The present invention provides a class of halogen-containing synthetic base oils, and preparation method and use thereof. The synthetic base oils have introduced with halogen, especially fluorine, wherein the dipole motion of the halogen groups results in dipole interaction between the dipoles of other components and the base oil molecules of dipole-dipole and dipole-induced halogen (especially fluorine), and the interaction force is stronger and more localized than the dispersion force between the molecules of pure hydrocarbon synthetic oils, and thus the performance of the base oils is directly affected. It solved the problem of oil solubility of pure hydrocarbon synthetic oils, and also improved the properties of oxidation resistance and thermal stability.

The present invention provides a class of halogen-containing synthetic base oils, and preparation method and use thereof. The synthetic base oils have introduced with halogen, especially fluorine, wherein the dipole motion of the halogen groups results in dipole interaction between the dipoles of other components and the base oil molecules of dipole-dipole and dipole-induced halogen (especially fluorine), and the interaction force is stronger and more localized than the dispersion force between the molecules of pure hydrocarbon synthetic oils, and thus the performance of the base oils is directly affected. It solved the problem of oil solubility of pure hydrocarbon synthetic oils, and also improved the properties of oxidation resistance and thermal stability.

The present disclosure provides compounds of formula (I), and preparation method thereof, ##STR00001## wherein W is independently selected from the group consisting of H, F, Cl, Br and I; X is independently selected from the group consisting of H, F, Cl, Br, I, CW.sub.3 and OR on the basis that at least one X is OR; R is independently selected from the group consisting of C(O)CH.sub.2).sub.m(CF.sub.2).sub.nY and CW.sub.2C(CW.sub.2OC(O)(CH.sub.2).sub.m(CF.sub.2).sub.nY).sub.3; m is an integer from 0 to 2;15 n is an integer from 2 to 8; Y is C(Z).sub.3; and Z is independently selected from the group consisting of H, F, Cl, Br and I. Such compounds may be utilised as lubricants, for example in heat transfer compositions.

The present disclosure provides compounds of formula (I), and preparation method thereof, ##STR00001## wherein W is independently selected from the group consisting of H, F, Cl, Br and I; X is independently selected from the group consisting of H, F, Cl, Br, I, CW.sub.3 and OR on the basis that at least one X is OR; R is independently selected from the group consisting of C(O)CH.sub.2).sub.m(CF.sub.2).sub.nY and CW.sub.2C(CW.sub.2OC(O)(CH.sub.2).sub.m(CF.sub.2).sub.nY).sub.3; m is an integer from 0 to 2;15 n is an integer from 2 to 8; Y is C(Z).sub.3; and Z is independently selected from the group consisting of H, F, Cl, Br and I. Such compounds may be utilised as lubricants, for example in heat transfer compositions.

A lithium-based grease and the preparation method thereof are provided. The raw materials for preparing the lithium-based grease include in parts by weight: 75-88 parts of base oil, 0.5-2.5 parts of antiwear agent, 0.1-1.5 parts of antirust agent, 0.1-1.5 parts of antioxidant, 5-25 parts of lubricant, 5-15 parts of thickening agent, and 0.6-2.0 parts of saponifying agent. The raw materials also include hydroxyl compound-containing modified graphene containing quaternary ammonium salt or aromatic ring. The grease has good colloid stability and mechanical stability, can greatly improve the antiwear property. More than that, the grease has excellent oxidation resistance, and can significantly shorten the reaction time of the saponification, reduce the reaction temperature of the saponification.

A lithium-based grease and the preparation method thereof are provided. The raw materials for preparing the lithium-based grease include in parts by weight: 75-88 parts of base oil, 0.5-2.5 parts of antiwear agent, 0.1-1.5 parts of antirust agent, 0.1-1.5 parts of antioxidant, 5-25 parts of lubricant, 5-15 parts of thickening agent, and 0.6-2.0 parts of saponifying agent. The raw materials also include hydroxyl compound-containing modified graphene containing quaternary ammonium salt or aromatic ring. The grease has good colloid stability and mechanical stability, can greatly improve the antiwear property. More than that, the grease has excellent oxidation resistance, and can significantly shorten the reaction time of the saponification, reduce the reaction temperature of the saponification.

A lithium-based grease and the preparation method thereof are provided. The raw materials for preparing the lithium-based grease include in parts by weight: 75-88 parts of base oil, 0.5-2.5 parts of antiwear agent, 0.1-1.5 parts of antirust agent, 0.1-1.5 parts of antioxidant, 5-25 parts of lubricant, 5-15 parts of thickening agent, and 0.6-2.0 parts of saponifying agent. The raw materials also include hydroxyl compound-containing modified graphene containing quaternary ammonium salt or aromatic ring. The grease has good colloid stability and mechanical stability, can greatly improve the antiwear property. More than that, the grease has excellent oxidation resistance, and can significantly shorten the reaction time of the saponification, reduce the reaction temperature of the saponification.

A lithium-based grease and the preparation method thereof are provided. The raw materials for preparing the lithium-based grease include in parts by weight: 75-88 parts of base oil, 0.5-2.5 parts of antiwear agent, 0.1-1.5 parts of antirust agent, 0.1-1.5 parts of antioxidant, 5-25 parts of lubricant, 5-15 parts of thickening agent, and 0.6-2.0 parts of saponifying agent. The raw materials also include hydroxyl compound-containing modified graphene containing quaternary ammonium salt or aromatic ring. The grease has good colloid stability and mechanical stability, can greatly improve the antiwear property. More than that, the grease has excellent oxidation resistance, and can significantly shorten the reaction time of the saponification, reduce the reaction temperature of the saponification.

The present disclosure provides compounds of formula (I), and preparation method thereof,

##STR00001## wherein W is independently selected from the group consisting of H, F, Cl, Br and I; X is independently selected from the group consisting of H, F, Cl, Br, I, CW.sub.3 and OR on the basis that at least one X is OR; R is independently selected from the group consisting of C(O)CH.sub.2).sub.m(CF.sub.2).sub.nY and CW.sub.2C(CW.sub.2OC(O)(CH.sub.2).sub.m(CF.sub.2).sub.nY).sub.3; m is an integer from 0 to 2; 15 n is an integer from 2 to 8; Y is C(Z).sub.3; and Z is independently selected from the group consisting of H, F, Cl, Br and I. Such compounds may be utilised as lubricants, for example in heat transfer compositions.

The present disclosure provides compounds of formula (I), and preparation method thereof,

##STR00001## wherein W is independently selected from the group consisting of H, F, Cl, Br and I; X is independently selected from the group consisting of H, F, Cl, Br, I, CW.sub.3 and OR on the basis that at least one X is OR; R is independently selected from the group consisting of C(O)CH.sub.2).sub.m(CF.sub.2).sub.nY and CW.sub.2C(CW.sub.2OC(O)(CH.sub.2).sub.m(CF.sub.2).sub.nY).sub.3; m is an integer from 0 to 2; 15 n is an integer from 2 to 8; Y is C(Z).sub.3; and Z is independently selected from the group consisting of H, F, Cl, Br and I. Such compounds may be utilised as lubricants, for example in heat transfer compositions.