Described herein are methods of stabilizing the beta hydrogen of glycerol based esters by the insertion of alkoxy groups to significantly improve the thermal, oxidative, and hydrolytic stability of the ester and allow for controlling the molar density of esters bonds in the lubricants to maximize hydrolytic stability while maintaining biodegradability and further improving performance properties.

Provided is a mixed powder for powder metallurgy that contains a readily available compound as a lubricant, does not need to contain a stain-causing metal soap, has excellent ejection properties and compressibility, and can exhibit excellent fluidity without deteriorating the ejection properties or the compressibility even in the case of further containing carbon black. The mixed powder for powder metallurgy comprising an (a) iron-based powder and a (b) lubricant, wherein the (b) lubricant is an ester of disaccharide and fatty acid represented by R—COOH, and the R is an alkyl group having 11 or more carbon atoms or an alkenyl group having 11 or more carbon atoms.

Provided is a mixed powder for powder metallurgy that contains a readily available compound as a lubricant, does not need to contain a stain-causing metal soap, has excellent ejection properties and compressibility, and can exhibit excellent fluidity without deteriorating the ejection properties or the compressibility even in the case of further containing carbon black. The mixed powder for powder metallurgy comprising an (a) iron-based powder and a (b) lubricant, wherein the (b) lubricant is an ester of disaccharide and fatty acid represented by R—COOH, and the R is an alkyl group having 11 or more carbon atoms or an alkenyl group having 11 or more carbon atoms.

Described herein are methods of stabilizing the beta hydrogen of glycerol based esters by the insertion of alkoxy groups to significantly improve the thermal, oxidative, and hydrolytic stability of the ester and allow for controlling the molar density of esters bonds in the lubricants to maximize hydrolytic stability while maintaining biodegradability and further improving performance properties.

An aspect of the present invention relates to a lubricant composition containing at least: (A) 50 to 80 mass % of silicone oil represented by formula (1) below, and having a mass-average molecular weight of 900 to 4000, a ratio (C/Si ratio) of carbon to silicon of 3.03 or higher in the structure, and a viscosity index (VI) of 300 or higher; (B) 10 to 49 mass % of hydrocarbon-based lubricant; and (C) 1 to 10 mass % of antioxidant.

One aspect of the present invention is a refrigerating machine oil containing: a base oil containing an ester of an alcohol and a fatty acid; a compound represented by the following formula (1): ##STR00001##
wherein R.sup.1 and R.sup.2 each independently represent a monovalent hydrocarbon group, R.sup.3 represents a divalent hydrocarbon group, and R.sup.4 represents hydrogen atom or a monovalent hydrocarbon group, and the refrigerating machine oil having a kinematic viscosity at 40° C. of 10 mm.sup.2/s or less.

An aspect of the present invention relates to a lubricant composition containing at least: (A) 50 to 80 mass % of silicone oil represented by formula (1) below, and having a mass-average molecular weight of 900 to 4000, a ratio (C/Si ratio) of carbon to silicon of 3.03 or higher in the structure, and a viscosity index (VI) of 300 or higher; (B) 10 to 49 mass % of hydrocarbon-based lubricant; and (C) 1 to 10 mass % of antioxidant.

Described herein are methods of stabilizing the beta hydrogen of glycerol based esters by the insertion of alkoxy groups to significantly improve the thermal, oxidative, and hydrolytic stability of the ester and allow for controlling the molar density of esters bonds in the lubricants to maximize hydrolytic stability while maintaining biodegradability and further improving performance properties.

One aspect of the present invention is a refrigerating machine oil containing: a base oil containing an ester of an alcohol and a fatty acid; a compound represented by the following formula (1):

##STR00001##

wherein R.sup.1 and R.sup.2 each independently represent a monovalent hydrocarbon group, R.sup.3 represents a divalent hydrocarbon group, and R.sup.4 represents hydrogen atom or a monovalent hydrocarbon group, and the refrigerating machine oil having a kinematic viscosity at 40 C. of 10 mm.sup.2/s or less.

Lubricant composition formulations comprising at least one biodegradable plastic, such as polyhydroxyalkanoate and/or polybutylene succinate, and at least one lubricant, such as a vegetable oil.