The present invention provides a method for manufacturing more beautiful black coated steel sheets by uniformly blackening the coating layer. Specifically, the present invention provides a method for manufacturing black coated steel sheets, which brings Zn—Al—Mg alloy coated steel sheets (1) into contact with steam in a closed container (10), wherein said closed container (10) can maintain a predefined internal pressure through variable control of the amount of steam flowing into said closed container (10) and/or the amount of steam flowing out of said closed container (10), and in said closed container (10) that can maintain said predefined pressure, said Zn—Al—Mg alloy coated steel sheets (1) have contact with the steam introduced into said closed container (10).

A rolled steel sheet, for press hardening is provided, having a chemical composition where Ti/N>3.42, and the carbon, manganese, chromium and silicon contents satisfy: $2.6C+\frac{\mathrm{Mn}}{5.3}+\frac{\mathrm{Cr}}{13}+\frac{\mathrm{Si}}{15}\ge 1.1\%.$
The sheet has a nickel content Ni.sub.surf at any point of the steel in the vicinity of the surface over a depth Δ, such that: Ni.sub.surf >Ni.sub.nom, Ni.sub.nom denoting the nominal nickel content of the steel, and such that, Ni.sub.max denoting the maximum nickel content within Δ: $\frac{\left({\mathrm{Ni}}_{\max }+{\mathrm{Ni}}_{\mathrm{nom}}\right)}{2}\times \left(\Delta \right)\ge 0.6,$
and such that: $\frac{\left({\mathrm{Ni}}_{\max }-{\mathrm{Ni}}_{\mathrm{nom}}\right)}{\Delta }\ge 0.01$
and the surface density of all of the particles D.sub.i and the surface density of the particles D.sub.(>2 μm) larger than 2 micrometers satisfy, at least to a depth of 100 micrometers in the vicinity of the surface of said sheet:
D.sub.i+6.75 D.sub.(>2 μm) <270
D.sub.i and D.sub.(>2 μm) being expressed as number of particles per square millimeter, and said particles denoting all the oxides, sulfides, and nitrides, either pure or combined such as oxysulfides and carbonitrides, present in the steel matrix.

Provided is a cold rolled steel sheet with excellent press formability, which contains a binder satisfying specific requirements and wax satisfying specific requirements, and has a layer containing the wax in a specific mass ratio at a specific coating weight.

Provided is a stainless steel substrate for a solar cell, the stainless steel substrate including, by mass %, Cr: 9% to 25%, C: 0.03% or less, Mn: 2% or less, P: 0.05% or less, S: 0.01% or less, N: 0.03% or less, Al: 0.005% to 5.0%, Si: 0.05% to 4.0%, and a remainder including Fe and unavoidable impurities, in which an oxide film containing (i) Al.sub.2O.sub.3 in an amount of 50% or more or containing (i) Al.sub.2O.sub.3 and (ii) SiO.sub.2 in a total amount of 50% or more is formed on a surface of stainless steel having a composition which contains Al: 0.5% or more and/or Si: 0.4% or more and satisfies the following expression (1).
Cr+10Si+Mn+Al>24.5  (1)

Provided is a galvannealed steel sheet with excellent anti-powdering property when press forming is performed, without controlling the contents of chemical elements in steel which are effective for strengthening a steel sheet, such as Si and P, to be low in order to achieve required material properties and without increasing cost due to, for example, processes being complicated. A galvannealed steel sheet with excellent anti-powdering property has a coated layer taking in grains of a base steel sheet such that the grains constitute 2.0% or more and 15.0% or less of the coated layer in terms of cross section area ratio.

This relates to a process for manufacturing a recovery annealed coated steel substrate for packaging applications and a packaging steel product produced thereby.

Provided is a high-strength hot-dip galvanized steel sheet having excellent plating adhesion, formability, and hole expandability with an ultimate tensile strength of 980 MPa or more, the hot-dip galvanized steel sheet comprising a hot-dip galvanized layer formed on a surface of a base steel sheet. The base steel sheet contains, by mass %, C: 0.05% to 0.4 %; Si: 0.01% to 3.0%; Mn: 0.1% to 3.0%; Al: 0.01 to 2.0%; in which Si+Al >0.5%, P: limited to 0.04% or less; S: limited to 0.05% or less; N: limited to 0.01% or less; and a balance including Fe and inevitable impurities, a microstructure of the base steel sheet contains 40% or more by total volume fraction of martensite and bainite, 8% or more by volume fraction of residual austenite, and a balance of the microstructure being ferrite or ferrite and 10% or less by volume fraction of pearlite. The martensite contains 10% or more by total volume fraction of two or more kinds of three kinds of martensites (1), (2), and (3), and the hot-dip galvanized layer contains less than 7 mass % of Fe.

The high strength steel sheet has a chemical composition including 0.08% to 0.20% of C, 0.3% or less of Si, 0.1% to 3.0% of Mn, 0.10% or less of P, 0.030% or less of S, 0.10% or less of Al, 0.010% or less of N, 0.20% to 0.80% of V, and the remainder composed of Fe and incidental impurities on a percent by mass basis, and a microstructure which includes 95% or more of ferrite phase on an area percentage basis, in which fine precipitates are dispersed having a distribution in such a way that the number density of precipitates having a particle size of less than 10 nm is 1.0×10.sup.5/μm.sup.3 or more and the standard deviation of natural logarithm values of precipitate particle sizes with respect to precipitates having a particle size of less than 10 nm is 1.5 or less.

The present invention pertains to a hot press forming member having excellent resistance to hydrogen embrittlement, and a method for manufacturing same. An aspect of the present invention provides a hot press forming member having excellent resistance to hydrogen embrittlement, the hot press forming member comprising a base steel plate and an alloy-plated layer formed on the surface of the base steel plate, wherein the alloy-plated layer contains pores such that pores having a size of 5 μm or less constitute 3-30% of the surface area of the alloy-plated layer as viewed in a cross-section taken in the thickness direction of the member.

A galvannealed steel sheet includes: a steel sheet; a coating layer on a surface of the steel sheet; and a mixed layer formed between the steel sheet and the coating layer, in which the mixed layer includes a base iron portion having fine grains having a size of greater than 0 μm and equal to or smaller than 2 μm, a Zn—Fe alloy phase, and oxides containing one or more types of Mn, Si, Al, and Cr, and in the mixed layer, the oxides and the Zn—Fe alloy phase are present in grain boundaries that form the fine grains and the Zn—Fe alloy phase is tangled with the base iron portion.
[Mn]+[Si]+[Al]+[Cr]≧0.4  (Expression 1)