The invention relates to a composition preparation method for preparing a composition of estolides, the method comprising reacting an unsaturated compound of a type such as an acid or ester, with a saturated fatty acid; in the presence of a catalyst of a type such as sulphonic acid, the said method including no vacuum distillation step thereby making it possible to separate the monoestolides from the polyestolides. The invention also relates to a composition of estolides that is obtainable by the method according to the invention and the use thereof in lubricating compositions.

A lithium complex hybrid grease is based on a lithium complex grease in combination with a PFPE grease. The lithium complex hybrid grease can be used at higher temperatures, does not form layers in the process, and exhibits a low hardening tendency. The lithium complex hybrid grease is usable in components in the automotive field and in the industrial field.

Compositions are obtained by mixing at least one oligomer A1, which is obtained by copolymerizing at least two monomers functionalized by diol functions with at least one second monomer, with at least one compound A2 having at least two boron ester functions. The compositions exhibit very varied rheological properties depending on the proportion of the compounds A1 and A2 used. A composition is also obtained by mixing at least one lubricating oil with such a composition of associative and exchangeable polymers, and the use of this composition to lubricate a mechanical part.

Compositions are obtained by mixing at least one oligomer A1, which is obtained by copolymerizing at least two monomers functionalized by diol functions with at least one second monomer, with at least one compound A2 having at least two boron ester functions. The compositions exhibit very varied rheological properties depending on the proportion of the compounds A1 and A2 used. A composition is also obtained by mixing at least one lubricating oil with such a composition of associative and exchangeable polymers, and the use of this composition to lubricate a mechanical part.

The invention relates to a composition preparation method for preparing a composition of estolides, the method comprising reacting an unsaturated compound of a type such as an acid or ester, with a saturated fatty acid; in the presence of a catalyst of a type such as sulphonic acid, the said method including no vacuum distillation step thereby making it possible to separate the monoestolides from the polyestolides. The invention also relates to a composition of estolides that is obtainable by the method according to the invention and the use thereof in lubricating compositions.

Provided herein are processes for preparing estolides and estolide base oils from fatty acid reactants utilizing catalysts. Further provided herein are processes for preparing carboxylic esters from at least one carboxylic acid reactant and at least one olefin.

Provided herein are processes for preparing estolides and estolide base oils from fatty acid reactants utilizing catalysts. Further provided herein are processes for preparing carboxylic esters from at least one carboxylic acid reactant and at least one olefin.

Provided herein are compounds of the formula:

##STR00001##

in which n is an integer equal to or greater than 1; R.sub.2 is selected from hydrogen and optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; and R.sub.1, R.sub.3, and R.sub.4, independently for each occurrence, are selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched, wherein compositions comprising the compounds are characterized by particular combinations of values for estolide number, kinematic viscosity, and pour point. Also provided are compositions containing the compounds and methods of making both the compounds and compositions thereof.

Provided herein are compounds of the formula: ##STR00001##
in which n is an integer equal to or greater than 1; R.sub.2 is selected from hydrogen and optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; and R.sub.1, R.sub.3, and R.sub.4, independently for each occurrence, are selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched, wherein compositions comprising the compounds are characterized by particular combinations of values for estolide number, kinematic viscosity, and pour point. Also provided are compositions containing the compounds and methods of making both the compounds and compositions thereof.