When performing dephosphorization treatment of hot metal by adding a refining agent as a lime source and an oxygen source (dephosphorizing agent(s) and a gaseous oxygen source into the hot metal accommodated in a hot metal holding container, the refining agent used is a refining agent having an Ig-loss value of from 4.0% by mass to 35.0% by mass and including 60% by mass or more of quicklime.

Provided is steel for a wind power gear with improved purity and reliability. The chemical components thereof comprise, in percentages by mass: 0.15-0.19% of C, ≤0.4% of Si, 0.5-0.7% of Mn, ≤0.012% of P, ≤0.006% of S, 1.5-1.8% of Cr, 0.28-0.35% of Mo, 1.4-1.7% of Ni, and 0.02-0.04% of Al, with the balance being Fe and inevitable impurities. A smelting method therefor comprises adding raw materials to a converter for primary melting, transferring same to a refining furnace for refining, carrying out continuous casting after vacuum degassing, and transferring same to a gas protection furnace for electroslag remelting. According to the present invention, a pure electroslag master batch is obtained by continuous casting, and the purity of the material is further improved by means of an electroslag remelting procedure; and the prepared steel material is used in a wind power gear, such that the flaw detection pass rate is significantly increased, large-particle inclusions in the steel material are significantly reduced, and the inclusions are fine and dispersed.

A method of making steel by deeply dephosphorization in a hot metal tank and decarburization using semi-steel with nearly zero phosphorus load in a converter includes the following steps: putting an efficient dephosphorization agent into the hot metal tank in advance, and conducting dephosphorization during blast furnace tapping and transportation of blast furnace hot metal by the hot metal tank to obtain semi-steel with [P] less than 0.04 wt. % and [C] greater than or equal to 3.5 wt. %; and removing dephosphorization slag, and pouring the semi-steel into the converter for decarburization to obtain molten steel. The efficient dephosphorization agent includes iron oxide scale, lime, and composite calcium ferrite. According to the method, a phosphorus content of the blast furnace hot metal is reduced to be less than or equal to 0.04 wt. % through the efficient dephosphorization agent.

Proposed is a method for removing phosphorus from a phosphorus-containing substance which is applicable in an industrial scale so as to effectively reduce phosphorus contained in the phosphorus-containing substance. In this method, the phosphorus-containing substance used as a raw material for metal smelting or metal refining is reacted with a nitrogen-containing gas at a treatment temperature T (° C.) which is lower than a melting temperature (T.sub.m) of the substance, so that phosphorus is removed preferably in the form of phosphorus nitride (PN). In this regard, a nitrogen partial pressure and an oxygen partial pressure in the nitrogen-containing gas are preferably controlled, thereby reducing a load of dephosphorization process, for example.

Process for dephosphorization of molten metal during a refining process using a lime composition in the form of compacted particles having a Shatter Test Index of less than 20%, leading to a refined metal reduced in phosphorus components to the extent that the refined metal reduced in phosphorus is showing a phosphorus content lower than 0.02 w % based on the total weight of the refined metal reduced in phosphorus.

Process for dephosphorization of molten metal during a refining process using a lime composition in the form of compacted particles having a Shatter Test Index of less than 20%, leading to a refined metal reduced in phosphorus components to the extent that the refined metal reduced in phosphorus is showing a phosphorus content lower than 0.02 w % based on the total weight of the refined metal reduced in phosphorus.

A method of making steel by deeply dephosphorization in a hot metal tank and decarburization using semi-steel with nearly zero phosphorus load in a converter includes the following steps: putting an efficient dephosphorization agent into the hot metal tank in advance, and conducting dephosphorization during blast furnace tapping and transportation of blast furnace hot metal by the hot metal tank to obtain semi-steel with [P] less than 0.04 wt. % and [C] greater than or equal to 3.5 wt. %; and removing dephosphorization slag, and pouring the semi-steel into the converter for decarburization to obtain molten steel. The efficient dephosphorization agent includes iron oxide scale, lime, and composite calcium ferrite. According to the method, a phosphorus content of the blast furnace hot metal is reduced to be less than or equal to 0.04 wt. % through the efficient dephosphorization agent.

On molten iron having a P concentration of 2 to 4 mass % and having a Cr concentration of 0.3 to 1.2 mass %, a dechromization treatment is performed by adjusting a basicity (CaO mass %)/(SiO.sub.2 mass %) of slag to greater than 0.1 and 1 or less and supplying an oxygen source with a molten iron temperature falling within a range of 1250 to 1500° C. to manufacture molten iron having a P concentration of 1.9 to 3.8 mass % and having a Cr concentration of less than 0.2 mass %.

On molten iron having a P concentration of 2 to 4 mass % and having a Cr concentration of 0.3 to 1.2 mass %, a dechromization treatment is performed by adjusting a basicity (CaO mass %)/(SiO.sub.2 mass %) of slag to greater than 0.1 and 1 or less and supplying an oxygen source with a molten iron temperature falling within a range of 1250 to 1500° C. to manufacture molten iron having a P concentration of 1.9 to 3.8 mass % and having a Cr concentration of less than 0.2 mass %.

A method for desulfurizing molten steel comprising taking a sample out from molten steel after tapping from a converter or during secondary refining and analyzing the sample rapidly with high accuracy by a method comprising a high frequency induction heating step wherein the sample is combusted and oxidized under the high frequency induction heating in an oxygen atmosphere having an oxygen purity of 99.5 vol % or more to convert S in the sample into SO.sub.2 and an analyzing step wherein SO.sub.2-containing gas produced in the high frequency induction heating step is analyzed through an ultraviolet fluorescence method to quantify S concentration of the sample.