This invention relates to polymer-based partially-open, hollow reservoirs in the nano-size to micro-size range that encapsulate an additive, which can be released from the reservoirs using specific event stimuli such as reduction-oxidation and voltage change, or at will, using the same stimuli. This invention also relates to method preparing such reservoirs, and for releasing the additive. This invention further relates to matrix that comprises such reservoirs and the method of preparing such matrix. This invention also relates to applications, for example in corrosion inhibition, lubrication, and adhesion, that benefit from using such a controlled release of an additive.

A super-lubricity water lubricating additive, a super-lubricity water lubricant, a preparation method and application, wherein the additive is of a hollow spherical shell structure which includes at least one layer of spherical shell; the spherical shell sequentially includes a first polydopamine layer, a nanoparticle layer, a second polydopamine layer and an oxidized graphene layer from inside to outside, or a first polydopamine layer, a nanoparticle layer, a second polydopamine layer, a graphene layer and a third polydopamine layer from inside to outside; and nanoparticles of the nanoparticle layer are nano diamond, nano molybdenum disulfide or nano tungsten disulfide. The additive is prepared into a uniform aqueous solution to obtain the super-lubricity water lubricant. The additive can be easily adsorbed on a dual surface, and the nanoparticles released in a friction process cooperate with spherical oxidized graphene or graphene to form rolling friction so as to reduce frictional abrasion.

A multi-grade lubricating oil including a (meth)acrylate polymer with at least two distinct molecular weight arms and a blend of heavier and lighter base oils with increased amounts of the heavier base oil to achieve SAE grade performance. The compositions herein achieve SAE certifications as lower CCS viscosities at target kinematic viscosities for multi-grade oils.

A super-lubricity water lubricating additive, a super-lubricity water lubricant, a preparation method and application, wherein the additive is of a hollow spherical shell structure which includes at least one layer of spherical shell; the spherical shell sequentially includes a first polydopamine layer, a nanoparticle layer, a second polydopamine layer and an oxidized graphene layer from inside to outside, or a first polydopamine layer, a nanoparticle layer, a second polydopamine layer, a graphene layer and a third polydopamine layer from inside to outside; and nanoparticles of the nanoparticle layer are nano diamond, nano molybdenum disulfide or nano tungsten disulfide. The additive is prepared into a uniform aqueous solution to obtain the super-lubricity water lubricant. The additive can be easily adsorbed on a dual surface, and the nanoparticles released in a friction process cooperate with spherical oxidized graphene or graphene to form rolling friction so as to reduce frictional abrasion.

A lubricating composition comprises an oil-soluble poly(2-oxazoline) additive having the repeat unit:

—N(COR.sup.1)CH.sub.2CH.sub.2— where the number of repeat units (n) is an integer between 4 and 1000; where the polymer carries an inorganic or organic nucleophilic polymerization terminating group t, and a linear, branched or cyclic hydrocarbyl polymerization initiator group (i); and where R.sup.1 comprises a single or a mixture of linear branched or cyclic hydrocarbyl groups having 1-100 carbon atoms, some or all having 12-100 carbon atoms, or of at least one macro-monomeric hydrocarbyl group with more than 50 carbon atoms provided that when the polymer is a homopolymer and R.sup.1 lacks any hetero atoms; (A) i has a molecular weight of less than 250 g/mol, and R.sup.1 has an average number of carbon atoms of 12 to 50; or (B) n is greater than 15.

The polymer may provide the composition, in the form of a lubricant, with friction modifier, and with low impact on lubricant viscosity.

The polymer may be a homopolymer, a block copolymer or a star polymer.

A lubricating oil composition comprising at least 50 percent by mass, based on the mass of the composition of an oil of lubricating viscosity and 0.01 to 25 percent by mass, based on the mass of the composition of a polymer comprising units (a) and one or both units (b) and (c):
—N(COR.sup.1)(CH.sub.2).sub.x—  (a)
—NH(CH.sub.2).sub.y—  (b)
—N(CH.sub.2CH.sub.2-k(CH.sub.3).sub.kCOOR.sup.2)(CH.sub.2).sub.z   (c) where the total number (n) of units (a), (b) and (c) is an integer between 4 and 500; wherein x, y and z are independently 2 or 3; wherein k is zero or 1. The polymer shows good solubility in the lubricating oil and provides friction modification. A method of synthesising a polymer is also disclosed.

Provided is a lubricating composition for inhibiting plugging including a base oil and any one selected from a fatty acid and an emulsifier, with the lubricating composition forming a single phase even when a carboxylic acid-based monomer is introduced with respect to the base oil. The lubricating composition suppresses plugging occurring in a process of preparing a copolymer derived from the carboxylic acid-based monomer. In addition, also provided is a method of inhibiting plugging using the lubricating composition for inhibiting plugging.

A lubricating oil composition for an internal combustion engine has a HTHS viscosity at 150° C. of 2.55-2.84 mPa.Math.s and includes: (A) a lubricating base oil including (a) mineral base oil(s) and/or (a) synthetic base oil(s), and having a kinematic viscosity at 100° C. of 3.8-4.6 mm.sup.2/s; (B) 1000-2000 mass ppm, in terms of metal content, of a metallic detergent including (a) metal salicylate detergent(s), and delivering ≥10 mmol/kg of total salicylate soap base per kilogram of the composition; (C) 1.0 to 4.0 mass % of a comb-shaped poly(meth)acrylate having a Mw of 350,000-1,000,000 and a PDI of ≤4.0; and (D) 100-1000 mass ppm, in terms of nitrogen, of a succinimide dispersant including (i) (a) non-modified succinimide dispersant(s) and/or (ii) (a) boric acid-modified succinimide dispersant(s), wherein the (i) and the (ii), in total, deliver ≥70 mass % of total nitrogen content of the component (D).

A metalworking fluid includes a pH buffer system having one or more organic acids and one or more organic amines. The organic acids, which include aromatic carboxylic acids and C.sub.10 or higher aliphatic carboxylic acids, may replace boric acid, such that boric acid may be excluded from the metalworking fluid. The organic acids may include at least one of phthalic acid, isophthalic acid, and terephthalic acid. The one or more organic amines include aliphatic and aromatic amines having an amine value of at least 50 mg KOH/g. A method of using the metalworking fluid includes shaping a metal by contacting the metal surface with a tool while cooling and lubricating at least one of the metal surface or tool with the metalworking fluid.

A product resulting from the reaction of at least: an alkali or alkaline earth metal hydroxybenzoate compound, optionally substituted by a hydrocarbyl group and optionally overbased, a boron compound, an amine component selected from a di-fatty-alkyl(ene) polyalkylamine composition including one or more polyalkylamines of formulae (I) or (II). A lubricant composition including this product. Use of this product as a lubricant for two-stroke marine engines and four-stroke marine engines, more preferably two-stroke marine engines.