the olefins is an alpha olefin and the other has an average double bond position between 1.5-5.0, and oligomerizing this mixture in the presence of a catalyst to form one or more branched alkenes, hydrogenating the branched alkenes, and fractionating to form base oils. According to one aspect, advantageous properties can be obtained by controlling one or more of the degree of branching, branch length, branching positions, selection of the C14-C18 olefins, and catalytic isomerization, during or after the oligomerization process.
Circular economy for plastic waste to polyethylene and lubricating oil via crude and isomerization dewaxing units
Provided is a continuous process for converting waste plastic into recycle for polyethylene polymerization. In one embodiment, the process comprises selecting waste plastics containing polyethylene and/or polypropylene and passing the waste plastics through a pyrolysis reactor to thermally crack at least a portion of the polyolefin waste and produce a pyrolyzed effluent. The pyrolyzed effluent is separated into offgas, a naphtha/diesel fraction, a heavy fraction, and char. The naphtha/diesel fraction is passed to a crude unit distillation column in a refinery where a straight run naphtha (C.sub.5-C.sub.8) fraction or a propane/butane (C.sub.3-C.sub.4) fraction is recovered. The straight run naphtha fraction (C.sub.5-C.sub.8) or the propane/butane (C.sub.3-C.sub.4) fraction is passed to a steam cracker for ethylene production. The heavy fraction from the pyrolysis unit can also be passed to an isomerization dewaxing unit to produce a base oil.
LUBRICANT COMPOSITION INHIBITING ADSORPTION OF ALPHA-OLEFIN, AND METHOD AND AGENT FOR INHIBITING ADSORPTION OF ALPHA-OLEFIN
A method for inhibiting adsorption of α-olefin in a lubricant composition to a metal surface is disclosed. The lubricant composition comprises any of oils of Group III, Group IV and polyisobutylenes classified into Group V according to the API base oil classification or a mixture thereof as a base oil, and the α-olefin coexisting in an amount of 1% by mass or less based on the total amount of the composition. The method comprises adding a sarcosinic acid derivative, an aspartic acid derivative or a diethanolamine derivative, or a mixture thereof to the lubricant composition.