An object of the present invention is to provide magnesium oxide for an annealing separator which is useful for obtaining grain-oriented electromagnetic steel sheets with excellent magnetic properties and insulating properties. To resolve the above object, an aspect of the present invention resides in magnesium oxide for an annealing separator having a sulfur content of 0.1 to 0.5 mass % and an aggregation degree R.sub.Blaine/R.sub.BET of 3.0 to 5.5 wherein R.sub.Blaine is the particle size calculated from the Blaine specific surface area and R.sub.BET is the particle size calculated from the BET specific surface area.

An object of the present invention is to provide magnesium oxide for an annealing separator which is useful for obtaining grain-oriented electromagnetic steel sheets with excellent magnetic properties and insulating properties. To resolve the above object, an aspect of the present invention resides in magnesium oxide for an annealing separator having a sulfur content of 0.1 to 0.5 mass % and an aggregation degree R.sub.Blaine/R.sub.BET of 3.0 to 5.5 wherein R.sub.Blaine is the particle size calculated from the Blaine specific surface area and R.sub.BET is the particle size calculated from the BET specific surface area.

A bolt of the present invention has a composition comprising: 0.50 mass % or greater and 0.65 mass % or less of carbon (C), 1.5 mass % or greater and 2.5 mass % or less of silicon (Si), 1.0 mass % or greater and 2.0 mass % or less of chromium (Cr), 0.2 mass % or greater and 1.0 mass % or less of manganese (Mn), 1.5 mass % or greater and 5.0 mass % or less of molybdenum (Mo), wherein a total amount of phosphorous (P) and sulfur (S) as impurities is 0.03 mass % or less, the remaining is iron (Fe), and the bolt comprises an iron based oxide film with a film thickness of 3 μm or greater and 20 μm or less on the surface thereof. The bolt has excellent delayed fracture resistance and reliably provides a fastening axial force.

An object of the present invention is to provide magnesium oxide for an annealing separator which is useful for obtaining grain-oriented electromagnetic steel sheets with excellent magnetic properties and insulating properties. To resolve the above object, an aspect of the present invention resides in magnesium oxide for an annealing separator which has a BET specific surface area of 12.0×10.sup.3 to 25.0×10.sup.3 m.sup.2.Math.kg.sup.−1 and a Blaine specific surface area of 2.0×10.sup.3 to 7.0×10.sup.3 m.sup.2.Math.kg.sup.−1.

An object of the present invention is to provide magnesium oxide for an annealing separator which is useful for obtaining grain-oriented electromagnetic steel sheets with excellent magnetic properties and insulating properties. To resolve the above object, an aspect of the present invention resides in magnesium oxide for an annealing separator which has a BET specific surface area of 12.0×10.sup.3 to 25.0×10.sup.3 m.sup.2.Math.kg.sup.−1 and a Blaine specific surface area of 2.0×10.sup.3 to 7.0×10.sup.3 m.sup.2.Math.kg.sup.−1.

Provided is a grain-oriented electrical steel sheet having better transformer iron loss property than conventional grain-oriented electrical steel sheets. A grain-oriented electrical steel sheet comprises: a steel substrate; a forsterite film on a surface of the steel substrate; and a Cr-depleted layer at a boundary between the steel substrate and the forsterite film, the Cr-depleted layer having a Cr concentration that is 0.70 times to 0.90 times a Cr concentration of the steel substrate.

Provided is a grain-oriented electrical steel sheet having better transformer iron loss property than conventional grain-oriented electrical steel sheets. A grain-oriented electrical steel sheet comprises: a steel substrate; a forsterite film on a surface of the steel substrate; and a Cr-depleted layer at a boundary between the steel substrate and the forsterite film, the Cr-depleted layer having a Cr concentration that is 0.70 times to 0.90 times a Cr concentration of the steel substrate.

A method for manufacturing a grain-oriented electrical steel sheet according to an embodiment of the present invention comprises the steps of: hot-rolling a slab to prepare a hot-rolled sheet, the slab containing, in wt %, 2.0 to 6.0% of Si, 0.04 to 0.12% of Mn, 0.001 to 0.022% of N, 0.027 to 0.060% of C, 0.01 to 0.08% of Nb, 0.01% or less of Ti, and the balance of Fe and other inevitable impurities; cold-rolling the hot-rolled sheet to prepare a cold-rolled sheet; and subjecting the primarily recrystallization-annealed cold-rolled sheet to secondary recrystallization annealing.

An exemplary embodiment in the present disclosure provides a grain-oriented electrical steel sheet containing, by wt %: 3.0 to 4.5% of Si; 0.05 to 0.2% of Mn; 0.015 to 0.035% of Al; 0.0015% or less (excluding 0%) of C; 0.0015% or less (excluding 0%) of N; 0.0015% or less (excluding 0%) of S; and a balance of Fe and other unavoidable impurities, wherein the grain-oriented electrical steel sheet satisfies the following Relational Expressions 1 and 2:

(W.sub.13/50/W.sub.17/50)≤0.57  [Relational Expression 1]

(W.sub.15/50/W.sub.17/50)≤0.76  [Relational Expression 2] where Wx/y represents a core loss value under conditions in which a magnitude of an applied magnetic field is x/10 T and a frequency is y Hz.

The present disclosure relates to a high-strength hot-dip galvanized steel sheet having excellent surface quality and electrical resistance spot weldability, and a method for manufacturing the same. A galvanized steel sheet according to an aspect of the present disclosure is a galvanized steel sheet including a base steel sheet and a zinc-based plating layer formed on a surface of the base steel sheet, wherein a ratio (a/b) of a hardness of a surface layer portion (a) to a hardness of an internal portion (b) of the base steel sheet may be less than 0.95.