A method for converting a blast furnace plant for synthesis gas utilization includes:

constructing a syngas stove, and constructing a syngas supply system for connecting the syngas stove to a blast furnace;

connecting a first syngas stove to the top-gas supply system, the cold-blast and hot-blast supply systems and operating the first syngas stove for hot blast generation;

disconnecting a first original stove from the top-gas supply system, the cold-blast and hot-blast supply systems; and

converting the first original stove to adapt it for producing syngas. The method includes

connecting the first original stove to the top-gas supply system;

disconnecting the first syngas stove from the cold-blast and hot-blast supply systems, connecting the first original stove and first syngas stove to a gas-combination supply system; and

operating the first original stove and first syngas stove to produce and then supply syngas to the blast furnace via the syngas supply system.

Blast furnace plant (1) and shutdown process for such a blast furnace plant (1). The blast furnace plant comprises a blast furnace (2) and a gas cleaning section (6) for cleaning gas from the blast furnace. Clean gas is released via a clean gas vent line (11) downstream of the gas cleaning section.

A plant complex may include a unit that produces CO.sub.2-containing gases, a gas conducting system for CO.sub.2-containing gases, a gas/liquid separation system, a reformer that is connected to the gas conducting system and where the CO.sub.2-containing gas reacts with H.sub.2 and/or hydrocarbons to give a CO— and H.sub.2-containing synthesis gas mixture. The reformer is connected to a reactor for producing higher alcohols in which the synthesis gas mixture reacts with H.sub.2 to give a gas/liquid mixture containing higher alcohols. For separating off the alcohols of the gas/liquid mixture, the gas/liquid separation system is connected to the reactor for producing higher alcohols.

A charging system for a shaft smelt reduction furnace includes a frame structure for mounting on a top charge opening of a shaft smelt reduction vessel; a center shaft arrangement supported by the frame structure and for removing off-gas gases from the furnace and to introduce granular charge materials to form a stack of materials in the furnace. The center shaft arrangement includes a center hood for off-gas extraction; a pair of first and second feed channels for first and second materials. The center hood includes a pair of facing off-gas panels defining an off-gas channel. The partition walls include lower portions that extend towards each other below the center hood to define a center feed passage, whereby material descending through the first feed channels may accumulate on lower portions according to the angle of repose of the material, permitting self-adjustment of the first material stock-line in the shaft arrangement.

Provided is a method of operating a blast furnace, having generating a regenerative methane gas from a by-product gas discharged from the blast furnace, and blowing a blast gas and a reducing agent into the blast furnace from a tuyere of the blast furnace in which the blast gas is oxygen gas and the regenerative methane gas is used as at least part of the reducing agent.

Herein discussed is a method of producing hydrogen comprising introducing a metal smelter effluent gas or a basic oxygen furnace (BOF) effluent gas or a mixture thereof into an electrochemical (EC) reactor, wherein the EC reactor comprises a mixed-conducting membrane. In an embodiment, the method comprises introducing steam into the EC reactor on one side of the membrane, wherein the effluent gas is on the opposite side of the membrane, wherein the effluent gas and the steam are separated by the membrane and do not come in contact with each other.

Disclosed are an apparatus and a method for granulation of a blast furnace slag and recycling of waste heat. The apparatus comprises an aerosol granulation nozzle module, a flow guide, a cyclone separator and a waste heat recovery device; wherein the aerosol granulation nozzle module comprises a slag flow controller, a compressed air flow control valve, a water volume control valve and an aerosol spray gun; the flow guide is configured to fully mix the medium temperature gas and the high-temperature granular slag having a primarily solidified surface in the flow guide; and the cyclone separator is configured to separate the high-temperature granular slag and the medium-to-high-temperature gas. The present invention completes the granulation of blast furnace slag, and organically couples slag sensible heat recovery with sludge drying, thereby recovering the waste heat in the process of slag granulation and improving the efficiency of waste heat recovery and utilization.

Provided is a solid carbon production facility including: a separation facility configured to separate a carbon dioxide gas contained in a produced gas produced by a blast furnace; a reaction facility configured to heat a fuel gas whose main component is a methane gas by using a heating facility and decompose the methane gas into solid carbon and a hydrogen gas; and a production facility configured to cause the carbon dioxide gas separated by the separation facility and the hydrogen gas decomposed by the reaction facility to react with each other to produce solid carbon and water.

Embodiments relate to systems and methods for regenerating and recirculating a CO, H.sub.2 or combinations thereof utilized for metal oxide reduction in a reduction furnace. The reduction furnace receives the reducing agent, reduces the metal oxide, and generates an exhaust of the oxidized product. The oxidized product is transferred to a mixing vessel, where the oxidized product, a calcium oxide, and a vanadium oxide interact to regenerate the reducing agent from the oxidized product. The regenerated reducing agent is transferred back to the reduction furnace for continued metal oxide reductions.

Provided is a steelmaking line contributing to the realization of a method that achieves energy saving and CO.sub.2 emission reduction when producing reduced iron from iron oxide. The steelmaking line comprises: a blast furnace configured to reduce iron oxide; a reducing furnace configured to reduce iron oxide; a methane synthesizer configured to synthesize methane from blast furnace gas and/or furnace top gas, and hydrogen gas; a blower configured to blow the methane gas synthesized by the methane synthesizer into the blast furnace; a heat-reformer configured to heat or heat-reform the blast furnace gas and/or the furnace top gas, and the methane gas synthesized by the methane synthesizer, to generate reducing gas; a reducing gas blower configured to blow the reducing gas into the reducing furnace; and a supply path configured to supply the furnace top gas to the methane synthesizer and/or the heat-reformer.