The present invention provides a die-cast product producing method and a spheroidizing agent of a spherical graphite cast iron with ultrafine spherical graphite by simple method and good reproducibility.

The present invention provides a sand mold producing method and a spheroidizing agent capable of producing an ultrafine spherical graphite cast iron with good reproducibility even in a sand mold thin walled spherical graphite cast iron, which has solidification cooling conditions equivalent to those of a metal mold.

The present invention provides a producing method of a die-cast product of a spherical graphite cast iron using a spheroidizing agent, in which a C amount is 0.5 mass % or more, a total nitrogen amount N is 150 ppm (by mass) or less, and a nitrogen amount generated during melting is 15 ppm (by mass) or less, in a producing method of a sand mold cast product of a thin walled spherical graphite cast iron having a melting process, a spheroidizing process, an inoculation process, and a casting process.

An inoculant for the manufacture of cast iron with lamellar, compacted or spheroidal graphite is disclosed. The inoculant has a particulate ferrosilicon alloy having about 40 to 80 wt % silicon, about 0.1 to 10 wt % calcium, 0 and 10% by weight of rare earths, for example cerium and/or lanthanum, and up to 5 wt % aluminium the balance being iron and incidental impurities in the ordinary amount, wherein the inoculant additionally has 0.1 to 10 wt %, based on the total weight of inoculant, antimony oxide where said antimony oxide is in particulate form and is mixed or blended with the ferrosilicon alloy particles, or is simultaneously added to cast iron together with the particulate ferrosilicon alloy particles.

An inoculant for manufacturing cast iron with lamellar, compacted or spheroidal graphite is disclosed. The inoculant has a particulate ferrosilicon alloy having 40 and 80% by weight of silicon, 0.5-5 wt % of calcium and/or strontium and/or barium, 0-10 wt % of rare earths, 0-5 wt % of magnesium, less than 5% by weight of aluminium, 0-10 wt % of manganese and/or zirconium, and the balance being iron, wherein the inoculant additionally contains 0.1-10 wt % of particulate bismuth oxide particles and optionally 0.1-10 wt % of one or more particulate metal sulphides and/or one or more particulate iron oxides, where the particulate bismuth oxide is mixed or blended with the ferrosilicon particles, or is simultaneously added to cast iron together with the particulate ferrosilicon particles.

An inoculant for the manufacture of cast iron with spheroidal graphite is disclosed, the inoculant has a particulate ferrosilicon alloy having between 40 and 80% by weight of Si; 0.02-8% by weight of Ca; 0-5% by weight of Sr; 0-12% by weight of Ba; 0-15% by weight of rare earth metal; 0-5% by weight of Mg; 0.05-5% by weight of Al; 0-10% by weight of Mn; 0-10% by weight of Ti; 0-10 by weight of Zr; the balance being Fe and incidental impurities in the ordinary amount, wherein the inoculant additionally contains, by weight, based on the total weight of inoculant: 0.1 to 15% of particulate Bi.sub.2S.sub.3, and optionally between 0.1 and 15% of particulate Bi.sub.2O.sub.3, and/or between 0.1 and 15% of particulate Sb.sub.2O.sub.3, and/or between 0.1 and 15% of particulate Sb.sub.2S.sub.3, and/or between 0.1 and 5% of particulate Fe.sub.3O.sub.4, Fe.sub.2O.sub.3, FeO, or a mixture thereof, and/or between 0.1 and 5% of one or more of particulate FeS, FeS.sub.2, Fe.sub.3S.sub.4, or a mixture thereof, a method for producing such inoculant and use of such inoculant.

An inoculant for the manufacture of cast iron with spheroidal graphite is disclosed, the inoculant has a particulate ferrosilicon alloy having between 40 and 80% by weight of Si; 0.02-8% by weight of Ca; 0-5% by weight of Sr; 0-12% by weight of Ba; 0-15% by weight of rare earth metal; 0-5% by weight of Mg; 0.05-5% by weight of Al; 0-10% by weight of Mn; 0-10% by weight of Ti; 0-10 by weight of Zr;
the balance being Fe and incidental impurities in the ordinary amount,
wherein the inoculant additionally contains, by weight, based on the total weight of inoculant: 0.1 to 15% of particulate Sb.sub.2S.sub.3, and optionally between 0.1 and 15% of particulate Bi.sub.2O.sub.3, and/or between 0.1 and 15% of particulate Sb.sub.2O.sub.3, and/or between 0.1 and 15% of particulate Bi.sub.2S.sub.3, and/or between 0.1 and 5% of one or more of particulate Fe.sub.3O.sub.4, Fe.sub.2O.sub.3, FeO, or a mixture thereof, and/or between 0.1 and 5% of one or more of particulate FeS, FeS.sub.2, Fe.sub.3S.sub.4, or a mixture thereof, a method for producing such inoculant and use of such inoculant.

An inoculant for the manufacture of cast iron with spheroidal graphite is disclosed, the inoculant has a particulate ferrosilicon alloy having between 40 and 80% by weight of Si; 0.02-8% by weight of Ca; 0-5% by weight of Sr; 0-12% by weight of Ba; 0-15% by weight of rare earth metal; 0-5% by weight of Mg; 0.05-5% by weight of Al; 0-10% by weight of Mn; 0-10% by weight of Ti; 0-10 by weight of Zr; the balance being Fe and incidental impurities in the ordinary amount, wherein the inoculant additionally contains, by weight, based on the total weight of inoculant: 0.1 to 15% of particulate Sb.sub.2S.sub.3, and optionally between 0.1 and 15% of particulate Bi.sub.2O.sub.3, and/or between 0.1 and 15% of particulate Sb.sub.2O.sub.3, and/or between 0.1 and 15% of particulate Bi.sub.2S.sub.3, and/or between 0.1 and 5% of one or more of particulate Fe.sub.3O.sub.4, Fe.sub.2O.sub.3, FeO, or a mixture thereof, and/or between 0.1 and 5% of one or more of particulate FeS, FeS.sub.2, Fe.sub.3S.sub.4, or a mixture thereof, a method for producing such inoculant and use of such inoculant.

An inoculant for the manufacture of cast iron with spheroidal graphite is disclosed, the inoculant has a particulate ferrosilicon alloy having between 40 and 80% by weight of Si, 0.02-8% by weight of Ca; 0-5% by weight of Sr; 0-12% by weight of Ba; 0-10% by weight of rare earth metal; 0-5% by weight of Mg; 0.05-5% by weight of Al; 0-10% by weight of Mn; 0-10% by weight of Ti; 0-10% by weight of Zr; the balance being Fe and incidental impurities in the ordinary amount, wherein the inoculant additionally contains, by weight, based on the total weight of inoculant: 0.1 to 15% by weight of particulate rare earth metal oxide(s) and at least one of from 0.1 to 15% of particulate Bi.sub.2O.sub.3, and/or from 0.1 to 15% of particulate Bi.sub.2S.sub.3, and/or from 0.1 to 15% of particulate Sb.sub.2O.sub.3, and/or from 0.1 to 15% of particulate Sb.sub.2S.sub.3, and/or from 0.1 to 5% of one of more of particulate Fe.sub.3O.sub.4, Fe.sub.2O.sub.3, FeO, or a mixture thereof, and/or from 0.1 to 5% of one of more of particulate FeS, FeS.sub.2, Fe.sub.3S.sub.4, or a mixture thereof, a method for producing such inoculant and use of such inoculant.

A method is provided for fabricating iron castings for metallic components. The method for fabricating the iron castings may include forming a molten solution by melting carbon and iron and combining carbon nanomaterials with the molten solution. A first portion of the carbon nanomaterials combined with the molten solution may be dispersed therein. The method may also include cooling the molten solution to solidify at least a portion of the carbon thereof to fabricate the iron castings. The first portion of the carbon nanomaterials may be dispersed in the iron castings.

An inoculant for the manufacture of cast iron with spheroidal graphite is disclosed, the inoculant has a particulate ferrosilicon alloy having

between 40 and 80% by weight of Si;
0.02-8% by weight of Ca;
0-5% by weight of Sr;
0-12% by weight of Ba;
0-15% by weight of rare earth metal;
0-5% by weight of Mg;
0.05-5% by weight of Al;
0-10% by weight of Mn;
0-10% by weight of Ti;
0-10 by weight of Zr;
the balance being Fe and incidental impurities in the ordinary amount,
wherein the inoculant additionally contains, by weight, based on the total weight of inoculant: 0.1 to 15% of particulate Sb.sub.2S.sub.3, and optionally between 0.1 and 15% of particulate Bi.sub.2O.sub.3, and/or between 0.1 and 15% of particulate Sb.sub.2O.sub.3, and/or between 0.1 and 15% of particulate Bi.sub.2S.sub.3, and/or between 0.1 and 5% of one or more of particulate Fe.sub.3O.sub.4, Fe.sub.2O.sub.3, FeO, or a mixture thereof, and/or between 0.1 and 5% of one or more of particulate FeS, FeS.sub.2, Fe.sub.3S.sub.4, or a mixture thereof, a method for producing such inoculant and use of such inoculant.

A ductile iron composition including, by weight: about 3.4% to about 4.0% Si; about 3.0% to about 3.5% C; about 0.5% to about 1.0% Cr; about 0.02% to about 0.05% Mo; up to about 0.01% S; up to about 0.5% Mn; and balance iron and incidental impurities. The composition has a a ferritic body center cubic microstructure and has a graphite nodule density of greater than 100 per mm.sup.2. A method for forming a ductile iron composition is also disclosed.