Disclosed is a lubricating oil composition capable of having a good balance of electrical insulation, seizure resistance and wear resistance. In particular, the lubricating oil composition comprises: (A) a lubricant base oil; (B) an alkaline earth metal detergent; (C) a triazole-based compound represented by the following general formula (1) or (2): ##STR00001##
wherein R.sup.1-R.sup.6 are as defined herein; (D) at least one sulfur-containing compound selected from the group consisting of a sulfur-containing heterocyclic ether compound and a sulfide compound; and (E) an ashless dispersant.

Lubricant compositions comprising a base oil, one or more antioxidants selected from a group consisting of N-α-naphthyl-N-phenylamine antioxidants and diphenylamine antioxidants; and a sulfur-containing additive comprising up to seven carbon atoms exhibit outstanding oxidative stability and non-corrosion properties. The N-α-naphthyl-N-phenylamine antioxidants plus diphenylamine antioxidants in total may be present from about 0.2 wt % to about 0.8 wt %, based on the total weight of the lubricant composition. The sulfur provided by the sulfur-containing additive may be present from about 50 ppm to about 1000 ppm by weight, based on the total weight of the lubricant composition.

With the present invention, sustainable systems for corrosion, inhibition in the processing of metals (in particular iron, aluminum and magnesium) are made available. These systems being in full accordance with the principles of green chemistry comprise an amino acid as neutralizing component for an acidic corrosion inhibitor, whereby the amino acid is used in deprotonated form. The resulting metalworking fluids may be water- or oil-based or semi synthetic formulations. The neutralization of acidic corrosion inhibitors with the claimed system comprising an amino acid consistently achieves convincing results and, together with acidic corrosion inhibitors from corresponding sources, completely renewable systems for corrosion inhibition are provided.

Lubricating compositions comprising a thiol-carboxylic adduct that is the reaction product of a thiol and carboxylic acid and/or a carboxylic acid derivative. The lubricating composition also comprises an antiwear agent. Methods of lubricating an internal combustion engine comprise contacting the internal combustion engine with a lubricating composition comprising a thiol-carboxylic adduct that is the reaction product of a thiol and carboxylic acid and/or a carboxylic acid derivative. Methods of reducing lubricant oxidation and/or corrosion in an internal combustion engine with a lubricating composition comprising a thiol-carboxylic adduct that is the reaction product of a thiol and carboxylic acid and/or a carboxylic acid derivative. The use of a comprising a thiol-carboxylic adduct that is the reaction product of a thiol and carboxylic acid and/or a carboxylic acid derivative to reduce lubricant oxidation and/or corrosion in an internal combustion engine.

A lubricating oil composition comprising at least 50 percent by mass, based on the mass of the composition of an oil of lubricating viscosity and 0.01 to 25 percent by mass, based on the mass of the composition of a polymer comprising units (a) and one or both units (b) and (c):
—N(COR.sup.1)(CH.sub.2).sub.x—  (a)
—NH(CH.sub.2).sub.y—  (b)
—N(CH.sub.2CH.sub.2-k(CH.sub.3).sub.kCOOR.sup.2)(CH.sub.2).sub.z   (c) where the total number (n) of units (a), (b) and (c) is an integer between 4 and 500; wherein x, y and z are independently 2 or 3; wherein k is zero or 1. The polymer shows good solubility in the lubricating oil and provides friction modification. A method of synthesising a polymer is also disclosed.

Lubricant compositions comprising a base oil, one or more antioxidants selected from a group consisting of N-α-naphthyl-N-phenylamine antioxidants and diphenylamine antioxidants; and a sulfur-containing additive comprising up to seven carbon atoms exhibit outstanding oxidative stability and non-corrosion properties. The N-α-naphthyl-N-phenylamine antioxidants plus diphenylamine antioxidants in total may be present from about 0.2 wt % to about 0.8 wt %, based on the total weight of the lubricant composition. The sulfur provided by the sulfur-containing additive may be present from about 50 ppm to about 1000 ppm by weight, based on the total weight of the lubricant composition.

Disclosed is a lubricating oil composition capable of having a good balance of electrical insulation, seizure resistance and wear resistance. In particular, the lubricating oil composition comprises: (A) a lubricant base oil; (B) an alkaline earth metal detergent; (C) a triazole-based compound represented by the following general formula (1) or (2):

##STR00001##

wherein R.sup.1-R.sup.6 are as defined herein; (D) at least one sulfur-containing compound selected from the group consisting of a sulfur-containing heterocyclic ether compound and a sulfide compound; and (E) an ashless dispersant.

The present invention relates to a sulphur-containing polyester capable of being obtained by a process comprising esterification reactions between a polyol and a carboxylic acid and a thiolactic acid, or by a process comprising an esterification reaction between a partially esterified polyol and a thiolactic acid. It also concerns its use as a multiproperty additive, and compositions comprising it.

The present invention provides a lubricating oil additive, including: a molybdenum compound (A) represented by the following general formula (1); and a sulfur-based composition (B) containing a sulfur-based compound (b-1) represented by the following general formula (2) and at least one kind of sulfur-based compound (b-2) represented by the following general formula (3) or (4), and a lubricating oil composition containing the additive. In the formula (1), R.sup.1 to R.sup.4 each represent alkyl groups having 6 to 18 carbon atoms, the groups being identical to or different from each other, and X.sup.1 to X.sup.4 each independently represent an oxygen atom or a sulfur atom. In the formula (2), R.sup.5 represents an alkyl group having 1 to 22 carbon atoms, R.sup.6 represents a hydrogen atom or an alkyl group having 1 to 20 carbon atoms, R.sup.7 represents a hydrogen atom or an alkyl group having 1 to 20 carbon atoms, and “a” represents a number from 1 to 10. In the formulae (3) and (4), R.sup.8 to R.sup.11 each represent alkylene groups having 1 to 28 carbon atoms, the groups being identical to or different from each other, R.sup.12 and R.sup.13 each independently represent a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, and “b” and “c” each independently represent a number from 1 to 8, provided that at least one of R.sup.12 or R.sup.13 represents an alkyl group having 1 to 3 carbon atoms. ##STR00001##

The present invention provides a lubricating oil additive, including: a molybdenum compound (A) represented by the following general formula (1); and a sulfur-based composition (B) containing a sulfur-based compound (b-1) represented by the following general formula (2) and at least one kind of sulfur-based compound (b-2) represented by the following general formula (3) or (4), and a lubricating oil composition containing the additive. In the formula (1), R.sup.1 to R.sup.4 each represent alkyl groups having 6 to 18 carbon atoms, the groups being identical to or different from each other, and X.sup.1 to X.sup.4 each independently represent an oxygen atom or a sulfur atom. In the formula (2), R.sup.5 and R.sup.6 each represent alkyl groups having 3 to 24 carbon atoms, the groups being identical to or different from each other, and “a” and “b” each represent a number from 1 to 5. In the formulae (3) and (4), R.sup.7 to R.sup.10 each represent alkylene groups having 1 to 28 carbon atoms, the groups being identical to or different from each other, R.sup.11 and R.sup.12 each independently represent a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, and “c” and “d” each independently represent a number from 1 to 8, provided that at least one of R.sup.11 or R.sup.12 represents an alkyl group having 1 to 3 carbon atoms.

##STR00001##