The present disclosure relates to a steel for pressure vessels used in a hydrogen sulfide atmosphere, and relates to a steel material for pressure vessels having excellent resistance to hydrogen induced cracking (HIC) and a manufacturing method thereof.

The present disclosure relates to a steel for pressure vessels used in a hydrogen sulfide atmosphere, and relates to a steel material for pressure vessels having excellent resistance to hydrogen induced cracking (HIC) and a manufacturing method thereof.

A Ni—Cr—Fe alloy with improved resistance to stress corrosion cracking in nuclear environments, the alloy comprising 23-28 wt % Cr, 25-35 wt % Ni, <0.03 wt % C, <0.70 wt % Si, <1.0 wt % Mn, <0.015 wt % S, >0.35 wt % Ti, 0.15-0.45 wt % Al, <0.75 wt % Cu, and balance Fe and incidental impurities. The alloy may be used in steam generator tubing of a nuclear reactor. A method of producing an article includes: providing the alloy as disclosed herein; forming the alloy into the article by cold working the alloy to 20%; and heat treating the article.

A case hardening steel having excellent fatigue resistance is provided at relatively low production cost. A case hardening steel has a chemical composition containing C: 0.10% to 0.30%, Si: 0.10% to 1.20%, Mn: 0.30% to 1.50%, S: 0.010% to 0.030%, Cr: 0.10% to 1.00%, B: 0.0005% to 0.0050%, Sb: 0.005% to 0.020%, and N: 0.0150% or less in a predetermined range, and further containing Al: 0.010%≤Al≤0.120% in the case where B−(10.8/14)N≥0.0003%, and 27/14[N−(14/10.8)B+0.030]≤Al≤0.120% in the case where B−(10.8/14)N<0.0003%.

A case hardening steel having excellent fatigue resistance is provided at relatively low production cost. A case hardening steel has a chemical composition containing C: 0.10% to 0.30%, Si: 0.10% to 1.20%, Mn: 0.30% to 1.50%, S: 0.010% to 0.030%, Cr: 0.10% to 1.00%, B: 0.0005% to 0.0050%, Sb: 0.005% to 0.020%, and N: 0.0150% or less in a predetermined range, and further containing Al: 0.010%≤Al≤0.120% in the case where B−(10.8/14)N≥0.0003%, and 27/14[N−(14/10.8)B+0.030]≤Al≤0.120% in the case where B−(10.8/14)N<0.0003%.

An embodiment of the present invention provides a steel material, for a pressure vessel, comprising, in weight %, 0.06-0.25% of carbon (C), 0.05-0.50% of silicon (Si), 1.0-2.0% of manganese (Mn), 0.005-0.40% of aluminum (Al), 0.010% or less of phosphorus (P), 0.0010% or less of sulfur (S), 0.001-0.03% of niobium (Nb), 0.001-0.03% of vanadium (V), 0.001-0.03% of titanium (Ti), 0.01-0.20% of chromium (Cr), 0.05-0.15% of molybdenum (Mo), 0.01-0.50% of copper (Cu), 0.05-0.50% of nickel (Ni), 0.0005-0.0050% of magnesium (Mg), 0.0005-0.0050% of calcium (Ca), 0.0020% or less of oxygen (O), and the remainder being Fe and other unavoidable impurities. A microstructure comprises in terms of area fraction 30% or less of pearlite and the remainder being ferrite. A non-metallic inclusion contains Mg—Al—Ca—O composite oxide.

Disclosed are a pressure vessel steel sheet and a method for manufacturing the same, the steel sheet comprising: by wt %, 0.10-0.20% of C, 0.15-0.40% of Si, 1.15-1.50% of Mn, 0.45-0.60% of Mo, 0.03-0.30% of Cu, 0.025% or less of P, 0.025% or less of S and 0.005-0.06% of sol. Al; two or more selected from the group consisting of 0.03-0.30% of Cr, 0.002-0.025% of Nb and 0.002-0.025% of Zr, and the balance of Fe and inevitable impurities, wherein the structure comprises a mixture structure of ferrite, perlite and tempered bainite after post weld heat treatment (PWHT) for 60 hours at 600-660° C., and the area fraction of the tempered bainite is at least 10% (excluding 100%).

Disclosed are a pressure vessel steel sheet and a method for manufacturing the same, the steel sheet comprising: by wt %, 0.10-0.20% of C, 0.15-0.40% of Si, 1.15-1.50% of Mn, 0.45-0.60% of Mo, 0.03-0.30% of Cu, 0.025% or less of P, 0.025% or less of S and 0.005-0.06% of sol. Al; two or more selected from the group consisting of 0.03-0.30% of Cr, 0.002-0.025% of Nb and 0.002-0.025% of Zr, and the balance of Fe and inevitable impurities, wherein the structure comprises a mixture structure of ferrite, perlite and tempered bainite after post weld heat treatment (PWHT) for 60 hours at 600-660° C., and the area fraction of the tempered bainite is at least 10% (excluding 100%).

A seamless steel pipe of the present invention is a seamless steel pipe having a composition that includes, in mass %, C: 0.02 to 0.12%, Si: 0.010 to 1.00%, Mn: 0.10 to 2.00%, P: 0.050% or less, S: 0.004% or less, Al: 0.010 to 0.100%, Cu: 0.03 to 0.80%, Ni: 0.02 to 0.50%, Cr: 0.55 to 1.00%, Sb: 0.005 to 0.20%, and the balance Fe and incidental impurities, and satisfying the following formula (1),

1.7×Cu*+11×Cr*+3.8×Sb*≥13.5   (1), where Cu*, Cr*, and Sb* represent average concentrations of Cu, Cr, and Sb, respectively, in mass %, as measured in a region 0.5 to 2.0 mm away from an outer surface of the steel pipe, the seamless steel pipe having a yield strength of 230 MPa or more, and a tensile strength of 380 MPa or more.

A seamless steel pipe of the present invention is a seamless steel pipe having a composition that includes, in mass %, C: 0.02 to 0.12%, Si: 0.010 to 1.00%, Mn: 0.10 to 2.00%, P: 0.050% or less, S: 0.004% or less, Al: 0.010 to 0.100%, Cu: 0.03 to 0.80%, Ni: 0.02 to 0.50%, Cr: 0.55 to 1.00%, Sb: 0.005 to 0.20%, and the balance Fe and incidental impurities, and satisfying the following formula (1),

1.7×Cu*+11×Cr*+3.8×Sb*≥13.5   (1), where Cu*, Cr*, and Sb* represent average concentrations of Cu, Cr, and Sb, respectively, in mass %, as measured in a region 0.5 to 2.0 mm away from an outer surface of the steel pipe, the seamless steel pipe having a yield strength of 230 MPa or more, and a tensile strength of 380 MPa or more.