The invention relates to aqueous composition comprising water-soluble glycerin-based polyalkylene glycols as synthetic base oils as well as the use of the composition and the glycerin-based polyalkylene glycols as or in metalworking fluids, wherein the glycerin was consecutively alkoxylated in the following order: first with propylene oxide, followed by ethylene oxide and finally with propylene oxide.

The invention relates to aqueous composition comprising water-soluble glycerin-based polyalkylene glycols as synthetic base oils as well as the use of the composition and the glycerin-based polyalkylene glycols as or in metalworking fluids, wherein the glycerin was consecutively alkoxylated in the following order: first with propylene oxide, followed by ethylene oxide and finally with propylene oxide.

A composition comprising water, a glycol, and a polyalkylene glycol which has a biodegradability of at least 60% as determined using OECD 301F wherein the composition has a kinematic viscosity of at least 25 mm.sup.2/sec at 40° C. is useful as a rheology modifier, particularly in subsea applications. In some instances, the composition comprises 10 to 65 weight % water, 20 to 60 weight % of a glycol selected from ethylene glycol, diethylene glycol, triethylene glycol and tetra ethylene glycol, 10 to 40 weight % of a polyalkylene glycol, and 0 to 10% of additives based on total weight of the composition wherein the polyalkylene glycol has a—molecular weight of no more than 4000 g/mol and is characterized in that it is an oxyethylene/oxypropylene block copolymer having a weight percent of oxyethylene of at least 20% based on total weight of the copolymer.

A composition comprising water, a glycol, and a polyalkylene glycol which has a biodegradability of at least 60% as determined using OECD 301F wherein the composition has a kinematic viscosity of at least 25 mm.sup.2/sec at 40° C. is useful as a rheology modifier, particularly in subsea applications. In some instances, the composition comprises 10 to 65 weight % water, 20 to 60 weight % of a glycol selected from ethylene glycol, diethylene glycol, triethylene glycol and tetra ethylene glycol, 10 to 40 weight % of a polyalkylene glycol, and 0 to 10% of additives based on total weight of the composition wherein the polyalkylene glycol has a—molecular weight of no more than 4000 g/mol and is characterized in that it is an oxyethylene/oxypropylene block copolymer having a weight percent of oxyethylene of at least 20% based on total weight of the copolymer.

A lubricating oil composition may be suitable for a refrigerator and have excellent thermal stability when used with a refrigerant using difluoromethane (R32), trifluoroiodomethane (CF.sub.3I), and at least one selected from saturated fluorinated hydrocarbon compounds (HFC) other than difluoromethane (R32). Such compositions may include: a base oil (A) with at least one selected from a polyoxyalkylene glycol, a polyvinyl ether, a copolymer of a poly(oxy)alkylene glycol or a monoether thereof and a polyvinyl ether, and a polyol ester; and an aliphatic epoxy compound (B), wherein the content of the aliphatic epoxy compound (B) is more than 2.0% by mass based on the total amount of the lubricating oil composition.

A lubricating oil composition may be suitable for a refrigerator and have excellent thermal stability when used with a refrigerant using difluoromethane (R32), trifluoroiodomethane (CF.sub.3I), and at least one selected from saturated fluorinated hydrocarbon compounds (HFC) other than difluoromethane (R32). Such compositions may include: a base oil (A) with at least one selected from a polyoxyalkylene glycol, a polyvinyl ether, a copolymer of a poly(oxy)alkylene glycol or a monoether thereof and a polyvinyl ether, and a polyol ester; and an aliphatic epoxy compound (B), wherein the content of the aliphatic epoxy compound (B) is more than 2.0% by mass based on the total amount of the lubricating oil composition.

Disclosed is a lubricant composition including: at least one base oil; at least one polyalkylene glycol with at least 50% by weight of butylene oxide units and having a kinematic viscosity, measured at 100° C. according to standard ASTM D445 (2015), which is greater than or equal to 50 mm2/s, a kinematic viscosity, measured at 40° C. according to standard ASTM D445 (2015), which is greater than or equal to 1000 mm2/s and a Viscosity Index, measured according to standard ASTM D2270 (2012), which is greater than or equal to 180. Also disclosed is the use of such a composition for transmission or gear lubrication.

Disclosed is a lubricant composition including: at least one base oil; at least one polyalkylene glycol with at least 50% by weight of butylene oxide units and having a kinematic viscosity, measured at 100° C. according to standard ASTM D445 (2015), which is greater than or equal to 50 mm2/s, a kinematic viscosity, measured at 40° C. according to standard ASTM D445 (2015), which is greater than or equal to 1000 mm2/s and a Viscosity Index, measured according to standard ASTM D2270 (2012), which is greater than or equal to 180. Also disclosed is the use of such a composition for transmission or gear lubrication.

A refrigerator oil composition with a base oil (A), and a first phosphorus compound (B). The first phosphorus compound (B) is a first phosphite ester (B1) represented by formula (1) and a second phosphite ester (B2) represented by formula (2):

(R.sup.11—O—).sub.n—PO—R.sup.12).sub.3-n   (1)

##STR00001##

A method of producing a refrigerator oil composition by mixing a base oil (A) with a first phosphorus compound (B). A refrigerator mixture composition includes the refrigerator oil composition and a refrigerant.

A refrigerator oil composition with a base oil (A), and a first phosphorus compound (B). The first phosphorus compound (B) is a first phosphite ester (B1) represented by formula (1) and a second phosphite ester (B2) represented by formula (2):

(R.sup.11—O—).sub.n—PO—R.sup.12).sub.3-n   (1)

##STR00001##

A method of producing a refrigerator oil composition by mixing a base oil (A) with a first phosphorus compound (B). A refrigerator mixture composition includes the refrigerator oil composition and a refrigerant.