A process for producing direct reduced iron with a hydrogen rich gas, utilizing a non-fired reducing gas heater such as an electric heater to heat the reducing gas to the temperatures sufficient for iron reduction, includes: providing a shaft furnace to reduce iron oxide with the hydrogen rich reducing gas; removing steam and particulates from the shaft furnace top gas with a scrubber; processing all or a portion of the scrubbed top gas in a gas separation unit such as a membrane and a PSA gas separation unit to create a hydrogen rich stream to be recycled back to the shaft furnace as the reducing agent, so that the hydrogen consumption can be reduced when non-fired reducing gas heater is applied.

The present disclosure provides a facility to produce direct reduced iron, which makes it possible to perform reforming and reduction and adjust the carbon amount in a product within a wide range without requiring an externally heating reformer and without causing the metal dusting problem in a circulating gas preheater and the problem of sintering each other or fusion between reduced iron, in a furnace. The facility to produce the direct reduced iron according to the present invention is equipped with a water content control device for controlling the water content in a gas discharged from a shaft-type reduction furnace, a first gas mixing device for mixing the gas from which a portion of water has been removed with an oxygen-containing gas and a hydrocarbon-containing gas to produce a mixed gas, and an auto-thermal reformer for reforming the mixed gas with its energy. The facility is also equipped with a cooling gas loop for circulating a cooling gas, wherein the cooling gas has a hydrocarbon concentration of 50% or more, and the cooling gas loop is equipped with a cooling gas after-cooler having a flow rate control function and capable of controlling the temperature of the cooling gas.

A method for operating a metallurgical furnace and a simplified way of providing synthesis gas for a metallurgical furnace, includes the following steps performing a combustion process outside the metallurgical furnace by combusting a carbon-containing material with an oxygen-rich gas to produce an offgas, which offgas is a CO.sub.2 containing gas; and combining the offgas, while having an elevated combustion-induced temperature due to the combustion process, with a hydrocarbon-containing fuel gas to obtain a first gas mixture having a temperature above a reforming temperature necessary for a reforming process, preferably a dry reforming process; the first gas mixture undergoing the reforming process, thereby producing a synthesis gas containing CO and H.sub.2, the reforming process being performed non-catalytically; and feeding the synthesis gas into the metallurgical furnace.

Method and system for producing direct reduced metal material, comprising the steps: a) charging metal material to be reduced into a furnace space (120); b) evacuating an existing atmosphere from the furnace space to achieve a gas pressure of less than 1 bar therein, c) providing heat and hydrogen gas into the furnace space, so that heated hydrogen gas heats the charged metal material to a temperature high enough so that metal oxides present in the metal material are reduced, in turn causing water vapour to be formed, which hydrogen gas provision is performed so that a pressure of more than 1 bar builds up inside the furnace space; and d) before evacuating the built up overpressure, condensing and collecting the water vapour formed in step c in a condenser (160) below the charged metal material. The invention is characterised in that it further comprises the step e) before evacuating the build up overpressure, providing a carbon-containing gas to the furnace space, so that the heated and reduced metal material is carburized by said carbon-containing gas.

A method of recovering enriched iron fines from bauxite waste includes calcining particles of bauxite waste to form oxygen carrier particles, subjecting the oxygen carrier particles to chemical looping combustion at a temperature of about 950° C.-1,050° C. for energy production and to produce the enriched iron fines as a by-product from the oxygen carrier particles via natural attrition and collecting the enriched iron fines.

A method for direct reduction of metal oxide-containing starting materials to produce metallized material by contact with hot reduction gas in a reduction unit (1), wherein the product of the direct reduction is discharged from the reduction unit (1) by means of a product discharge device (3) which is flushed with seal gas and from which vent gas is drawn and subsequently de-dusted. The vent gas is de-dusted dry and the content of at least one gaseous constituent is reduced by catalytic conversion or combustion. Also, a device for carrying out the method is disclosed.

A method for producing a homogenous molten composition and a fluid product is disclosed. For example, the method includes producing a first molten metal composition in an enclosed volume, contacting a hydrocarbon reactant with the first molten metal composition, decomposing the hydrocarbon reactant into at least one fluid product and carbon, forming a metal alloy from a mixture of the carbon and the first molten metal composition, and separating a homogenous second molten composition from the metal alloy.

A method for producing direct reduced iron is provided. The method includes circulating a first stream of spent reducing gas exiting a reactor in a reducing gas circuit through at least one carbon dioxide removal unit and a reducing gas heater and the reactor. The method also includes mixing the first stream with reducing gas containing heavier hydrocarbons than methane.

The invention relates to a process for direct reduction of iron ore to afford direct reduced iron, wherein the iron ore sequentially passes through a reduction zone for reducing the iron ore to direct reduced iron and a cooling zone for cooling the direct reduced iron, wherein in the reduction zone the iron ore is subjected to a flow of a reduction gas and wherein in the cooling zone the direct reduced iron is subjected to a flow of a cooling gas. The cooling gas in the cooling zone comprises H2 and CO2, wherein the ratio of the mole fractions of H2 to CO2 is greater than 1.8 and the mole fraction of CO2 is greater than 20 mol %.

A system and method of direct reduction of iron (DRI) is disclosed, having a reduction unit configured to reduce iron oxides to metallic iron; a process gas heater coupled to the reduction unit, the process gas heater configured to supply the reduction unit directly with a source of heated reducing gas, where the process gas heater is further configured to receive a synthetic combustion air stream for heating the reducing gas, the synthetic combustion air stream comprising a source of oxygen with essentially no nitrogen. A method of carbon dioxide emission reduction from a direct reduction of iron (DRI) process is also disclosed.